Results 91 to 100 of about 137 (128)

Rediscovering Sodium Ionophores as Selective Agents for Lithium Recognition and Extraction

open access: yesAngewandte Chemie, EarlyView.
Long‐classified sodium ionophores unexpectedly prefer lithium and act as efficient extractants in solid–liquid extraction (SLE). Readily prepared from catechol and haloacetamides, these hosts recover hydrated LiCl from multicomponent salt mixtures via a hydration‐assisted O···Li+ binding mode, enabling scalable lithium separation with Li/Na, Li/K, and ...
Jakub Narodowiec   +6 more
wiley   +2 more sources

Miniaturized Conductometric Biosensor for Rapid Detection of TNF‐α in Saliva

open access: yesAdvanced NanoBiomed Research, EarlyView.
A miniaturized conductometric sensor detects TNF‐α at femtomolar levels with high selectivity. The device enables noninvasive testing using pooled human saliva and supports smartphone‐based, real‐time resistance readings. This portable biosensor offers a practical alternative for monitoring TNF‐α, providing new opportunities for diabetes and related ...
Mingjie Yang   +8 more
wiley   +1 more source

Synergistic Lewis Acid Photocatalysis Over Cluster‐Defect‐Engineered UiO‐66 for Efficient Liquid Biomass Upgrading

open access: yesAngewandte Chemie, EarlyView.
A cluster‐defect engineering strategy is presented for the rational design of Zn‐incorporated UiO‐66 photocatalysts. Selective acid etching mediates hierarchical porosity and abundant Lewis acid sites, tailoring the electronic structure and enhancing light harvesting.
Hao Wang   +6 more
wiley   +2 more sources

Supramolecular Modulation of Photoinduced Charge Transfer: Tuning Between Tunneling and Incoherent Hopping

open access: yesAngewandte Chemie, EarlyView.
Molecular recognition guest binding can comprehensively modulate photoinduced charge‐transfer dynamics in the cyclophane host, including charge separation and recombination, via coherent superexchange and incoherent hopping. Unlike covalent donor–bridge–acceptor systems, this supramolecular approach avoids tedious syntheses and offers precise tuning of
Xueze Zhao   +11 more
wiley   +2 more sources

Chelator‐Free Radiometal Labeling Inside Engineered Affibodies

open access: yesAngewandte Chemie, EarlyView.
Affibodies are compact and robust three‑helix binders used in imaging and therapy. Engineering a triple‑cysteine motif into their core enables chelator‑free binding of important radiometals, like Bi(III), Pb(II), In(III), and Ga(III) with rapid uptake and exceptional stability.
Lani J. Davies   +6 more
wiley   +2 more sources

Novel Non‐Cytotoxic Acylphosphinates and Acylphosphine Oxides Photoinitiators

open access: yesAngewandte Chemie, EarlyView.
Novel acylphosphine oxide (APO) and acylphosphinate photoinitiators based on DPO and DOPO were designed to investigate structure–property relationships including photochemical performance, polymerization efficiency and cytotoxicity. While DPO derivatives showed excellent reactivity, DOPO‐based systems also displayed good efficiency and significantly ...
Jiansong Yin   +13 more
wiley   +2 more sources

3D‐Printable Nanoporous Thermosets via Disulfide‐Based Polymerization‐Induced Microphase Separation

open access: yesAngewandte Chemie, EarlyView.
α‐Lipoic acid‐derived degradable macro‐chain transfer agents (macroCTAs) with tunable hydrophilicity drive polymerization‐induced microphase separation (PIMS) in photocurable resins. Selective etching via disulfide cleavage then generates interconnected nanoporous thermosets, and compatibility with liquid‐crystal display (LCD) 3D printing enables the ...
Xueheng Dai   +8 more
wiley   +2 more sources

Synthesis and Interfacial Behavior of Mixed Potassium N‐Lauroyl/N‐Myristoyl Glycinate Surfactants With Varying Alkyl Chain Ratios

open access: yesAsia-Pacific Journal of Chemical Engineering, EarlyView.
ABSTRACT Biodegradable and low‐irritant amino acid–based surfactants have attracted considerable attention as environmentally friendly alternatives to conventional petroleum‐derived surfactants. In this study, a series of acyl amino acid surfactants with identical amino acid head groups but different alkyl chain lengths were synthesized via a modified ...
Toshihiro Takeshita   +11 more
wiley   +1 more source

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