Results 41 to 50 of about 5,436 (176)

Immediate Organic Room‐Temperature Phosphorescence in Programmable Luminescent Tags Enabled by Oxygen‐Free Fabrication

open access: yesAdvanced Materials Technologies, EarlyView.
Programmable luminescent tags based on organic room‐temperature phosphorescence are shown to be governed by oxygen incorporation during fabrication. Oxygen‐free processing enables immediate phosphorescence activation, controlled thermal preconditioning, and tunable activation doses.
Lucy Winkler   +2 more
wiley   +1 more source

Planar Chiral Carbazole‐Naphthalene Bisimide Hetero‐Cyclophane for Circularly Polarized Delayed Fluorescence

open access: yesAngewandte Chemie, EarlyView.
Tightly stacked carbazole and 1,2:5,6–naphthalene bisimide units afforded a planar chiral hetero‐cyclophane. The architecturally refined system, with strong charge‐transfer interaction and enhanced structural rigidity, exhibits orange‐red delayed CPL emission in both solution and solid states.
Sanchari Debnath   +3 more
wiley   +2 more sources

Lead‐Free Chiral Hybrid Metal Halides for Circularly Polarized Light‐Emitting Diodes

open access: yesAdvanced Optical Materials, EarlyView.
Lead‐free chiral hybrid metal halides provide a versatile platform for realizing chiroptical responses through chiral modulation of metal–halide frameworks with diverse dimensionalities, induces inversion‐symmetry breaking and enables dissymmetric excited‐state transitions toward efficient circularly polarized luminescence and electroluminescence. This
Kun Zhu, Li Wan
wiley   +1 more source

Stacking the Deck to Make Materials With Atypically Short Heterometallic d8 M(II)···Au(III) Bonds

open access: yesAngewandte Chemie, EarlyView.
Tetracyanoplatinate(II) and tetracyanoaurate(III), through self‐assembly in the presence of KCl, crystallize from water to form a one‐dimensional chain featuring the first reported PtII···AuIII metallophilic interaction with a very short distance of ∼3.0 Å between the metal centers.
Leanna M. Karn   +6 more
wiley   +2 more sources

Mechanical Stretch α‐Cyclodextrin Pseudopolyrotaxane Elastomer with Reversible Phosphorescence Behavior

open access: yesAdvanced Science
Polyethylene glycol chains in two terminals of the naphthalene functional group are threaded into α‐cyclodextrin cavities to form the pseudopolyrotaxane (NPR), which not only effectively induces the phosphorescence of the naphthalene functional group by ...
Yi Zhang   +4 more
doaj   +1 more source

Temperature Correction in a Single Luminophore Pressure‐Sensitive Paint Using a Dual‐Emitting Gold Acridine Complex

open access: yesAdvanced Optical Materials, EarlyView.
The use of pressure‐sensitive luminescent molecules to quantify surface pressure in wind tunnel testing has revolutionized experimental aerodynamics. This work develops a dual‐emitting gold acridine complex for the simultaneous sensing of pressure and temperature independently of each other.
Alexander C. Brannan   +5 more
wiley   +1 more source

Energy Transfer‐Mediated Magnetoluminescence of an Octahedral MnII Complex Ligated With Bis(Diphenylphosphino)Methane Dioxide

open access: yesAngewandte Chemie, EarlyView.
Energy‐transfer‐mediated magnetoluminescence of paramagnetic transition metal complexes: dope solids of an octahedral MnII complex into the corresponding ZnII complex exhibited a pronounced magnetic field response of emission spectra under the application of magnetic fields.
Asato Mizuno   +5 more
wiley   +2 more sources

Matrix‐free room‐temperature phosphorescence graphitic carbon nitride quantum dots based on halogen bond interactions for security applications

open access: yesNano Select, 2022
Herein, we first designed a one‐step strategy to achieve matrix‐free room temperature phosphorescence (RTP) materials by low temperature solid phase synthesis, using sodium citrate as carbon source and urea as nitrogen source.
Yuelin Kong   +3 more
doaj   +1 more source

Benzo[b]Thiophene‐Derived Low‐T1 Multi‐Resonance Emitter with Suppressed Thermally Activated Delayed Fluorescence for Extending Organic Light‐Emitting Diode Lifetime by Managing Triplet‐Related Bimolecular Interactions

open access: yesAdvanced Optical Materials, EarlyView.
Introducing a 5‐phenylbenzo[b]thiophene unit into the DABNA core lowers the T1 level, enlarging the ΔEST to suppress TADF. This molecular design preserves narrow deep‐blue emission while drastically reducing triplet‐related degradation. Consequently, the resulting emitter, BN‐TPh‐TPA, delivers a threefold operational lifetime over the TADF‐active t ...
Jihun Hwang   +7 more
wiley   +1 more source

Force‐Induced Control of Circularly Polarized Luminescence With Rotaxane Architecture

open access: yesAngewandte Chemie, EarlyView.
Force‐induced reversible on/off switching of circularly polarized luminescence is achieved with a rotaxane‐based supramolecular mechanophore. The mechanophore, featuring a chiral helicene luminophore, is incorporated as a first network cross‐linker into a double‐network organogel.
Keigo Nonaka   +10 more
wiley   +2 more sources

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