Results 71 to 80 of about 177,691 (298)

Mesoporous Carbon Thin Films with Large Mesopores as Model Material for Electrochemical Applications

open access: yesAdvanced Functional Materials, EarlyView.
Mesoporous carbon thin films possessing 70 nm mesopores are prepared on titanium substrates by soft templating of resol resins with a self‐synthesized poly(ethylene oxide)‐block‐poly(hexyl acrylate) block copolymer. A strategy to avoid corrosion of the metal substrate is presented, and the films are extensively characterized in terms of morphology ...
Lysander Q. Wagner   +9 more
wiley   +1 more source

Thermodynamics in Modified Gravity with Curvature Matter Coupling

open access: yesAdvances in High Energy Physics, 2013
The first and generalized second laws of thermodynamics are studied in f(R,Lm) gravity, a more general modified theory with curvature matter coupling. It is found that one can translate the Friedmann equations to the form of first law accompanied with ...
M. Sharif, M. Zubair
doaj   +1 more source

Atomic‐Level Dual‐Cation Engineering Enables High‐Performance Na4VMn(PO4)3 Cathodes for Sodium‐Ion Batteries

open access: yesAdvanced Functional Materials, EarlyView.
Dual‐cation site engineering unlocks stable and fast sodium storage in Na4VMn(PO4)3 cathodes. Li+ at Na2 suppresses Jahn‐Teller distortion, while K+ at Na1 expands ion channels, enabling synchronized V/Mn redox and quasi‐single‐phase kinetics. This atomic‐level strategy achieves ultralong cycling stability, high‐rate capability, and full cell viability
Jiaze Sun   +8 more
wiley   +1 more source

Clausius’ Disgregation: A Conceptual Relic that Sheds Light on the Second Law

open access: yesEntropy, 2015
The present work analyzes the cognitive process that led Clausius towards the translation of the Second Law of Thermodynamics into mathematical expressions.
Emilio Marco Pellegrino   +2 more
doaj   +1 more source

Hamiltonian Derivations of the Generalized Jarzynski Equalities under Feedback Control

open access: yes, 2011
In the presence of feedback control by "Maxwell's demon," the second law of thermodynamics and the nonequilibrium equalities such as the Jarzynski equality need to be generalized.
Abreu D   +6 more
core   +1 more source

Biomimetic Ion‐Orchestrated Hierarchical Armored Hydrogel Coating for Robust and Multifunctional Surface Protection

open access: yesAdvanced Functional Materials, EarlyView.
Inspired by the skin‐toughening mechanism of marine sponges, an ion‐orchestrated structural engineering strategy is proposed to regulate the surface microstructure of hydrogel coatings, enabling the in situ formation of a robust armor layer that enhances mechanical integrity and provides multifunctional protection by suppressing fouling attachment and ...
Wenshuai Yang   +11 more
wiley   +1 more source

Enhanced Nitric Oxide Electroreduction to Ammonia via Modulating Spin‐Polarization of Fe Single‐Atom Catalysts

open access: yesAdvanced Functional Materials, EarlyView.
A strategic spin‐polarization suppression in Fe single‐atom catalysts is proposed to enhance electrocatalytic reduction of NO to NH3. Employing a top‐down electrospinning strategy, self‐supported FeSAC with Fe‐N3S1 coordination structure and spin‐state transition is engineered from high‐spin to low‐spin.
Jialing Song   +13 more
wiley   +1 more source

Unified Classical Thermodynamics: Primacy of Dissymmetry over Free Energy

open access: yesThermo
In thermodynamic theory, free energy (i.e., available energy) is the concept facilitating the combined applications of the theory’s two fundamental laws, the first and the second laws of thermodynamics.
Lin-Shu Wang
doaj   +1 more source

Silver Ion‐Mediated [hk1]‐Oriented Sb2Se3 Crystal Growth for Efficient Photoelectrochemical Hydrogen Evolution

open access: yesAdvanced Functional Materials, EarlyView.
Ag+‐mediated hydrothermal crystal engineering promotes preferential [hk1]‐oriented growth of Sb2Se3 via an ultrathin MoOx interlayer, improving crystallinity and suppressing non‐radiative recombination. The optimized Ag+ treatment photocathode delivers 24.7 mA cm−2 at 0 VRHE and improved stability, revealing an ion‐modulated route to high‐performance ...
Ziying Zhang   +10 more
wiley   +1 more source

Generalized second law of thermodynamics in massive gravity

open access: yesEuropean Physical Journal C: Particles and Fields
Here, we study the generalized second law (GSL) of thermodynamics in the framework of massive gravity. To do this, we consider a FRW universe filled only with matter and enclosed by the apparent horizon.
Mohammad Beigmohammadi, Kayoomars Karami
doaj   +1 more source

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