Results 191 to 200 of about 19,865 (266)

Catalyst‐Free Selective Reduction of Nitrogen Dioxide to Nitric Oxide

Chemistry – A European Journal, EarlyView.
Common main group reductants selectively convert nitrogen dioxide to nitric oxide in a catalyst‐free manner. Computational studies suggest divergent reaction pathways depending on the reductant employed. Where boranes and silanes proceed via a two‐electron process, and hydrogen surrogates undergo stepwise one‐electron processes.
Awais W. Seyyad, Agamemnon E. Crumpton, Reece Lister‐Roberts, Meera Mehta   +3 more
wiley   +1 more source

Hydrosilylation of a Molecular Molybdenum Nitride Provides Mechanistic Insights into Photodriven Ammonia Synthesis from N₂ and H₂. [PDF]

J Am Chem Soc
Kim J, Kaul N, Pecoraro MV, Chirik PJ.
europepmc   +1 more source

Azidophosphonamido Rhodium(I) and Iridium(I) Complexes: Synthesis, Properties, and Linkage Isomerism

Chemistry – A European Journal, EarlyView.
A family of azidophosphonamido ligands and their corresponding rhodium(I) and iridium(I) complexes were synthesized. The rich reaction chemistry of these species revealed unusual linkage isomerization processes and bonding motifs. M = Rh, Ir; Mes = 2,4,6‐Me3C6H2. ABSTRACT A series of azidophosphonamido rhodium(I) and iridium(I) complexes ([iPr2P(N3R)NR]
Emily L. Trew, Daisy E. Cruz‐Milette, Douglas Turnbull, Paul G. Hayes   +3 more
wiley   +1 more source

State-of-the-Art and Synthetic Challenges for Hydrosilane Production. [PDF]

Chemistry
Durin G, Fontaine A, Berthet JC, Cantat T.   +3 more
europepmc   +1 more source

Germylium Catalyzed Dehydrofluorination Reactions of Fluorinated Alkanes

Chemistry – A European Journal, EarlyView.
Dehydrofluorination reactions of fluorinated alkanes catalyzed by germylium ions are reported. Computational studies of the mechanism revealed an E2 type mechanism involving a germane as a base to facilitate olefin formation in competition with an SN2 mechanism for hydrodefluorination.
Julie Borel, Morten Lehmann, Martin Kaupp, Thomas Braun   +3 more
wiley   +1 more source

Catalytic Enantioselective Cross-Nucleophile Coupling via Valence Tautomerism. [PDF]

J Am Chem Soc
Zhang Z, Khosravi A, Shah JA, Quirion KP, Yachuw SC, Poore AT, Tian S, Liu P, Ngai MY.   +8 more
europepmc   +1 more source

Stereochemical Control in the Matteson Reaction

Chemistry – A European Journal, EarlyView.
The Matteson homologation is a highly versatile method for the stereoselective insertion of carbenoids into boronic esters. Through iterative application of the process, complex chiral molecules can be synthesized. The stereoselectivity of the reaction is determined by a chiral diol incorporated in the boronic ester.
Hae Mo Lee, Christoph Hirschhäuser
wiley   +1 more source

Microstructural and Surface Energy Evaluation of Concrete Coatings Modified with Methyl Ester and Stearic Acid. [PDF]

Materials (Basel)
Hunek R, Janek M, Franus W.
europepmc   +1 more source

Development of Second-Generation Acyl Silane Photoaffinity Probes for Cellular Chemoproteomic Profiling. [PDF]

ACS Chem Biol
Page ACS, Orr LM, Meyers ML, Belcher BP, Coffey TG, Scholz SO, Cismoski S, Nomura DK, Toste FD.   +8 more
europepmc   +1 more source

A Mini Review on CO₂ Capture and Separation Using Nanocellulose-Based Scaffolds. [PDF]

Polymers (Basel)
Sharma P.
europepmc   +1 more source