Results 211 to 220 of about 1,139,197 (299)

CO‐Adsorption on MgO Revisited: Polarization‐Resolved Identification of Step Edges as the Dominant Defects on MgO(100) and MgO(110)

open access: yesAngewandte Chemie International Edition, EarlyView.
By combining polarization‐resolved IRRAS with hybrid HSE06 DFT calculations, we establish site‐specific vibrational fingerprints, adsorption geometries, and binding energies for CO on wide‐band‐gap MgO surfaces. Low‐coordinated Mg4c2+ step‐edge sites, rather than terrace Schottky defects, are identified as the dominant binding and reactive sites, with ...
Wangtao Li   +9 more
wiley   +1 more source

Automated Spin‐Assisted Layer‐by‐Layer Epitaxy Produces Highly Oriented Mixed‐Linker MOF Thin Films

open access: yesAngewandte Chemie International Edition, EarlyView.
An automated spin‐assisted layer‐by‐layer growth method enables rapid fabrication of highly oriented Zn2BDC2DABCO metal‐organic framework thin films under ambient conditions. Correlative characterization confirms excellent reproducibility, uniform film formation, and exceptional out‐of‐plane orientation exceeding 85%.
Eleonora Afanasenko   +13 more
wiley   +1 more source

Hierarchical Membrane for Photoelectrostatically Gated Monovalent‐Divalent Ion Separation

open access: yesAngewandte Chemie International Edition, EarlyView.
We report a hierarchical poly(ionic liquid)–carbon nitride membrane supported on anodic alumina for efficient monovalent/divalent ion separation. Confined nanochannels and tailored interfacial ion interactions enable exceptional K+/Mg2+ ( > 500) and Li+/Mg2+ ( > 200) selectivities, offering a promising strategy for advanced aqueous ion separations ...
Enis Oğuzhan Eren   +3 more
wiley   +1 more source

Forage selection of dairy cows grazing contrasting multispecies swards is influenced by cow characteristics. [PDF]

open access: yesVet Anim Sci
Dittmann MT   +6 more
europepmc   +1 more source

Tracheal chambers as a key innovation for high‐frequency emission in bat echolocation

open access: yesThe Anatomical Record, EarlyView.
Abstract Key innovations are pivotal for biodiversity and facilitating evolutionary success, enabling organisms' adaptation to various ecological niches through the diversification of phenotypic traits. In mammals, notable adaptations include evolving hypsodonty for grazing on grasses and, for bats, evolving echolocation and wing acquisition.
Nicolas L. M. Brualla   +7 more
wiley   +1 more source

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