Results 171 to 180 of about 9,530 (292)

Modular Rh‐Catalyzed Synthesis and Biological Profiling of Diverse Pentafluorobenzenesulfonamide Reactive Fragments

Chemistry – A European Journal, EarlyView.
A modular Rh‐catalyzed synthetic approach enabled the preparation of diverse reactive fragments from available substrates. The reactive fragments modified Aurora A kinase via several distinct modification reaction classes. In a complex biological environment, the constellation of modified proteins depended critically on the reactive fragment structure.
Julian Chesti, Jennifer A. Miles, George J. Wade, Scott Grossman, George W. Preston, Richard Bayliss, Stuart L. Warriner, Megan H. Wright, Adam Nelson   +8 more
wiley   +1 more source

Low‐Temperature Initiation Enhances HCN and NH3 Formation From Methane and NO Over Pt/Al2O3

Chemistry – A European Journal, EarlyView.
Hydrogen cyanide (HCN) was formed from CH4 and NO over Pt/Al2O3 at low temperatures. Increasing NO concentration and optimizing reaction‐start conditions significantly enhanced HCN yield. In situ FTIR and DXAFS measurements revealed that dynamically balancing Pt‑CO and Pt‑CN surface species, particularly their desorption under temperature‑swing ...
Emika Yamashita, Kyoko K. Bando, Toshitaka Kubo, Atsushi Takagaki   +3 more
wiley   +1 more source

Alkali‐Metal Base Catalyzed Electrocyclization of Isoprene Derivatives

Chemistry – A European Journal, EarlyView.
Simple and abundant alkali‐metal base catalysis in combination with Lewis basic polyamines enables the electrocyclization of isoprene‐derived trienes to cycloheptadienes under neat conditions. Mechanistic insight supported by DFT guides a scalable route to seven‐membered carbocycles which, after reduction, give saturated cycloalkanes relevant as ...
Mikaël Le Roch, Krzysztof Piech, Aurélien Crochet, Andreu Tortajada   +3 more
wiley   +1 more source

Influence of Particle Size, Moisture, and Cloud Density on Wood Dust Ignition

Chemie Ingenieur Technik, EarlyView.
The ignition and combustion of particle clouds are strongly affected by particle interactions. This study uses spectroscopy to examine effects of particle size, water content, and cloud density. Results show ignition delay rises with larger size and density, whereas combustion duration depends mainly on water and density due to moisture‐driven ...
Matteo Giesen, Daniel Bernhardt, Michael Beckmann   +2 more
wiley   +1 more source

Microplastics and nanoplastics in water: Improving removal in wastewater treatment plants with alternative coagulants

The Canadian Journal of Chemical Engineering, EarlyView.
The contaminant removal performance of a conventional coagulant, alum, and alternative coagulants, aluminium chlorohydrate (ACH) and ACH + pDADMC, are compared in challenging wastewater treatment conditions (pH >7.8). The interactions of each coagulant with a negatively charged surface are depicted based on quartz crystal microbalance with dissipation ...
Sinan Abi Farraj, Mathieu Lapointe, Rafael S. Kurusu, Nathalie Tufenkji   +3 more
wiley   +1 more source

Online SIFT-MS measurement of a biofilter response to dimethylsulfide concentration step changes [PDF]

, 2013
Heynderickx, Philippe, Van Langenhove, Herman, Volckaert, Diego   +2 more
core  

Xylose Acetals ‐ a New Class of Sustainable Solvents and Their Application in Enzymatic Polycondensation

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
Novel organic solvents with an unmodified carbohydrate core were synthesised both from D‐xylose and directly from biomass and were successfully used as reaction media for lipase biocatalysts to synthesise aliphatic and aromatic polyesters. Abstract The use of organic solvents in academic research and industry applications is facing increasing ...
Anastasia O. Komarova, Cicely M. Warne, Hugo Pétremand, Laura König‐Mattern, Johannes Stöckelmaier, Chris Oostenbrink, Georg M. Guebitz, Jeremy Luterbacher, Alessandro Pellis   +8 more
wiley   +1 more source

Stabilization of Pd Active Sites by Defective NaY Zeolite Framework for Enhanced Stability in Dimethyl Carbonate Synthesis

EcoEnergy, EarlyView.
A tailored‐defect strategy employing sequential high‐temperature calcination and acetylacetone treatment was developed to generate framework defects in NaY zeolite while preventing the formation of strong acid sites. These defects facilitate electron transfer from Pd to the zeolite framework and stabilize the Pd2+ active sites, thereby conferring ...
Chunzheng Wang, Rongyan Mei, Shicheng Yuan, Yida Zhou, Yipu Xu, Xianglong Meng, Longgang Tao, Shutao Xu, Hailing Guo, Svetlana Mintova   +9 more
wiley   +1 more source

Gold(I) Phosphine/Phosphido‐Borohydride Complexes

European Journal of Inorganic Chemistry, EarlyView.
Synthesis, structure, and electrochemical characteristics of a homologous series of gold(I) complexes featuring phosphine and phosphido–borohydride ligands. A homologous series of linear, mononuclear gold(I) phosphine/phosphido‐borohydride complexes, encompassing [Au(PR3)2]+ 1, [Au(PR3)(PR2BH3)] 2 and [Au(PR2BH3)2]– 3 (R = tBu, Ad), has been prepared ...
Matthew J. G. Sinclair, Marc‐Etienne Moret, Luke A. Wilkinson, Adrian B. Chaplin   +3 more
wiley   +1 more source

Phenolate‐ and Alcoholate‐Based Chromium N‐Heterocyclic Carbene Complexes: Structural Peculiarities, Magnetometric and Electron Paramagnetic Resonance Study, and Catalytic Ethylene Oligomerization

European Journal of Inorganic Chemistry, EarlyView.
The first low‐oxidation (I/III) state chromium‐complex bearing a O‐chelating NHC ligand has been synthesized and structurally characterized by single‐crystal X‐ray analysis. The formation of the mixed‐valence species was further supported by SQUID magnetometry and high‐field electron paramagnetic resonance (EPR) spectroscopy.
Somnath Bhattacharya, Alexander Allgaier, Wolfgang Frey, Joris van Slageren, Michael R. Buchmeiser   +4 more
wiley   +1 more source