Variable coordination of amine functionalised N-heterocyclic carbene ligands to Ru, Rh and Rr: C-H and N-H activation and catalytic transfer hydrogenation [PDF]
Chelating amine and amido complexes of late transition metals are highly valuable bifunctional catalysts in organic synthesis, but complexes of bidentate amine–NHC and amido–NHC ligands are scarce.
Arita +49 more
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Non-Cyanide Silver as a Substitute for Cyanide Processes [PDF]
Since the mid 1800s, silver has been deposited from a cyanide-based formulation on a commercial basis. Commercial non-cyanide silver plating solutions were first made generally available in the late 1970s, and yet today the vast majority, and nearly ...
Chicago Metal Finishers Institute
core
Photoinitiated oxidative addition of CF3I to gold(I) and facile aryl-CF3 reductive elimination. [PDF]
Herein we report the mechanism of oxidative addition of CF3I to Au(I), and remarkably fast Caryl-CF3 bond reductive elimination from Au(III) cations. CF3I undergoes a fast, formal oxidative addition to R3PAuR (R = Cy, R = 3,5-F2-C6H4, 4-F-C6H4, C6H5, 4 ...
TOSTE, F. Dean +2 more
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Facile Preparation of Silver Halide Nanoparticles as Visible Light Photocatalysts
In this study, highly efficient silver halide (AgX)-based photocatalysts were successfully fabricated using a facile and template-free direct-precipitation method. AgX nanoparticles, which included silver chloride (AgCl), silver bromide (AgBr) and silver
Linfan Cui +4 more
doaj +1 more source
Localized surface plasmon effects on the photophysics of perovskite thin films embedding metal nanoparticles [PDF]
Herein we provide direct experimental evidence that proves that the photophysical properties of thin methylammonium lead iodide perovskite films are significantly enhanced by localized surface plasmon resonances (SPRs). Observations are well supported by
Bayles, Aaron +5 more
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Iodine speciation in a silver-amended cementitious system
Silver-impregnated zeolite (AgIZ) has been used for removing radioiodine from contaminated groundwater and nuclear waste streams and the worldwide inventory of such secondary waste is rapidly increasing. The objective of this study was to 1) quantify the
Daniel I. Kaplan +11 more
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Method of inhibiting stress corrosion cracks in titanium alloys Patent [PDF]
Method to prevent stress corrosion cracking in titanium ...
Beck, T. R.
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Variations in β(T)-function due to addition of LiI-4AgI system
Impedance spectroscopy measurements of the LiI-4AgI samples, in the frequency range 20 Hz{1 MHz, and in the temperature range between 353 K and 378 K were made. Both pure and lithium-doped silver iodide showed blocking phenomena in the electrodes and the
Carlos Alberto Lozano Zapata +2 more
doaj +1 more source
Crystalline forms of silver iodide II: Determination of phase transformations [PDF]
In order to obtain appropriate forms of AgI (β- and γ-), a procedure was developed to synthesize AgI at room temperature (23°C), whereby samples of varying crystallographic purity and of varying crystallographic contents of the different forms were ...
Vukić Marija R. +2 more
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Chemical Stabilization of Perovskite Solar Cells with Functional Fulleropyrrolidines. [PDF]
While perovskite solar cells have invigorated the photovoltaic research community due to their excellent power conversion efficiencies (PCEs), these devices notably suffer from poor stability. To address this crucial issue, a solution-processable organic
Duzhko, Volodimyr V +6 more
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