Results 181 to 190 of about 53,000 (304)

CO2‐Induced Reverse Lattice Oxygen Spillover on Pt/CeO2 Enables Sulfur‐Resistant Dry Reforming of Methane

open access: yesAngewandte Chemie, EarlyView.
A critical step, dry reforming of methane (DRM) converts biogas into useful syngas. Yet trace H2S in biogas rapidly poisons DRM catalysts, limiting practical use. We developed a robust Pt/CeO2 catalyst sustaining DRM activity via CO2‐induced reverse lattice oxygen spillover in H2S‐rich environments.
Jun Liu   +11 more
wiley   +2 more sources

Some Economics of Seasonal Gas Storage

open access: yes
We propose a model of seasonal gas markets which is flexible enough to include supply and demand shocks while also considering exhaustibility. The relative performances of alternative policies based on price caps and associated measures or tariffs are ...
Villeneuve, Bertrand   +2 more
core  

Resolving passive heat transfer and phase‐change heat in cryogenic CO2 deposition (Desublimation) from CO2/N2 mixtures

open access: yesAIChE Journal, EarlyView.
Abstract In cryogenic CO2 desublimation systems where phase change dominates both heat transfer and separation, conventional lumped thermal‐resistance treatments embed interfacial latent heat into an overall heat‐transfer coefficient, obscuring how phase‐change heat is partitioned between the gas phase and the coolant and limiting diagnostic insight ...
Shengwen Xiao   +2 more
wiley   +1 more source

π‐Enlargement in Porphyrin Macrocycles at Interfaces

open access: yesAngewandte Chemie, EarlyView.
On‐surface synthesis of a 20‐π free‐base expanded porphyrin, by depositing onto a hot Ag(111) substrate an 18‐π free‐base precursor equipped with ‐CF3 functional groups ABSTRACT Porphyrins are essential heteroatomic macrocycles, fundamental to both biological systems and advanced technology.
Ana Barragán   +11 more
wiley   +2 more sources

Rethinking energy transition strategies for the European Union amid rising energy prices. [PDF]

open access: yesProc Natl Acad Sci U S A
Meng W   +9 more
europepmc   +1 more source

An Autonomous Large Language Model‐Agent Framework for Transparent and Local Time Series Forecasting

open access: yesAdvanced Intelligent Discovery, EarlyView.
Architecture of the proposed large language model (LLM)‐based agent framework for autonomous time series forecasting in thermal power generation systems. The framework operates through a vertical pipeline initiated by natural language queries from users, which are processed by the LLM Agent Core powered by Llama.cpp and a ReAct loop with persistent ...
William Gouvêa Buratto   +5 more
wiley   +1 more source

Facet‐Dependent Water Inhibition of Alkanol Dehydration on TiO2 via Distinct Water–Alkanol Complexes

open access: yesAngewandte Chemie, EarlyView.
Water inhibits alkanol dehydration on TiO2 through facet‐dependent manners via distinct IPA‐water complexes. On TiO2(001), water forms a strongly hydrogen‐bonded isopropoxide–H2O complex that readily dominates the surface and substantially elevates the activation barrier, whereas on TiO2(101), water weakly hydrogen‐bonds to molecular IPA, resulting in ...
Wenda Hu   +14 more
wiley   +2 more sources

Economic Assessment of Biomethane Supply System Based on Natural Gas Infrastructure

open access: yes
Upgraded biogas injected into a natural gas grid provide considerable increase of renewable energy share within the natural gas-fired systems. The costs of biomethane produced in distributed biogas plants and injected into the natural gas grid were ...
Paturska, Anna   +2 more
core  

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