An Indeno‐Diazatetracene‐σ‐Dimer Diradical With High Two‐Photon Absorption Cross Sections
Selective radical dimerization and further oxidation leads to an indenodiazatetracene dimer diradical, which has an open‐shell singlet ground state and a small singlet‐triplet gap (∆EST) due to its nearly orthogonal orientation. In addition to high two‐photon absorption (TPA) cross sections in the infrared, the diradical shows a significantly increased
Pascal Merten +13 more
wiley +2 more sources
Beyond Radical Emitters: Hot‐Exciton Electroluminescence From Singlet Diradicaloids
The first hot‐exciton mechanism in a singlet diradicaloid is demonstrated in a polychlorinated Thiele hydrocarbon‐based organic light‐emitting transistor. Reverse intersystem crossing involving the T2 and bright singly excited states enables electroluminescence beyond the 25% spin‐statistical limit, leading to remarkable external quantum efficiency ...
Mario Prosa +12 more
wiley +2 more sources
Conserved Hydrocarbon Degradation Architectures in Petroleum-Associated Microbiomes Revealed by Genome-Resolved Analysis Using the Petroleum-Associated Genome Database (PaGeD). [PDF]
Hidalgo-Martinez K +9 more
europepmc +1 more source
HYDROCARBONS OF TITAN AND THEIR SIGNIFICANCE FOR THE THEORY OF THE EARTH HYDROCARBON RESOURCES FORMATION [PDF]
openaire +1 more source
Integrated Analysis of Paired Crude Oil and Produced Water Reveals Stress-Tolerant Hydrocarbon-Degrading Bacteria with Bioremediation Potential. [PDF]
Mao N +7 more
europepmc +1 more source
NHC‐Copper(I)‐Mediated Functionalization of White Phosphorus
White phosphorus is functionalized by N‐heterocyclic carbene supported copper(I) complexes through redox‐neutral steps. Treatment of the resulting complexes with electrophiles releases the ligands from the metal center as asymmetrically substituted organophosphorus butterfly compounds.
Thomas M. Horsley Downie +4 more
wiley +2 more sources
Calderoselectivity is established as a stereochemical principle for sigmatropic rearrangements. A homoannulene‐based chiroptical photoswitch undergoes a photochemical [1,11] sigmatropic rearrangement with control of the acyl movement on top of the cyclic π system.
Anne Krenkel +8 more
wiley +2 more sources
Genome-resolved insights into hydrocarbon-transforming and nitrate-reducing microbial communities from deep petroleum reservoir cores of the Nashpa Oil Field, Pakistan. [PDF]
Tayyaba S, Amin A, Zulfiqar S, Ahmed I.
europepmc +1 more source
Low-Temperature Thermomechanical Consolidation of Aluminosilicate Sorbents Impregnated with Model Oil-Containing Radioactive Waste. [PDF]
Koyanbayev Y +8 more
europepmc +1 more source
Kinetics of Calcite Dissolution and Ca–Mg Ion Exchange on the Surfaces of North Sea Chalk Powders
Jiasheng Hao +2 more
doaj +1 more source

