Results 21 to 30 of about 378 (91)
Segmental‐level molecular engineering of a supramolecular polyurethane elastomer integrates strain‐adaptive chains, soft elastic segments, and dynamic hydrogen bonding motifs. This design reconciles skin‐like softness with muscle‐level strength, offering a sustainable and high‐performance material platform for next‐generation artificial skin and soft ...
Haoming Zou +5 more
wiley +1 more source
Thermoelectric Properties of a Diketopyrrolopyrrole Polymer With Radical Pending Units
The successful incorporation of TEMPO radicals as side‐chain groups onto the conjugated backbone of an n‐type polymer significantly enhanced the doping efficiency of N‐DMBI via a hydrogen transfer doping mechanism. ABSTRACT Organic n‐type polymers usually suffer from relatively low electrical conductivity which hampers their application as an active ...
Jiang Jing +16 more
wiley +1 more source
This work systematically investigates the effects of 3‐phenylthiophene (TPh), biphenyl (BPh), and 1‐chloro‐4‐iodobenzene (CIB) additive treatments on photoactive layer morphology. Among them, BPh synergistically enhances charge dynamics and significantly reduces energy loss, enabling simultaneous improvements in photocurrent and voltage and thus ...
Yue Xu +6 more
wiley +1 more source
Abstract Proteins operate in crowded physiological environments, yet their conformational and oligomeric states are largely inferred from experiments performed under dilute buffer conditions. Here, we show that for lysozyme (LYS) and bovine serum albumin (BSA), self‐crowding at physiologically relevant concentrations alters protein structure and ...
Gil I. Olgenblum +2 more
wiley +1 more source
A Dithio Vinylthio C2 Synthon Enabling Crystalline and Luminescent Sulfur‐Decorated Polymers
Transforming CaC2 into a modular C2 building block enables the synthesis of α,ω‐bis(vinylthio) monomer and its conversion into crystalline, sequence‐defined sulfur‐decorated polymers. Their dense thioether clustering induces nonconventional luminescence and provides structure–function control in a more‐sustainable polymer platform.
Bercis Pektas +4 more
wiley +1 more source
Solution‐processed OLEDs containing discotic liquid‐crystalline MR‐TADF emitters are reported. Supramolecular self‐assembly induces homeotropic columnar alignment, enforcing preferential horizontal orientation of the emitter transition dipole moment in spin‐coated films, which leads to an enhancement in the device light outcoupling efficiency while ...
Joydip De +6 more
wiley +1 more source
The shape of guanine self‐assemblies is tuned by introducing alkyl (G8), fluoroalkyl (G8f), and oligoether (G8g) side chains into the G moiety. The scanning tunneling microscopy results and calculations show that the presence and type of the side chain strongly affect the G self‐assembly network.
So‐Huei Kang +9 more
wiley +1 more source
Counterion‐Controlled Photocatalytic Doping of Organic Semiconductors
Counterion size is shown to actively control photocatalytic doping in organic semiconductors. Small anions suppress aggregation of acridinium photocatalysts, enhance electron transfer, and dramatically increase doping efficiency. This simple strategy enables conductivities up to 2000 S cm−1 in benchmark polymers, revealing counterions as a powerful yet
Tiefeng Liu +16 more
wiley +1 more source
Time‐resolved SAXS reveals how physiologically relevant metal ions shape the earliest conformational responses of monomeric α‐synuclein. Fe3+ induces rapid compaction, Cu2+ generates heterogeneous and partially folded ensembles, while Mn2+ and Zn2+ cause only modest changes.
Rebecca Sternke‐Hoffmann +3 more
wiley +1 more source
Cartilage‐inspired supramolecular polyurethane–urea (PU‐BAMB) elastomers are developed by integrating hierarchical hydrogen bonding and π–π stacking interactions within a dynamically reconfigurable network. This synergistic supramolecular architecture overcomes the intrinsic trade‐off between rigidity and recoverability, imparting exceptional toughness,
Rou‐Han Lai +14 more
wiley +1 more source

