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Single-Crystal-to-Single-Crystal Topochemical Polymerizations by Design
Accounts of Chemical Research, 2008The polymerization of simple conjugated dienes has long been of interest: polydienes occur throughout Nature, and polyisoprene and its analogues form the basis of entire industries. In contrast, the polymers of similar small conjugated compounds, diacetylenes, trienes, and triacetylenes, are either unknown or laboratory curiosities.
Joseph W, Lauher +2 more
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Fast growth of single-crystal covalent organic frameworks for laboratory x-ray diffraction
ScienceThe imine-exchange strategy makes single-crystal growth of covalent organic frameworks (COFs) with large size (>15 microns) possible but is a time-consuming process (15 to 80 days) that has had limited success (six examples) and restricts structural ...
Jing Han +7 more
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Mechano-Photonics: Flexible Single-Crystal Organic Waveguides and Circuits.
Angewandte Chemie, 2020Microfabrication of circuits by combining the mechanical and photonic properties of flexible crystals is imperative for flexible miniature photonic devices.
R. Chandrasekar +6 more
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International Journal of Biological Macromolecules, 1996
Lamellar crystals of inulin were grown by crystallizing sharp fractions of low molecular weight inulin from dilute aqueous ethanol solutions. The crystals were analyzed using three-dimensional electron diffraction and X-ray powder diagrams. Two crystalline polymorphs were observed, depending on the hydration conditions: a hydrated form which indexed on
Andre, I. +5 more
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Lamellar crystals of inulin were grown by crystallizing sharp fractions of low molecular weight inulin from dilute aqueous ethanol solutions. The crystals were analyzed using three-dimensional electron diffraction and X-ray powder diagrams. Two crystalline polymorphs were observed, depending on the hydration conditions: a hydrated form which indexed on
Andre, I. +5 more
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Bioengineering Single Crystal Growth
Journal of the American Chemical Society, 2011Biomineralization is a "bottom-up" synthesis process that results in the formation of inorganic/organic nanocomposites with unrivaled control over structure, superior mechanical properties, adaptive response, and the capability of self-repair. While de novo design of such highly optimized materials may still be out of reach, engineering of the ...
Ching-Hsuan, Wu +2 more
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Polymorphic single crystal ↔ single crystal transition in K0.975Rb0.025NO3
Crystallography Reports, 2010Polymorphic transformations in K0.975Rb0.025NO3 single crystals have been investigated by optical microscopy and X-ray diffraction. The equilibrium temperature between modifications II and III has been determined. It is established that the crystal growth at II ↔ III polymorphic transitions is accompanied by the formation and growth of daughter ...
Yu. G. Asadov, E. V. Nasirov
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Single-crystal AlN nanonecklaces
Nanotechnology, 2008Distinct single-crystal aluminum nitride nanonecklaces with uniform [1011] faceted beads are synthesized via catalyst-assisted nitriding of Al. The detailed morphology and structure of the nanonecklaces have been characterized. The growth process has been investigated by comparing the products obtained at different synthesis times.
Huatao, Wang +6 more
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Shaped protein single crystals
Acta Crystallographica Section D Biological Crystallography, 1995The formation of protein single crystals grown with the shape controlled by the geometry of the capillary used as a growth cell is presented. The shaped crystals show strong birefringence under crossed nicols and diffract as single crystals up to 1.74 A.
J M, García-Ruiz +3 more
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Journal of Nanoscience and Nanotechnology, 2001
Single crystal gallium nitride nanowires have been obtained by heating gallium acetylacetonate in the presence of carbon nanotubes or activated carbon in NH3 vapor at 910 degrees C. GaN nanowires also were obtained when the reaction of gallium acetylacetonate with NH3 was carried out over catalytic Fe/Ni particles dispersed over silica.
F L, Deepak, A, Govindaraj, C N, Rao
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Single crystal gallium nitride nanowires have been obtained by heating gallium acetylacetonate in the presence of carbon nanotubes or activated carbon in NH3 vapor at 910 degrees C. GaN nanowires also were obtained when the reaction of gallium acetylacetonate with NH3 was carried out over catalytic Fe/Ni particles dispersed over silica.
F L, Deepak, A, Govindaraj, C N, Rao
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Single Crystal Perovskite Solar Cells: Development and Perspectives
Advanced Functional Materials, 2019The efficiency of perovskite solar cells has increased to a certified value of 25.2% in the past 10 years, benefiting from the superior properties of metal halide perovskite materials.
Xiao Cheng +4 more
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