Results 161 to 170 of about 585,207 (352)

Exploring the Photophysical Processes of an Al3+ Sensor Based on Schiff Base

open access: yesChemPhysChem, EarlyView.
Multiple excited‐state intramolecular proton transfer (ESIPT) processes and twisted intramolecular charge transfer (TICT) states are observed on the S1 state potential energy surface of an Al3+ sensor. The ESIPT process induces an ultrafast CC rotation process and leads to a non‐emissive TICT state.
Bingqing Sun   +4 more
wiley   +1 more source

Semi‐Automated Pipeline for Transition State Search of Molecular Photoswitches

open access: yesChemPhotoChem, EarlyView.
A semi‐automated pipeline for the transition state search of molecular switches (PiTS3) is reported, which facilitates the search, optimization, and conformational analysis of transition states of photochemical switches based on the stilbene, imine, aza‐diarylethene, and norbornadiene structures.
Roman Yu. Peshkov   +2 more
wiley   +1 more source

Carbonate microfacies and transgressive‐regressive sequences of Oxfordian shallow‐water limestones (Korallenoolith, Lower Saxony Basin)

open access: yesThe Depositional Record, EarlyView.
The Bisperode section is one of the most expanded and complete sections with shallow‐marine Oxfordian strata in the LSB. This study provides a reference record for shallow‐marine settings and allows for the correlation of the strata from the LSB with Oxfordian deposits distributed elsewhere in the world.
Deyan Zhang   +3 more
wiley   +1 more source

Covalent Organic Framework‐Based Photocatalysts from Synthesis to Applications

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This review explores the principles, synthesis, and reactions of COFs, highlighting their structural influences on photocatalytic activity. It presents key applications of COFs as photocatalyst. Various modification strategies for optimizing their efficiency are discussed.
Junxian Liu   +5 more
wiley   +1 more source

A C3‐Symmetric Diphenylethylendiamine‐Based Catalyst in the Asymmetric Michael Addition of α,β‐Unsaturated Ketones with 4‐Hydroxycoumarin and 4‐Hydroxyquinolin‐2‐One

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Two C3‐symmetric organocatalysts with multiple amino groups are prepared and employed in the asymmetric addition of 4‐hydroxycoumarin and quinoline‐2‐one to unsaturated ketones. The all‐amino version of the catalyst induces the better stereoselectivity and provides the products in up to 95% yield.
Shilashi Badasa Oljira   +10 more
wiley   +1 more source

A path to reconciliation between Indigenous and settler–colonial epistemologies

open access: yesFrontiers in Ecology and the Environment, EarlyView.
There is a movement across settler–colonial institutions of education and research to engage with Indigenous Peoples and Knowledges. Many settler and Indigenous governments are pursuing pathways to move forward together to address global problems such as climate change. However, given the pervasive history of exploitation and displacement of Indigenous
Joseph Gazing Wolf   +20 more
wiley   +1 more source

Error Analysis of a Pressure‐Correction Method With Explicit Time‐Stepping

open access: yesInternational Journal for Numerical Methods in Fluids, EarlyView.
We study explicit variants of this well‐established pressure‐correction scheme for solving the Navier–Stokes equations. Step 3 is replaced by an explicit time‐integration method. We give the complete error analysis for this scheme that allows for highly efficient implementations.
Utku Kaya, Thomas Richter
wiley   +1 more source

Potential Spectral Tuning of the Tapetum Lucidum in a Broadly Distributed Ungulate

open access: yesJournal of Experimental Zoology Part A: Ecological and Integrative Physiology, EarlyView.
ABSTRACT The tapetum lucidum, a biological reflector system found in the eyes of many vertebrate species, enhances visual sensitivity in low light conditions by reflecting light back through the retina. The structure of the ungulate tapetum fibrosum is unique, and its reflectance varies temporally in reindeer (Rangifer tarandus).
Blaise A. Newman   +2 more
wiley   +1 more source

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