Toward the True Second Law Part I: The Flaws in Clausius’ Second Law Thermodynamics
José Iñiguez
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Thiosulfonate‐Derived BODIPY “Stick and Glue” Strategy for Fluorescent Thiol Labeling
We present a powerful photochemical strategy for converting disulfide bonds into stable thioether linkages via a [1,2]‐sigmatropic rearrangement. By integrating this reaction into traditional methanethiosulfonate‐based thiol labeling, we enable light‐triggered stabilization of peptide and protein conjugates with enhanced robustness and versatility ...
Lucie Šálková +4 more
wiley +1 more source
Towards Pragmatist Thermodynamics: An Essay on the Natural Philosophy of Entropy and Sustainability. [PDF]
Herrmann-Pillath C.
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Plasmonic Hot‐Carrier Redox Enables Proton‐Coupled Electron Transfer at C─H Bonds
Plasmonic hot carriers provide unprecedented control over coupled electron–proton transfer, enabling visible‐light activation of strong C─H bonds. Using an energy‐filter electrode, we reveal a stepwise electron‐then‐proton pathway and directly tune the underlying driving forces.
Daniel Velev Latchev +3 more
wiley +1 more source
Accumulation Function for the Ideal Air-Standard Brayton Cycle Based on Serrin's Thermodynamics. [PDF]
Sanchez-Sanchez VAJ, Quinto Diez P.
europepmc +1 more source
Black hole thermodynamics at null infinity. Part 1: Dual Generalized Second Law
Antoine Rignon-Bret, Matthieu Vilatte
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Molar Heat Capacity for Graphical Pedagogy Applied to Heat Engines, Refrigerators, and Heat Pumps Driven by Chemical Change. [PDF]
Martin ST.
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The Knudsen Layer in the Heat Transport Beyond the Fourier Law: Application to the Wave Propagation at Nanoscale. [PDF]
Carlomagno I, Sellitto A.
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A Pedagogical Reinforcement of the Ideal (Hard Sphere) Gas Using a Lattice Model: From Quantized Volume to Mechanical Equilibrium. [PDF]
de Miguel R.
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