Results 121 to 130 of about 5,309,525 (360)

Preconditioning for Allen-Cahn variational inequalities with non-local constraints [PDF]

open access: yes, 2010
The solution of Allen-Cahn variational inequalities with mass constraints is of interest in many applications. This problem can be solved both in its scalar and vector-valued form as a PDE-constrained optimization problem by means of a primal-dual active
Blank, Luise   +2 more
core  

Polycyclic Aromatics as Promising Phosphorescence Materials

open access: yesChemistryEurope, EarlyView.
This review focuses on the recent progress of polycyclic aromatic compounds (PACs)‐based phosphorescent materials. Their molecular structural characteristics as promising phosphors are highlighted, and the efficient strategies from molecular and aggregation levels have been illustrated systematically to promote the development of PACs with desirable ...
Peipei Liu, Qianqian Li, Zhen Li
wiley   +1 more source

Nonlinear dynamics of turbulent waves in fluids and plasmas [PDF]

open access: yesNonlinear Processes in Geophysics, 2005
In a model drift wave system that is interesting both in fluids and plasmas, we find that an embedded moving saddle point plays an important role at the onset of turbulence.
K. He, A. C.-L. Chian
doaj  

Copper‐Catalyzed Defluorinative Allylboration of Allenes with Trifluoromethyl Alkenes

open access: yesChemistryEurope, EarlyView.
A copper‐catalyzed borylative coupling of allenes with 1‐trifluoromethyl alkenes is reported. The reaction selectively provides synthetically versatile borylated 1,1‐difluoro‐1,5‐dienes that can be converted into a range of medicinally relevant fluorinated compounds. Mechanistic studies reveal a key role of the catalytically generated LiCl by assisting
Martín Piñeiro‐Suárez   +3 more
wiley   +1 more source

Direct Growth of Leopard‐Patterned Graphene on Zinc Anodes via Sonochemistry for High‐Performance Aqueous Zinc‐Ion Batteries

open access: yesCarbon Energy, EarlyView.
We propose a novel bottom‐up synthesis method for 2D nanocarbon films using a sonochemical deposition process at room temperature and under atmospheric pressure. This process uniformly coats a Zn foil with unique 2D nanocarbon films, termed Leopard‐patterned graphene (Leo‐G).
Dong Il Kim   +9 more
wiley   +1 more source

Steric Restraints in Redox‐Active Guanidine Ligands and Their Impact on Coordination Chemistry

open access: yesChemistry – A European Journal, EarlyView.
One carbon makes the difference; a diguandine with an ethylene bridge does not coordinate metals, while a diguanidine with a propylene bridge coordinates to a variety of metals. In this work, we report the synthesis and coordination chemistry of the first cyclic diguanidino‐benzene ligands and compare their coordination chemistry with that of open ...
Eliane Engels   +7 more
wiley   +1 more source

Robust Decision Trees Against Adversarial Examples

open access: yes, 2019
Although adversarial examples and model robustness have been extensively studied in the context of linear models and neural networks, research on this issue in tree-based models and how to make tree-based models robust against adversarial examples is ...
Boning, Duane   +3 more
core  

Proton Conductivities of Stepwise Protonated Imidazole‐Fused Tetraphenylene Derivatives

open access: yesChemistry – A European Journal, EarlyView.
Proton conducting tetraphenylene molecules (ImTP) containing a imidazole group were controlled by the degree of protonation. By controlling the degree of protonation from neutral ImTP to H1ImTP⁺, H2ImTP2⁺, and H4ImTP⁴⁺, we demonstrated that the balance between intermolecular hydrogen bonding and electrostatic interactions affects structural stability ...
Mu Li   +4 more
wiley   +1 more source

Finite Larmor radius influence on MHD solitary waves [PDF]

open access: yesNonlinear Processes in Geophysics, 2009
MHD solitons are studied in a model where the usual Hall-MHD model is extended to include the finite Larmor radius (FLR) corrections to the pressure tensor. The resulting 4-dimensional set of differential equations is treated numerically.
E. Mjølhus
doaj  

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