Results 211 to 220 of about 693,650 (251)

Intermolecular Carbon–Carbon Naphthalene Coupling Involves a Radical Mechanism Driven by Cytochrome P450 in Alternaria alternata

Angewandte Chemie, EarlyView.
1,8‐DHN is an important intermediate to form complex aromatic ring systems. Phenol‐coupling reactions are important for the dimerization of two molecules. Here, we show that a fungal cytochrome P450 enzyme catalyzes specific C─C bonds. ABSTRACT Dihydroxynaphthalene (DHN) derivatives are precursors of biologically important molecules, including melanin ...
Jia Gao, Leyao Chen, Karin Steffen, Henrik Schweder, Birgit Schreckenberger, Shu‐Ming Li, Ben Auxier, Antonis Rokas, Reinhard Fischer   +8 more
wiley   +2 more sources

Enhanced platinum and palladium recovery from aqueous solutions: a comparative study of acylthiourea and amine-modified silica gel adsorbents. [PDF]

RSC Adv
Mphahlele MRR, Mosai AK, Tutu H, Kotzé IA.   +3 more
europepmc   +1 more source

Patient‐Personalized Membrane‐Coated Magnetic Nanovectors: Probing the Biomimetic Interface for Targeted Tumor Theranostics

Advanced NanoBiomed Research, EarlyView.
This study presents a label‐free spectroscopic platform to evaluate membrane protein conformation on patient‐derived glioblastoma cell membrane‐coated magnetic nanovectors. This work demonstrates that preserving membrane protein integrity during nanoparticle fabrication enhances homotypic tumor targeting and reduces hard protein corona formation ...
Daniele De Pasquale, Michela Patrucco, Melike Belenli Gümüş, Alessandra Flori, Luca Menichetti, Stefania Moscato, Valentina Bonanni, Alessandra Gianoncelli, Milan Žižić, Pietro Fiaschi, Monica Truffelli, Andrea Bianconi, Melis Emanet, Gianmarco Ferri, Chiara Maria Mazzanti, Carlotta Pucci, Gianni Ciofani   +16 more
wiley   +1 more source

An Alkali Amide Approach to Triphosphabenzenes

Angewandte Chemie, EarlyView.
Alkali metal amides offer a simple route to phosphorus aromatics. LiNMe2 catalyzes [2+2+2] cyclotrimerization of a phosphaalkyne, while tetrahydrofuran (THF) stabilizes a λ4‐triphosphabenzene anion intermediate. Using KN(SiMe3)2 switches reactivity to arene C(sp3)─H activation, giving benzylated λ4‐triphosphabenzenes and rare λ5‐triphosphabenzenes ...
Owen J. Jones, Andrew D. Bond, Ruth L. Webster   +2 more
wiley   +2 more sources

Color Compounds Removal from Tequila Vinasses Using Silica Gel Adsorbents Functionalized with Thiol Moieties: Equilibrium and Kinetics Studies. [PDF]

Molecules
Gonzalez-Valerio C, Peregrina-Lucano AA, Manríquez-González R, Pérez-Fonseca AA, Robledo-Ortíz JR, Shenderovich IG, Gómez-Salazar S.   +6 more
europepmc   +1 more source

Biomimetic Nanomedicine for Aging‐Impaired Bone Regeneration: From Microenvironmental Dysfunction to Precision Therapeutics

Advanced NanoBiomed Research, EarlyView.
Aging disrupts the cellular, immune, vascular, and neural processes required for bone regeneration. This review connects these pathological barriers with biomimetic nanomedicine design, highlighting strategies for cellular rejuvenation, immune modulation, vascular regeneration, and neuro–bone coupling.
Zeyu Wang, He Zhang, Simo Liu, Rui Wang, Yiran Wei, Kailu Zheng, Yanming Guo, Min Li, Dian Yuan, Yuxin Liu, Lifang Feng, Yongping Ma, Yan Liu   +12 more
wiley   +1 more source

Macrocyclization of ω‐Isocyano Aldehydes

Angewandte Chemie, EarlyView.
The ω‐isocyano aldehydes readily undergo cyclization to afford α‐acyloxy, α‐hydroxy, α‐acetamido, and α‐keto macrolactams, as well as tetrazole‐fused macrocycles, via C(sp3)─C(sp2) bond formation, providing access to diverse α‐functionalized medium‐sized lactams and macrolactams. ABSTRACT Medium‐sized rings and macrocycles constitute a privileged class
Baochao Yang, Teerawat Songsichan, Cyril Piemontesi, Qian Wang, Jieping Zhu   +4 more
wiley   +2 more sources

Separation of Adjacent Light Rare Earth Elements Using Silica Gel Modified with Diglycolamic Acid. [PDF]

Materials (Basel)
Ogata T, Narita H.
europepmc   +1 more source

Sequence‐Controlled Helical Ladder Polymers: Impact of Stereochemical Sequence on Helical Geometry and Chiral Recognition

Angewandte Chemie, EarlyView.
Nature programs distinct secondary structures and functions through subtle stereochemical differences, as exemplified by amylose and cellulose. Translating this principle into synthetic ladder polymers, stereochemical sequence control gives rise to diastereomeric coil‐ and ribbon‐type helices with complementary chiral recognition, demonstrating ...
Tomoyuki Ikai, Kanta Wakabayashi, Masaya Yoshida, Kosuke Oki, Eiji Yashima   +4 more
wiley   +2 more sources

Degradation of Dyes Catalyzed by Aminophenyl-Substituted Mn-Porphyrin Immobilized on Chloropropyl Silica Gel and Evaluation of Phytotoxicity. [PDF]

ACS Omega
de Oliveira IM, Docílio Pereira JV, da Silva Pereira EC, de Souza MS, Cazetta ML, da Cruz Neto CC, da Silva Santana VM, Araújo Pinto VH, Rebouças JS, da Silva Martins DC, DeFreitas-Silva G, Costa DS, da Silva VS, da Silva VS.   +13 more
europepmc   +1 more source