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Radical-Bridged Heterometallic Single-Molecule Magnets Incorporating Four Lanthanoceniums.
Angewandte Chemie, 2023The syntheses and magnetic properties of organometallic heterometallic compounds [K(THF)6]{CoI[(μ3-HAN)RE2Cp*4]2} (1-RE) and [K(Crypt)]2{CoI[(μ3-HAN)RE2Cp*4]2} (2-RE) containing hexaazatrinaphthylene radicals (HAN · 3-) and four rare earth (RE) ions are ...
Peng Zhang +9 more
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Heterometallic CuII–LnIII complexes: Single molecule magnets and magnetic refrigerants
, 2021Molecular nanomagnets containing heterometallic 3d-4f complexes have been investigated extensively for the past few years realizing the role of exchange interaction to minimize the QTM effect.
Atanu Dey +3 more
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Journal of the American Chemical Society, 2021
Lanthanide dimetallofullerenes with single-electron M-M bonds are an important class of single molecular magnets and qubit candidates, but stabilization of their unique electronic and spin structure in the form of a neutral molecule requires ...
Yaofeng Wang +6 more
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Lanthanide dimetallofullerenes with single-electron M-M bonds are an important class of single molecular magnets and qubit candidates, but stabilization of their unique electronic and spin structure in the form of a neutral molecule requires ...
Yaofeng Wang +6 more
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Shining new light on multifunctional lanthanide single-molecule magnets.
Angewandte Chemie, 2020Single-molecule magnets (SMMs) are at the forefront of new technological advances in quantum information processing and spintronics. Despite the recent impressive breakthroughs in extending the magnetic blocking temperatures beyond liquid nitrogen ...
R. Marin, G. Brunet, M. Murugesu
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Single-molecule magnets within polyoxometalate-based frameworks.
Dalton Transactions, 2021As an extension of our interest in polyoxometalates (POMs) and lanthanoids, we report the design and synthesis of two polyoxometalate-based frameworks under hydrothermal conditions; [Ho4(PDA)4(H2O)11][(SiO4)@W12O36]·8H2O (1) and [Tb4(PDA)4(H2O)12][(SiO4)@
M. Babaei Zarch +5 more
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Development of Single‐Molecule Magnets †
Chinese journal of chemistry, 2020Single-molecule magnets (SMMs) are paramagnetic molecules that can be magnetized below a certain temperature and have potential applications in high-density information storage, magnetic qubits, spintronic devices, etc .
Dong Shao, Xin-Yi Wang
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Organolanthanide Single-Molecule Magnets with Heterocyclic Ligands.
Angewandte ChemieLanthanide (Ln) based mononuclear single-molecule magnets (SMMs) provide probably the finest ligand regulation model for magnetic property. Recently, the development of such SMMs has witnessed a fast transition from coordination to organometallic ...
Yidian Wang, Qianfu Luo, Yanzhen Zheng
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Optical Readout of Single-Molecule Magnets Magnetic Memories with Unpolarized Light.
Journal of the American Chemical SocietyMagnetic materials are widely used for many technologies in energy, health, transportation, computation, and data storage. For the latter, the readout of the magnetic state of a medium is crucial.
Maria Sara Raju +6 more
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Encyclopedia of Inorganic and Bioinorganic Chemistry, 2021
Single-Molecule Magnets (SMMs) are finite molecular species that display slow relaxation of their magnetisation, equivalent to a magnetic memory effect. Here we give an overview of how SMM behaviour can arise from the spin properties of a giant molecular
M. Giansiracusa +3 more
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Single-Molecule Magnets (SMMs) are finite molecular species that display slow relaxation of their magnetisation, equivalent to a magnetic memory effect. Here we give an overview of how SMM behaviour can arise from the spin properties of a giant molecular
M. Giansiracusa +3 more
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A Study of Magnetic Relaxation in Dysprosium(III) Single-Molecule Magnets.
Chemistry, 2020Though the development of SMMs is rapid, there are only two families of high Ueff Dy(III) SMMs known so far: the cyclopentadienyl (Cp) family with sandwich structure and the pentagonal-bipyramidal (PB) family with D5h symmetry.
Yousong Ding +6 more
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