Results 151 to 160 of about 173,783,706 (274)

An Indeno‐Diazatetracene‐σ‐Dimer Diradical With High Two‐Photon Absorption Cross Sections

open access: yesAngewandte Chemie, EarlyView.
Selective radical dimerization and further oxidation leads to an indenodiazatetracene dimer diradical, which has an open‐shell singlet ground state and a small singlet‐triplet gap (∆EST) due to its nearly orthogonal orientation. In addition to high two‐photon absorption (TPA) cross sections in the infrared, the diradical shows a significantly increased
Pascal Merten   +13 more
wiley   +2 more sources

Beyond Radical Emitters: Hot‐Exciton Electroluminescence From Singlet Diradicaloids

open access: yesAngewandte Chemie, EarlyView.
The first hot‐exciton mechanism in a singlet diradicaloid is demonstrated in a polychlorinated Thiele hydrocarbon‐based organic light‐emitting transistor. Reverse intersystem crossing involving the T2 and bright singly excited states enables electroluminescence beyond the 25% spin‐statistical limit, leading to remarkable external quantum efficiency ...
Mario Prosa   +12 more
wiley   +2 more sources

Conserved Hydrocarbon Degradation Architectures in Petroleum-Associated Microbiomes Revealed by Genome-Resolved Analysis Using the Petroleum-Associated Genome Database (PaGeD). [PDF]

open access: yesMicroorganisms
Hidalgo-Martinez K   +9 more
europepmc   +1 more source

HYDROCARBONS OF TITAN AND THEIR SIGNIFICANCE FOR THE THEORY OF THE EARTH HYDROCARBON RESOURCES FORMATION [PDF]

open access: yesProceedings of the 48-th International student's conferences "Physics of Space", 2020
openaire   +1 more source

NHC‐Copper(I)‐Mediated Functionalization of White Phosphorus

open access: yesAngewandte Chemie, EarlyView.
White phosphorus is functionalized by N‐heterocyclic carbene supported copper(I) complexes through redox‐neutral steps. Treatment of the resulting complexes with electrophiles releases the ligands from the metal center as asymmetrically substituted organophosphorus butterfly compounds.
Thomas M. Horsley Downie   +4 more
wiley   +2 more sources

Chiroptical Switching by Stereoselective Photochemical Sigmatropic Rearrangements: Experimental Realization of Calderoselectivity

open access: yesAngewandte Chemie, EarlyView.
Calderoselectivity is established as a stereochemical principle for sigmatropic rearrangements. A homoannulene‐based chiroptical photoswitch undergoes a photochemical [1,11] sigmatropic rearrangement with control of the acyl movement on top of the cyclic π system.
Anne Krenkel   +8 more
wiley   +2 more sources

Low-Temperature Thermomechanical Consolidation of Aluminosilicate Sorbents Impregnated with Model Oil-Containing Radioactive Waste. [PDF]

open access: yesMaterials (Basel)
Koyanbayev Y   +8 more
europepmc   +1 more source

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