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Applications of single-atom catalysts

Nano Research, 2021
Owning to unsaturated coordination environment, quantum size effect and metal-support interaction, single- or dual-atom metal sites, such as Mn, Fe, Co, Ni, Cu, Zn, Mo, Ru, Rh, Pd, Ag, Sn, Ir, Pt, Au, Bi, and Er coordinated with nonmetallic elements such as O, N, P, and S, exhibit different electronic configurations, which endow them with high ...
Qiaoqiao Zhang, Jingqi Guan
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Co Single‐Atom Catalysts Boost Chemiluminescence

Chemistry – A European Journal, 2020
AbstractCo single‐atom catalysts (SACs) with good aqueous solubility and abundant labelling functional groups were prepared in Co/Fe bimetallic metal‐organic frameworks by a facile solvothermal method without high‐temperature calcination. In contrast to traditional chemiluminescence (CL) catalysts, Co SACs accelerated decomposition of H2O2 to produce a
Hui Ouyang   +5 more
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Single‐Atom Catalysts for Hydrogen Activation

Small, 2023
AbstractSelective hydrogenation is one of the most important reactions in fine chemical industry, and the activation of H2 is the key step for hydrogenation. Catalysts play a critical role in selective hydrogenation, and some single‐atom catalysts (SACs) are highly capable of activating H2 in selective hydrogenation by virtue of the maximized atom ...
Wenwen Gao   +4 more
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Single‐Atom Catalysts in Catalytic Biomedicine

Advanced Materials, 2020
AbstractThe intrinsic deficiencies of nanoparticle‐initiated catalysis for biomedical applications promote the fast development of alternative versatile theranostic modalities. The catalytic performance and selectivity are the critical issues that are challenging to be augmented and optimized in biological conditions.
Huijing Xiang, Wei Feng, Yu Chen
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Why do Single‐Atom Alloys Catalysts Outperform both Single‐Atom Catalysts and Nanocatalysts on MXene?

Angewandte Chemie International Edition, 2023
AbstractSingle‐atom alloys (SAAs), combining the advantages of single‐atom and nanoparticles (NPs), play an extremely significant role in the field of heterogeneous catalysis. Nevertheless, understanding the catalytic mechanism of SAAs in catalysis reactions remains a challenge compared with single atoms and NPs. Herein, ruthenium‐nickel SAAs (RuNiSAAs)
Shuyan Guan   +8 more
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Theoretical insights into single-atom catalysts

Chemical Society Reviews, 2020
Schematic diagram of theoretical models and applications of single atom catalysts. A review on the theoretical models, intrinsic properties, and the related application of SACs.
Lulu Li   +4 more
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Single atom catalyst for electrocatalysis

Chinese Chemical Letters, 2021
Abstract Single atom catalyst (SAC) refers to a novel catalyst with the active metal atoms individually anchored on the support. Single atom catalysts present the unique appeal due to the high atomic availability and specific activity, as well as the high pathway selectivity.
Jianan Su   +5 more
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Engineering single-atom catalysts toward biomedical applications

Chemical Society Reviews, 2022
The advances of catalysts now enter an era of atomic-level precise control. Single-atom catalysts (SACs), characterized by outstanding catalytic activity and selectivity, afford attractive opportunities to revolutionize traditional nanomedicine.
Baisong Chang   +4 more
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Locally Ordered Single‐Atom Catalysts for Electrocatalysis

Angewandte Chemie International Edition, 2023
AbstractSingle‐atom catalysts manifest nearly 100 % atom utilization efficiency, well‐defined active sites, and high selectivity. However, their practical applications are hindered by a low atom loading density, uncontrollable location, and ambiguous interaction with the support, thereby posing challenges to maximizing their electrocatalytic ...
Yujing Ren   +6 more
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Toward Rational Design of Single-Atom Catalysts

The Journal of Physical Chemistry Letters, 2021
Downscaling catalyst size has long been used to promote the atomic utilization efficiency of catalysts. Single-atom catalysts (SACs) are the current end of this downscaling road, offering the potential of 100% metal atom utilization and excellent catalytic behavior compared with traditional nanoparticle catalysts.
Bosi Peng   +4 more
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