Results 201 to 210 of about 165,449 (248)

Stacking the Deck to Make Materials With Atypically Short Heterometallic d8 M(II)···Au(III) Bonds

Angewandte Chemie, EarlyView.
Tetracyanoplatinate(II) and tetracyanoaurate(III), through self‐assembly in the presence of KCl, crystallize from water to form a one‐dimensional chain featuring the first reported PtII···AuIII metallophilic interaction with a very short distance of ∼3.0 Å between the metal centers.
Leanna M. Karn, Samyadeb Mahato, Adlih Britton, Mojtaba Abbasi, Scott Kroeker, Tim Storr, Daniel B. Leznoff   +6 more
wiley   +1 more source

Remote Desaturation of Unprotected Amines and C─H Amination of Alkanes by Polarity‐Matched N‐Radical Cations

Angewandte Chemie, EarlyView.
Highly electrophilic N‐radical cations enable efficient and selective H‐atom transfer (HAT) of unprotected amines. In this exceedingly practical strategy, simple CuCl catalyzes an interrupted Hofmann–Löffler–Freytag (HLF) reaction to afford δ desaturated amines, aza‐heterocycles, and C─H aminated alkanes without protecting groups.
Pavitra Laohapaisan, Ross M. Dare, Meredith L. Rudich, Jacob J. A. Garwood, Siyuan Gong, R. Thomas Simons, David A. Nagib   +6 more
wiley   +1 more source

Joint Cognitive Models Reveal Sources of Robust Individual Differences in Conflict Processing. [PDF]

Comput Brain Behav
Molloy MF, Lee TG, Jonides J, Zhang H, Sellers J, Heathcote A, Sripada C, Weigard AS.   +7 more
europepmc   +1 more source

Reductive Activation of White Phosphorus to [P4]2–, [P2]2–, and a Formal P2– Radical by Rare‐Earth Dinitrogen Complexes

Angewandte Chemie, EarlyView.
Masked divalent yttrium and gadolinium dinitrogen complexes mediate the fragmentation of white phosphorus, converting P4 into discrete dimetallic complexes of [P4]2– and [P2]2– ligands, and an unprecedented monatomic P2– radical ligand. Structural, spectroscopic, magnetic, and DFT studies reveal insight into the bonding between these unusual Pn units ...
Arpan Mondal, Richard A. Layfield
wiley   +1 more source

Delayed goal-directed processing underlies inhibitory control challenges in adult ADHD. [PDF]

Sci Rep
Osborne JB, Sellers J, Zhang H, Wang S, Liberatore S, Sripada C, Shah P, Jonides J.   +7 more
europepmc   +1 more source

A Comprehensive 19F NMR Framework for Fragment‐Based Drug Discovery: The Validated Screening Library OpenFL600 and Efficient Affinity Ranking by CSAR

Angewandte Chemie, EarlyView.
NMR screening is a powerful method for hit detection in drug‐discovery. We designed and validated the OpenFL600 19F$^{19}{\rm F}$ NMR library to probe diverse targets, including RNA, GPCRs, kinases, and proteases. This library yields target‐specific ligands without generating promiscuous binders.
Simon H. Rüdisser, Gabriela Stadler, Giacomo Padroni, Daria Barbash, Marco M. Ruckstuhl, Nils Lorz, Christina Jordan, Sarah Skibinski, Timo T. Stühlinger, Sarah E. Kratzwald, Katharina M. Siess, Sven Brüschweiler, Gerald Platzer, Antoine Cléry, Robert Konrat, Frédéric H.‐.T. Allain, Alvar D. Gossert   +16 more
wiley   +1 more source

BCL2 overexpression in donor lymphocytes reduces the risk of graft-versus-host disease. [PDF]

Blood Adv
Bejarano-García JA, Nufer M, Palacios-Barea MJ, Guijarro-Albaladejo B, Sierro-Martínez B, Bella Á, Robles-Benítez C, García-Guerrero E, Carrasco-Brocal I, Lara-Chica M, Sanoja-Flores L, Mendendez NV, Caballero-Velázquez T, Rodríguez-Gil A, Pérez-Simón JA.   +14 more
europepmc   +1 more source

The Missing Link in Ferrocenophane Chemistry: Isolation of a Carba[1]Ferrocenophane

Angewandte Chemie International Edition, EarlyView.
The synthesis and isolation of a crystalline carba[1]ferrocenophane is reported. A single carbon atom is the smallest bridging motif yet incorporated into a ferrocenophane, resulting in a dihedral angle between the cyclopentadienyl ring planes of 36.7°, which is the highest angular deflection from ferrocene's coplanarity observed so far.
Aylin Feuerstein, Sergi Danés, Kathrin Kolling, Bernd Morgenstern, Markus Gallei, André Schäfer   +5 more
wiley   +1 more source

Nightly variations in sleep quality and next-day cognitive performance: an in-home study in healthy older adults. [PDF]

Front Aging Neurosci
Brooks M, El Chami R, Jourde HR, Savard MA, Coffey EBJ.   +4 more
europepmc   +1 more source

Congruency effects can interact even when controlling for the reactivation aversion effect: implications for the generality-specificity paradox in hybrid distractor-interference tasks. [PDF]

Psychol Res
Dunaway MG, Weissman DH.
europepmc   +1 more source