Results 151 to 160 of about 15,414 (260)

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

open access: yesChemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

Zr-Site Lewis Acidity Determines Terpenoid Reduction Selectivity. [PDF]

open access: yesACS Catal
Gołabek K   +5 more
europepmc   +1 more source

Two‐Step Synthesis of a Chiral Fluorinated Alcohol With Silica‐Supported Enzyme RrADH in Batch and Continuous Flow Mode

open access: yesChemistry – A European Journal, EarlyView.
A two‐step process was transferred from batch to flow mode for the synthesis of (R)‐2‐fluoro‐1‐phenylethanol as a benchmark, consisting of a decarboxylative fluorination in aqueous media, followed by an enantioselective biocatalytic reduction of the prochiral intermediate with RrADH immobilized on silica supraparticles.
Egzon Cermjani   +7 more
wiley   +1 more source

Particles exposures and sarcoidosis. [PDF]

open access: yesSarcoidosis Vasc Diffuse Lung Dis
Ghio AJ, Scott SA, Tilley SL.
europepmc   +1 more source

Boric Acid Post‐Modified [Al]ZSM‐5 Zeolites: Properties, Acidity, and Ethanol/Ethene Conversion

open access: yesChemistry – A European Journal, EarlyView.
The modification of MFI zeolites with boric acid leads to the formation of framework boron, unstable surface species, and unbound deposits. Relevant BAS for catalysis and access to pores are strongly reduced. The boric acid is removed upon converting C1 or C2 alcohols and ethene. ABSTRACT The effect of boric acid post‐modification on [Al]ZSM‐5 zeolites
Zheng Li   +3 more
wiley   +1 more source

Chemo‐Enzymatic Route for Covalent Cellulose Fiber Dyeing

open access: yesChemistry – A European Journal, EarlyView.
This work presents a proof of concept for a chemo‐enzymatic approach to the covalent dyeing of cotton fibers. Laccase/TEMPO oxidation introduces aldehyde groups, enabling subsequent reductive amination with amino dyes. Excellent color homogeneity and wash fastness were demonstrated using acid red 33, highlighting the robustness of the approach and its ...
Awilda Maccow   +6 more
wiley   +1 more source

Energy Landscapes in Chemical Reactions and Transport

open access: yesChemPhysChem, Volume 26, Issue 6, March 15, 2025.
Kinetics/dynamics of chemical reactivity and transport of chemical species in a solid are both determined by the energy landscape in which they take place. Discussing common grounds but also distinct differences may help in advancing the understanding in both fields.
Karl‐Michael Weitzel
wiley   +1 more source

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