Potassium‐Ligand Cooperation Facilitated Chemical Bond Activation and Catalytic Hydrogenation
A new strategy for alkali metal‐mediated catalysis based on metal–ligand cooperation (MLC) is presented. Potassium pincer complexes exhibit remarkable reactivity toward a range of molecules via an unprecedented potassium–ligand cooperative mechanism. This reactivity enables potassium‐catalyzed hydrogenation, providing efficient reduction of ketones and
Yaoyu Liang +6 more
wiley +1 more source
Fast Entangling Gates for Rydberg Atoms via Resonant Dipole-Dipole Interaction
The advent of digital neutral-atom quantum computers relies on the development of fast and robust protocols for high-fidelity quantum operations. In this work, we introduce a novel scheme for entangling gates using four atomic levels per atom: a ground ...
Giuliano Giudici +4 more
doaj +1 more source
Spin–Phonon Relaxation Dynamics from a Conical Intersection of Trapped Rydberg Ions
Non-adiabatic processes near conical intersections are rooted in the stronger coupling between electronic and nuclear degrees of freedom. Using a system of two trapped Rydberg ions, their high polarizability and strong dipolar interactions allow to form ...
Manish Chaudhary, Rejish Nath, Weibin Li
doaj +1 more source
Rényi Entropies of Multidimensional Oscillator and Hydrogenic Systems with Applications to Highly Excited Rydberg States. [PDF]
Dehesa JS.
europepmc +1 more source
Calculated Rydberg States of the PO Molecule
The Rydberg States of the PO molecule, converging to the ground state of the PO+ ion, are calculated using the LCAO–MO SCF orbitals of the molecular ion core.
A. L. Roche +2 more
core +1 more source
Heavy Rydberg and ion-pair states: chemistry, spectroscopy and theory
Recent advances in our knowledge of heavy Rydberg and ion-pair states are critically reviewed, with emphasis placed on the close kinship between the two. Heavy Rydberg states are long-range vibrational states, reaching far beyond ≫102 Å for higher levels.
Kirrander, Adam +5 more
core +1 more source
Charge-Transfer-Induced Predissociation in Rydberg States of Molecular Cations: MgAr. [PDF]
Wehrli D +4 more
europepmc +1 more source
Valence and Rydberg states of protonated formaldehyde
MR-CISD and MR-CISD + Q calculations have been performed for the vertical excitations of protonated formaldehyde in comparison to formaldehyde. Singlet and triplet states have been investigated.
Müller, T. +4 more
core +1 more source
Space Imaging of Six-Wave Mixing in a Rydberg Dressing Atomic Ensemble
Atoms excited to Rydberg states can be used to enhance the nonlinearity of medium via electromagnetic induced transparency (EIT) due to their special property.
Junling Che, Jintao Bai, Yanpeng Zhang
doaj +1 more source
Exciton-polaron Rydberg states in monolayer MoSe2 and WSe2. [PDF]
Liu E +7 more
europepmc +1 more source

