Results 181 to 190 of about 85,113 (264)

Rich‐Electronic Interface Promoting Hydrogen‐Bond Reversible Formation for Ultra‐Stable and Energy‐Efficient Catalytic CO2 Capture

open access: yesCarbon Energy, EarlyView.
Bridging micro–macro scales, a biomass‐derived Ni@C interface creates electron‐rich sites and hydrogen‐bond proton‐relay pathways, tuning interfacial charge and reversible hydrogen bond to enhance carbon capture capacity. Verified by in situ spectroscopy, multi‐scale simulations, and long‐term industrial testing, this system enables low‐temperature and
Yuetong Zhao   +14 more
wiley   +1 more source

Nitrooxylation in Organic Synthesis: From Classical Nitrate Ester Formation to Modern Catalytic Strategies

open access: yesChemistry – A European Journal, EarlyView.
Nitrooxylation—the installation of nitrate esters (–ONO2) has evolved from classical mixed‐acid protocols to catalytic and mechano‐, flow‐, photo‐, and electrochemical strategies. This review delineates ionic and radical manifolds for C–ONO2 bond formation, emphasizing mechanistic control, selected substrate scope, and selectivity.
Jayanta Dey, Dmitry Katayev
wiley   +1 more source

Relay Approach: A Convergent Synthesis of Key Fragments en route to (+)‐Neosorangicin A

open access: yesChemistry – A European Journal, EarlyView.
A selective synthesis of three key fragments of the antibiotically active (+)‐neosorangicin A is reported, providing a foundation for its convergent total synthesis and proof of strategy via a relay approach. ABSTRACT Herein, we report the synthesis of the three key fragments of the macrolide antibiotic (+)‐neosorangicin A, a compound exhibiting potent
Marvin Wenninger   +6 more
wiley   +1 more source

Efficient Light‐Driven Multi‐Electron Accumulation on Viologens by Molecular Control Over Photochemical Reaction Pathways

open access: yesChemistry – A European Journal, EarlyView.
Minimum structural changes, maximum output: By either utilizing a more oxidizing Ru(II) polypyridyl chromophore or by using a more reducing SED, the photocatalytic reduction of methyl viologen (MV2+) proceeds via a reductive quenching pathway. This not only significantly accelerates the overall photoreduction process but also allows accumulation of ...
Fatemeh Sousani   +7 more
wiley   +1 more source

CYP2C19 Genotyping to Guide Clopidogrel Prescribing for Neurovascular Indications: A Survey of Institutional Approaches

open access: yesClinical Pharmacology &Therapeutics, EarlyView.
Dual antiplatelet therapy (DAPT) with aspirin and clopidogrel is commonly used for secondary prevention following acute ischemic stroke (AIS) and neurointerventional procedures. However, the efficacy of clopidogrel is reduced in carriers of CYP2C19 no‐function alleles.
Rachael M. Stone   +11 more
wiley   +1 more source

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