Results 181 to 190 of about 3,964,268 (253)

Polyoxometalates in Photocatalytic CO2 Reduction: Multielectron Redox Regulation Across Molecular and Hybrid Architectures

open access: yesEcoEnergy, EarlyView.
This review focuses on multielectron redox regulation across molecular and hybrid architectures for photocatalytic CO2 reduction, covering intrinsic POM photocatalysts, photosensitizer‐assisted assemblies, POM–metal–organic complexes, and POM‐integrated semiconductors and MOF/COF heterostructures to link structural motifs with charge transport, product
Bonan Li, Xiaowen Ruan, Sai Kishore Ravi
wiley   +1 more source

Near‐Infrared Light‐Driven Photocatalysis: From Advanced Light‐Harvesting Architectures to Rational Reactor Design

open access: yesEcoEnergy, EarlyView.
This review systematically elucidates the regulatory strategies for NIR light, encompassing macroscopic mechanisms such as band engineering, localized surface plasmon resonance (LSPR), upconversion luminescence, and photosensitizer molecules. Furthermore, it provides an in‐depth discussion on their cutting‐edge applications in energy conversion (e.g ...
Huijuan Wang   +8 more
wiley   +1 more source

Precisely Constructed Asymmetric Coordination Tuned High‐Spin Co Sites for Sacrificial Agent‐Free H2O2 Photocatalytic Production

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The asymmetric Co–N2O2 coordination structure was precisely constructed through the assembly of Salen COF. The high‐spin (t2g4eg3$$ {\mathrm{t}}_{2\mathrm{g}}^4{\mathrm{e}}_{\mathrm{g}}^3 $$) Co center enables Pauling‐type O2 adsorption, inhibiting the cleavage of the O–O bond. π‐d conjugation enhances charge separation and transport.
Wenhui Qi   +5 more
wiley   +1 more source

Lignocellulosic Triboelectric Materials for Energy Harvesting and Emerging Applications: A Review on Lignin‐Molecular Engineering toward Improved Performance

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Contrasting sustainable biomass with depleting petroleum resources, this review charts the evolutionary timeline of lignin‐based TENGs. We systematically evaluate their fundamental mechanisms, enhancement strategies, and applications in green self‐powered electronics.
Yuxin Yang   +9 more
wiley   +1 more source

Bio‐Inspired Sclerotization of Lignin: A Robust Adhesive for Photothermal Wood‐Based Panels

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A high‐performance lignin adhesive is engineered via an insect‐inspired sclerotization strategy involving oxidation and hyperbranched polymer grafting, overcoming lignin's adhesion failure, and yielding a wet shear strength of 1.02–1.21 MPa. The adhesive endows wood‐based panels with photothermal functionality; building energy simulations indicate HVAC‐
Zihao Ye   +8 more
wiley   +1 more source

High‐Strength, Fluorescent, Triboelectric Cellulose Hydrogel‐Derived Plastics Through Molecular Network Engineering for Energy Harvesting and Motion Sensing

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Multifunctional cellulose hydrogel‐derived plastics (FCBPs) are fabricated via a novel molecular network engineering strategy involving epoxy cross‐linking, solvent exchange, and hot‐pressing techniques. The resulting materials exhibit high mechanical strength, excellent thermal/solvent resistance, stable fluorescence, complete biodegradability, and ...
Fuyuan Lu   +11 more
wiley   +1 more source

Polymerization of Heteroleptic Amphiphilic Osmium(II) Complexes at the Air/Water Interface: Attempts Toward Nanoarchitectonics in Form of Molecular Textiles

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Amphiphilic heteroleptic osmium(II) complexes enable a bottom‐up route toward molecular textiles via interfacial polymerization. Confined to a single monolayer, noncontact atomic force microscopy reveals predominantly linear polymers with partial branching.
Luise J. Sokoliuk   +7 more
wiley   +1 more source

Fluorinated Iminosugar Glycomimetics: Synthesis and Activity as GCase Ligands

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
DAST‐mediated deoxyfluorination of suitably functionalized piperidines provided regio‐ and stereoselective access to fluorinated piperidine and pyrrolidine glycomimetics, the latter arising from an unusual ring‐contraction process. Fluorination generally enhanced β‐glucocerebrosidase (GCase) inhibitory potency, but lost PC activity toward L444P/L444P ...
Francesca Mangiavacchi   +9 more
wiley   +1 more source

“Nature's Polymer Reimagined: Conventional and Green Routes to Pectin, Its Bioactive Promise and Industrial Applications”

open access: yesFood Chemistry International, EarlyView.
Pectin, a versatile natural polymer, is extracted through conventional and emerging green extraction methods, offering multifunctional bioactive properties useful in food, pharmaceutical, and environmental applications. ABSTRACT Pectin, a molecular tapestry woven from diverse polysaccharides, holds a pivotal role across food, pharmaceutical, and ...
Afra Anika Rafique   +3 more
wiley   +1 more source

Hydrogel‐Based Bioelectronics: From Therapy and Sensing to Neuromorphic Computation

open access: yesFlexTech, EarlyView.
This review establishes a material–conduction–property–application framework connecting hydrogel chemistry and charge transport with therapy, sensing, closed‐loop feedback, and neuromorphic computation. ABSTRACT Bioelectronics establish bidirectional communication between living systems and electronic devices, providing an enabling platform for ...
Jianlong Hong   +7 more
wiley   +1 more source

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