Results 111 to 120 of about 10,737 (209)

Oxidative Generation and Reactivity of the Cyclopropyl Radical From a Martin Silicate

Chemistry – A European Journal, EarlyView.
A photoredox strategy employing Martin silicates enables the oxidative generation and controlled capture of cyclopropyl radicals, including the naked one, long considered challenging intermediates. The method affords functionalized cyclopropanes through both Giese‐type additions and dual nickel/photoredox C(sp3)−C(sp2) cross‐couplings.
Amal Lakhal, Alexandre Millanvois, Louis Fensterbank, Cyril Ollivier   +3 more
wiley   +1 more source

Multivalent RNA‐Cleaving Agents on a Cubic Octameric Silsesquioxane Core

Chemistry – A European Journal, EarlyView.
RNA‐cleaving agents on a cubic octameric silsesquioxane core were synthesized and characterized. Several catalytic systems of these structures were screened using hexaribonucleotide models. The best systems were then further used to study their catalytic efficiency in cleaving a HER2 mRNA model sequence. The induced cleavage sites were also determined.
Hanni Haapsaari, Iris Tuomi, Pasi Virta
wiley   +1 more source

Peroxodisulfate‐Enhanced Leaching of Deep‐Sea Manganese Crusts and Sulfides

Chemie Ingenieur Technik, EarlyView.
Ammonium peroxodisulfate enables efficient leaching of deep‐sea manganese crusts and massive sulfides while offering electrolytic recycling. High leaching yields for V, Mn, Co, Mo, Sn, and W, along with complete leaching of As and Sb, highlight its potential as a powerful and sustainable oxidant for marine resource processing.
Bastian Hansel, Lucas Thumeyer, Ebbe H. Hartz, Håvard Hallås Stubseid, Peter Fröhlich, Martin Bertau   +5 more
wiley   +1 more source

Green and sustainable synthesis of magnetite from copper slag via citrate complexation for methylene blue dye removal from water

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract This study proposes a novel, green, and sustainable method for synthesizing magnetic iron oxides from metallurgical copper slag (CS), leveraging its iron content as a valuable resource. Iron was extracted via acid leaching using edible citric acid (ECA), forming a citrate–iron complex (CSL), which was subsequently thermally decomposed at 300°C
Melisa Portilla‐Sangabriel, Karen Valencia García, Tania‐Ariadna García‐Mejía, Agileo Hernández‐Gordillo, Rosa‐María Ramírez‐Zamora   +4 more
wiley   +1 more source

Feasibility Study of Basic Steel Slag as Anode of Li‐Ion Batteries

CleanMat, EarlyView.
This study presents a low‐cost, eco‐friendly approach to utilize basic steel slag as a sustainable anode for lithium‐ion batteries, demonstrating good cyclic stability, rate capability, and long‐term electrochemical performance. ABSTRACT The elevated expenses and utilization of hazardous chemicals in traditional chemical synthesis of anode materials of
Rudra Barua, Konok Chandra Bhowmik, Md. Arafat Rahman   +2 more
wiley   +1 more source

Magnetic Supraparticles as Identifiers in Single‐Layer Lithium‐Ion Battery Pouch Cells

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
As an alternative to externally applied optical identifiers, magnetic supraparticles (SPs) can be used for contactless identification of lithium‐ion battery pouch cells via magnetic particle spectroscopy. This study validated the integration and detection of magnetic markers in three model scenarios.
Sara Li Deuso, Simon Ziegler, Daniel Weber, Felix Breuer, Daniel Haddad, Stephan Müssig, Andreas Flegler, Guinevere A. Giffin, Karl Mandel   +8 more
wiley   +1 more source

Perceived importance and didactic difficulty of chemistry education: Insights from Czech teachers

The Curriculum Journal, EarlyView.
Abstract This empirical study examines how chemistry teachers in lower and upper secondary schools in the Czech Republic evaluate the content of the chemistry curriculum, focussing on its perceived importance and didactic difficulty. Based on a quantitative survey (N = 146), the study provides insight into the pedagogical content knowledge of ...
Jitka Lorenzová, Blanka Jirkovská, Martin Čapek Adamec, Jan Havlík, Petr Holzhauser, Daniela Nováková, Karel Němejc   +6 more
wiley   +1 more source

Surface hydration‐induced damage in tight oil‐bearing sandy conglomerate reservoirs

Deep Underground Science and Engineering, EarlyView.
A series of techniques such as X‐ray diffraction, scanning electron microscopy, energy‐dispersive spectroscopy, conductivity tests, and infrared thermal imaging were used. The key findings are the identification of a two‐stage surface hydration process and the elucidation of the effects of various minerals and elements on the hydration process ...
Anbang Zhao, Shuheng Du, Yuan Zhang, Jinghong Hu, Bo Zhou, Yun Wei   +5 more
wiley   +1 more source

Study on the composite fracture characteristics of filling and reinforcing cracked rock mass after high temperature damage

Deep Underground Science and Engineering, EarlyView.
Cement infill shares compressive and shear stresses during loading, while interfacial friction hinders crack propagation and reduces stress concentration, improving the rock's load‐bearing capacity. Failure modes vary with crack inclination. Unfilled specimens show four modes.
Shihao Yuan, Qiang Sun, Jianjun Hu, Liwei Zhang, Jishi Geng   +4 more
wiley   +1 more source

Research progress and current status of dynamic wave propagation characteristics in rock mass: A review

Deep Underground Science and Engineering, EarlyView.
This review elucidates the velocity–dispersion–attenuation coupling mechanisms of wave propagation in rock masses, compares six representative models, and reveals how pressure, temperature, mineral composition, and anisotropy jointly control dynamic responses in complex geological media.
Jiajun Shu, Tao Li, Ruiqi Yuan, Yue Li, Bingni Wu, Bo Liu, Zhengding Deng, Galindo Rubén, Fausto Molina‐Gómez   +8 more
wiley   +1 more source