Results 61 to 70 of about 1,333 (175)
This review summarizes the latest progress of RTP materials with self‐healing and shape–memory functions, in which reversible bonding interactions are the key points. With the careful discussions of the typical strategies and representative works, the intrinsic relationship between dynamic bonding interactions and RTP property is well revealed. Finally,
Dan Li, Jie Yang, Zhen Li
wiley +1 more source
Circularly Polarized Luminescence in Rotaxanes and Catenanes
Rotaxanes and catenanes have proven to be key structures in the development of artificial molecular machines with a variety of applications. Among them, the study and modulation of optical properties, mainly light emission, have been widely explored. The
Dr. Arthur H. G. David +2 more
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Long-range movement of large mechanically interlocked DNA nanostructures
Rotaxanes are interlocked molecules that can undergo sliding and rotational movements and can be used in artificial molecular machines and motors. Here, Simmel and co-workers show a rigid rotaxane structures consisting of DNA origami subunits that can ...
Jonathan List +4 more
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Catechol‐based annulated aromatics with carbonyl units are ideal ligands for the formation of titanium(IV) containing lithium‐bridged hierarchical helicates. They allow for the first time the use of amide units to obtain the dimeric helicate‐type complexes.
Steffen Schauerte +4 more
wiley +1 more source
Triacetylated γ‐cyclodextrin incorporated into poly(methyl methacrylate) primarily acted as a rigid filler and reinforced the matrix polymer, with the reinforcement behavior following the Guth–Gold equation. In addition, the glass transition temperature was maintained upon incorporation, indicating that the additive did not plasticize the polymer ...
Rinsei Toda +2 more
wiley +1 more source
This contribution highlights recent studies focused on mechanically interlocked molecules. By combining density functional theory‐converged wavefunctions with highly effective real‐space algorithms for visualizing and quantifying covalent bonds and noncovalent interactions, a first‐principles description of the driving forces governing molecular motion,
Costantino Zazza
wiley +1 more source
Smart molecules for imaging, sensing and health (SMITH)
This autobiographical review provides a personal account of the author’s academic journey in supramolecular chemistry, including brief summaries of research efforts in membrane transport, molecular imaging, ion-pair receptors, rotaxane synthesis ...
Bradley D. Smith
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Photocatalytically Active Mechanically Interlocked Carbon Nanotubes
Mechanically interlocked CNTs (MINTs) are studied as heterogeneous photocatalysts. Two different motifs are presented, which own enhanced activity versus homogeneous systems at very low loadings, high TON, excellent recyclability, varied scope and no leaching.
Paula Blanco‐Caamano +5 more
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Rotaxane‐Functionalized Dyes for Charge‐Rectification in p‐Type Photoelectrochemical Devices
A supramolecular photovoltaic strategy is applied to enhance power conversion efficiencies (PCE) of photoelectrochemical devices by suppressing electron–hole recombination after photoinduced electron transfer (PET).
Tessel Bouwens +5 more
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We report novel pseudorotaxanes based on the complexation between pillar[4]arene[1]quinone and 1,10-dibromodecane. The complexation is found to have a 1:1 host–guest complexation stoichiometry in chloroform but a 2:1 host–guest complexation stoichiometry
Xinru Sheng, Errui Li, Feihe Huang
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