Results 181 to 190 of about 44,617 (255)

Turning Bonding Into Function: The Emerging Role of the Bioactive Selenium─Metal Motif in Toxicology and Medicinal Chemistry

Chemistry – A European Journal, EarlyView.
Balancing Act: Se─M bond serving as the fulcrum of the balance scale to compare the different weight of toxicity and therapeutic effects in biological environment. ABSTRACT The synthesis and characterization of organo‐selenium compounds have attracted considerable interest for decades, driven by the search for efficient catalysts and bioinspired ...
Matteo Filippi, Alessandro Rubbi, Pablo A. Nogara, Giovanni Ribaudo, Vito Lippolis, João B. T. Rocha, Laura Orian   +6 more
wiley   +1 more source

Cyano-modulated Zn(II)-Schiff base complexes for lysosome-targeted fluorescence imaging and pH-responsive camptothecin delivery. [PDF]

Int J Pharm X
Zhang X, Sun W, Li X, Li Y, Xiang S, Zhang L, Yang Y.   +6 more
europepmc   +1 more source

Spatiotemporal cellular dynamics of the notochord shape intervertebral disc morphogenesis in the mouse embryo through apoptosis and proliferation

Developmental Dynamics, EarlyView.
Abstract Background The notochord is a midline structure essential for vertebrate embryogenesis, contributing to the development of the nervous system, digestive tract, and vertebral column. In particular, notochord signaling is indispensable for proper patterning and coordinated development of alternating vertebrae and intervertebral discs (IVDs ...
Julie Warin, Estelle Balissat, Pauline Colombier, Lily Paillat, Maeva Dutilleul, Anne Camus   +5 more
wiley   +1 more source

Polyoxometalates in Photocatalytic CO2 Reduction: Multielectron Redox Regulation Across Molecular and Hybrid Architectures

EcoEnergy, EarlyView.
This review focuses on multielectron redox regulation across molecular and hybrid architectures for photocatalytic CO2 reduction, covering intrinsic POM photocatalysts, photosensitizer‐assisted assemblies, POM–metal–organic complexes, and POM‐integrated semiconductors and MOF/COF heterostructures to link structural motifs with charge transport, product
Bonan Li, Xiaowen Ruan, Sai Kishore Ravi
wiley   +1 more source

Precisely Constructed Asymmetric Coordination Tuned High‐Spin Co Sites for Sacrificial Agent‐Free H2O2 Photocatalytic Production

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The asymmetric Co–N2O2 coordination structure was precisely constructed through the assembly of Salen COF. The high‐spin (t2g4eg3$$ {\mathrm{t}}_{2\mathrm{g}}^4{\mathrm{e}}_{\mathrm{g}}^3 $$) Co center enables Pauling‐type O2 adsorption, inhibiting the cleavage of the O–O bond. π‐d conjugation enhances charge separation and transport.
Wenhui Qi, Shaonan Gu, Yinan Wang, Wenhao Yin, Bin Sun, Guowei Zhou   +5 more
wiley   +1 more source

Lignocellulosic Triboelectric Materials for Energy Harvesting and Emerging Applications: A Review on Lignin‐Molecular Engineering toward Improved Performance

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Contrasting sustainable biomass with depleting petroleum resources, this review charts the evolutionary timeline of lignin‐based TENGs. We systematically evaluate their fundamental mechanisms, enhancement strategies, and applications in green self‐powered electronics.
Yuxin Yang, Boyu Du, Yuwen Wang, Tian Tang, Yuxuan Xie, Jiajun Zhang, Yajun Zhang, Jingyu Xu, Xing Wang, Chuanyin Xiong   +9 more
wiley   +1 more source

Bio‐Inspired Sclerotization of Lignin: A Robust Adhesive for Photothermal Wood‐Based Panels

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A high‐performance lignin adhesive is engineered via an insect‐inspired sclerotization strategy involving oxidation and hyperbranched polymer grafting, overcoming lignin's adhesion failure, and yielding a wet shear strength of 1.02–1.21 MPa. The adhesive endows wood‐based panels with photothermal functionality; building energy simulations indicate HVAC‐
Zihao Ye, Zheng Liu, Jiahao Wu, Canling Wen, Tingting Xie, Yonggang Chen, Chusheng Qi, Pingan Song, Qiang Gao   +8 more
wiley   +1 more source

High‐Strength, Fluorescent, Triboelectric Cellulose Hydrogel‐Derived Plastics Through Molecular Network Engineering for Energy Harvesting and Motion Sensing

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Multifunctional cellulose hydrogel‐derived plastics (FCBPs) are fabricated via a novel molecular network engineering strategy involving epoxy cross‐linking, solvent exchange, and hot‐pressing techniques. The resulting materials exhibit high mechanical strength, excellent thermal/solvent resistance, stable fluorescence, complete biodegradability, and ...
Fuyuan Lu, Yifan Jiao, Yuxuan Chen, Zhezhe Zhou, Gaobo Lou, Caicai Li, Gaojie Jiao, Mark Lynch, Jialong Wen, Xiaochun Zhang, Pingan Song, Dan Sun   +11 more
wiley   +1 more source

Sustainable Iron Catalysis for Chemodivergent Oxidation of Lignin‐Based Vanillyl Alcohol: Selective Access to Vanillin and Vanillic Acid

European Journal of Organic Chemistry, EarlyView.
Green reaction media enable chemodivergent oxidation of vanillyl alcohol, selectively affording vanillin or its fully oxidized counterpart, vanillic acid. The use of an earth‐abundant, inexpensive, and nontoxic iron catalyst for the transformation of lignin‐derived alcohol to fine chemicals underscores the sustainability of the process. A low E‐factor (
Rasmiranjan Hota, Chinmaya Kumar Meher, Bidraha Bagh   +2 more
wiley   +1 more source

Chemoselective Aldehyde and Imine Reduction by a Macrocyclic Triazole–Borane Complex Triggered by a Non‐innocent Proton–Hydride Interaction

European Journal of Organic Chemistry, EarlyView.
This work describes the study on a new recyclable reagent, based on a macrocyclic triazole–borane complex. It showed high chemoselectivity for aldehyde reduction and reductive amination over ketones. This selectivity is driven by a noncovalent hydride–proton interaction that stabilizes the transition state for aldehydes but is sterically inhibited in ...
Luca Di Marino, Artur Brotons Rufes, Rosaria Schettini, Giorgio Della Sala, Francesco De Riccardis, Chiara Costabile, Irene Izzo   +6 more
wiley   +1 more source