Electron‐Deficient Linkers Enhance H2O2 Electrosynthesis in Covalent Organic Frameworks
Linker π‐conjugation modulates the electronic state of the Ni–N4 centers and their interaction with the key *OOH intermediate while preserving the primary coordination motif. NiPc‐PTDA delivers an H2O2 selectivity of 92% and a production rate of 34.8 mol gcat−1 h−1, highlighting linker electronic properties as a molecular design parameter for NiPc ...
Houting Xie +7 more
wiley +1 more source
Dataset of the palaeozoic (Carboniferous - Permian) Kinta Limestone Pinnacles in Kampar, Perak, Malaysia. [PDF]
Khor WC +4 more
europepmc +1 more source
Ground‐State Charge‐Transfer Doping in Donor–Acceptor Semiconducting Polymers
This work demonstrates controlled ground‐state charge‐transfer complex formation (GS‐CTC) and doping in a series of diketopyrrolopyrrole‐based donor–acceptor semiconducting polymers paired with a π‐conjugated penta‐t‐butylpentacyanopentabenzo[25]annulene “cyanostar” macrocycle. Complementary experimental techniques show how subtle molecular, electronic,
Tanner L. Smith +13 more
wiley +1 more source
Viral architects of the deep biosphere: reshaping the framework of sedimentary biogeochemistry. [PDF]
Wang C, Sun C.
europepmc +1 more source
An Alhagi maurorum inspired hierarchical composite membrane (NFCu) was developed by integrating heavy metal remediation and solar‐driven interfacial evaporation in a single platform. Beyond the photothermal effect, a localized photocatalytic process is realized on the CuO surface, deepening the mechanistic understanding of light–matter–water ...
Yuqiong He +9 more
wiley +1 more source
Red to Green: A Lipid Biomarker Record of Tonian-Ediacaran Algae in Siberia. [PDF]
Rizzo AI +7 more
europepmc +1 more source
We investigate size‐dependent CO selectivity on Ag nanoparticles, where optimized Ag loading achieves nearly 100% Faradaic Efficiency for CO at −100 mA·cm−2. In situ SERS and XPS reveal the crucial role of optimized loading in catalytic performance. The Ag/C catalyst further exhibits bifunctional activity, enabling efficient electrolysis of CO2 and ...
Venkata S. R. K. Tandava +16 more
wiley +1 more source
Nitrogen Isotopic Composition of Crude Oils from the Dongpu Depression, Bohai Bay Basin, Eastern China: Implications for Sedimentary Redox Conditions and Oil-Source Correlation. [PDF]
Chen J +6 more
europepmc +1 more source
Inspired by metal‐free carbonic anhydrases (CAs) that achieve efficient catalysis without metal cofactors, we herein report a sequence‐defined supramolecular peptoid platform that mimics metal‐free CAs and exhibits hydrolytic activity via a supramolecular assembly‐mediated proton‐transfer mechanism.
Progyateg Chakma +8 more
wiley +1 more source
Characterization of Hydrocarbon Molecular Signatures across Sedimentary Subbasins and Stratigraphic Units: Insights into Source Rock Attributes in Kansas. [PDF]
Omoyemi OV +4 more
europepmc +1 more source

