A custom-designed series of unsymmetrical spiroalkanedithiols having tailgroups comprised of a terminally fluorinated chain and a hydrocarbon chain of varying lengths were synthesized and used to prepare self-assembled monolayers (SAMs) on gold ...
Pawilai Chinwangso +3 more
doaj +1 more source
Formation and removal of alkylthiolate self-assembled monolayers on gold in aqueous solutions [PDF]
We report the development of novel reagents and approaches for generating recyclable biosensors. The use of aqueous media for the formation of protein binding alkylthiolate monolayers on Au surfaces results in accelerated alkylthiolate monolayer ...
Canaria, Christie A. +7 more
core +1 more source
Study of the ability of self-assembled N-vinylcarbazole monolayers to protect copper against corrosion [PDF]
N-Vinylcarbazole (NVC) monolayers were self-assembled on copper surfaces. The electrochemical properties of the copper surfaces modified by NVC self-assembled monolayers (SAMs) were investigated using polarization and electrochemical impedance ...
NAI-XING WANG +4 more
doaj
Channel-forming activity of syringopeptin 25 A in mercury-supported phospholipid monolayers and negatively charged bilayers [PDF]
Interactions of the cationic lipodepsipeptide syringopeptin 25 A (SP25A) with mercury-supported dioleoylphosphatidylcholine (DOPC), dioleoylphosphatidylserine (DOPS) and dioeleoylphosphatidic acid (DOPA) self-assembled monolayers (SAMs) were investigated
Becucci, Lucia +4 more
core +2 more sources
Self-assembled monolayers (SAMs) have shown tremendous number of applications but can suffer from low stability. Here, the authors report air and bench stable carbene precursors allowing facile SAM formation, and furthermore demonstrate an application in
Cathleen M. Crudden +17 more
doaj +1 more source
From Monomers to Self-Assembled Monolayers: The Evolution of Molecular Mobility with Structural Confinements [PDF]
The effect of structural constriction on molecular mobility is investigated by broadband dielectric spectroscopy (BDS) within three types of molecular arrangements: monomers, oligomers and self-assembled monolayers (SAMs).
Chen, Ziguang +7 more
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Precise surface area is needed for accurate characterization of self-assembled monolayers (SAMs) on metallic surfaces. The aim of this manuscript was to emphasize that miscalculation of surface area is the major source of errors in SAM electrochemical ...
Tiago A. Benites +4 more
doaj +1 more source
Controlling Leakage of Potential Juxtacrine Self-Assembled Monolayer-BMP-2 Surfaces
A question which has been intriguing researchers since 1969 is whether covalently linked hormones or growth factors on surfaces are still biologically active i.e. still bind and activate cell surface receptors in the insoluble state. There is evidence of
Holtkamp Julia, Jennissen H. P.
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Conformations and charge transport characteristics of biphenyldithiol self-assembled-monolayer molecular electronic devices: A multiscale computational study [PDF]
We report a computational study of conformations and charge transport characteristics of biphenyldithiol (BPDT) monolayers in the (sqrt(3)×sqrt(3))R30° packing ratio sandwiched between Au(111) electrodes. From force-field molecular-dynamics and annealing
Goddard, William A., III +2 more
core +2 more sources
Lactone-Terminated Self-Assembled Monolayers for Mimicking Nanoscale Polyester Surfaces
Two series of lactone-terminated alkanethiol adsorbates with five- and six-membered lactone groups, γ-COCnSH and δ-COCnSH (n = 11, 12), were synthesized and employed to create nanoscale self-assembled monolayers (SAMs) on gold substrates to mimic the ...
Pooria Tajalli +5 more
doaj +1 more source

