Results 111 to 120 of about 493 (208)

Water, Alcohols, Amines, and Amides as Formal Hydrogen‐Atom‐Transfer Reagents Through Activation With Redox‐Active Lewis Acids

Angewandte Chemie, EarlyView.
Protic molecules containing strong O─H or N─H bonds typically resist hydrogen‐atom abstraction because of the high reactivity of the resulting heteroatom‐centered radicals. However, association of the protic molecules with redox‐active Lewis acids can provide powerful hydrogen‐atom donors or proton‐coupled‐electron‐transfer reagents.
Petra Vojáčková, Armido Studer
wiley   +2 more sources

Borylcyclopropanes: Synthetic Strategies and Applications

Angewandte Chemie, EarlyView.
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley   +2 more sources

Unified Synthesis of Unconventional α‐Polyhalogenated Amines Through Hydroaminoalkylation

Angewandte Chemie International Edition, EarlyView.
A unified, redox‐neutral method that transforms alkenes and alkynes into α‐polyhalomethyl amines using stable hemiaminal reagents is reported. This approach enables access to CF3, CF2H, CF2Cl, and CFClH motifs, expanding halogenated amine space with broad substrate scope, functional group tolerance, and applicability to late‐stage modification of drug ...
Angela K. Hofmeister, Giulia Iannelli, Péter Angyal, Augustin Malandain, Daniel Kaiser, Boris Maryasin, Hanspeter Kählig, Matteo Barel, Gaia Novarino, Nuno Maulide   +9 more
wiley   +1 more source

Synthesis of a Novel Amine‐Based Curing Agent for Epoxy Resins Derived From Vanillin

Journal of Applied Polymer Science, EarlyView.
The four‐step synthesis of a new bio‐based amine hardener is described starting from vanillin as a bio‐based compound. The hardener ADBA was utilized to cure DGEBA and the resulting Tg,tanδmax was determined via DMA. Compared to other bio‐based curing agents, our curing agent is obtainable in a high yield and leads to a superior Tg of 135°C.
Bastian Hahn, Gerd Wehnert, Elisabeth Schamel, Dominik Söthje   +3 more
wiley   +1 more source

Wood Sawdust as a Low‐Cost Filler in Whole‐Tire Reclaimed Rubber: Mechanical Characterization and Factory‐Scale Cost Analysis

Journal of Applied Polymer Science, EarlyView.
Whole‐tire reclaimed rubber is upgraded with wood sawdust, a carpentry by‐product available at no cost, across loadings from 0 to 20 wt%. At 5 wt%, tensile strength, elongation, hardness, viscosity, and water absorption all stay within commercial specification, and real factory data show an annual production saving near $62,000 with no capital ...
Mohammed S. Matar, Faris Tarlochan, Sami E. Alkhatib, Abdullah Abdelhamid   +3 more
wiley   +1 more source

Morphological and morphometric aspects of the equine aortic valve: New insights for comparative studies in mammals

The Anatomical Record, EarlyView.
Abstract New data on the equine aortic valve obtained using advanced techniques is especially important given the greater availability of animal models for translational research. Here we characterized the morphological and morphometric aspects of the equine aortic valve from 60 healthy hearts collected at equine abattoirs.
Vitor Pires Pereira, Victoria Brondani de Oliveira, Carlos Eduardo Seyfert, Luciano de Morais‐Pinto   +3 more
wiley   +1 more source

Shape‐directed formation of T8/T6 Zn–siloxane clusters and their deep‐UV shielding properties

Bulletin of the Korean Chemical Society, EarlyView.
The shape and conformational characteristics of silane substituents direct the assembly of Zn–siloxane clusters into conventional T8 or rare T6 siloxane frameworks. Non‐planar cyclic substituents selectively promote T6 formation through steric effects, while the resulting clusters exhibit deep‐ultraviolet absorption and can be processed into ...
Dopil Kim, Min Jeong Park, Purna Chandra Rao, Younghu Son, Sung Hwa Jhung, Minyoung Yoon   +5 more
wiley   +1 more source

Takeover Vulnerability and the Discipline of ESG Overinvestment

Business Strategy and the Environment, EarlyView.
ABSTRACT While takeovers serve a disciplinary role by replacing inefficient managers, the threat of takeovers may compel firms to divert attention from Environmental, Social and Governance (ESG) efforts as a strategic response to external pressure, especially when such firms are already overinvesting in ESG.
Abongeh Tunyi, Ruth O. Sagay, Reon Matemane   +2 more
wiley   +1 more source

Strategic Shift: The Power of Green Strategy on Sustainability Performance

Business Strategy and the Environment, EarlyView.
ABSTRACT Employing FTSE Russell's unique Green Revenues data on S&P 1500 firms from 2016 to 2024, this study examines the long‐term effects of a corporate strategic shift toward green strategy, proxied by green revenue reporting, on corporate sustainability performance.
Post Raj Pokharel
wiley   +1 more source

Supply Chain Network, ESG Scores and Financial Performance

Business Strategy and the Environment, EarlyView.
ABSTRACT This paper provides novel evidence on the role of supply chain networks in influencing firms' environmental, social and governance (ESG) scores and financial performance. Our analysis employs financial, board, ESG and supply chain data, resulting in an unbalanced panel of over 16,000 firm‐year observations from 3028 publicly traded US firms ...
Michail Filippidis, Renatas Kizys, Panagiotis Tzouvanas   +2 more
wiley   +1 more source