A cationic and ferromagnetic hexametallic Mn(III) single-molecule magnet based on the salicylamidoxime ligand [PDF]
The salicylamidoxime-based complex [Mn-6(mu(3)-O)(2)(N-H2-sao)(6)(py)(6)(EtOH)(2)](ClO4)(2)center dot 4EtOH (1.4EtOH) constitutes the first example of a cationic and ferromagnetic member of the oxime-based family of [Mn-6(III)] single-molecule magnets.
An +32 more
core +1 more source
Origin of the anomalously low Raman exponents in single molecule magnets
The Raman exponent of single molecular magnetic relaxation may take various unexpected values because of rich phonon spectra and spin-phonon coupling of molecular crystals.
Lei Gu, R. Wu
semanticscholar +1 more source
We synthesized the dinuclear and mononuclear dysprosium(III) complexes [{Dy(Tp)2}2(Cl2An)]·2CH2Cl2 (1) and [Co(Cp)2][Dy(Tp)2(Cl2An)] (3), where Cl2An2− and Tp− are the chloranilate and hydrotris(pyrazolyl)borate ligand, respectively.
Ryuta Ishikawa +6 more
doaj +1 more source
Mn-doped II-VI quantum dots: artificial molecular magnets [PDF]
The notion of artifical atom relies on the capability to change the number of carriers one by one in semiconductor quantum dots, and the resulting changes in their electronic structure.
Aguado, Ramon, Fernandez-Rossier, J.
core +2 more sources
Dysprosium Single-Molecule Magnets Involving 1,10-Phenantroline-5,6-dione Ligand
The two mononuclear complexes of the formula [Dy(tta)3(L)] (1) and [Dy(hfac)3(L)] (2) (where tta- = 2-thenoytrifluoroacetylacetonate and hfac- = 1,1,1,5,5,5-hexafluoroacetylacetonate) were obtained from the coordination reaction of the Dy(tta)3·2H2O or ...
Olivier Galangau +6 more
doaj +1 more source
Ferroelectric Single‐Molecule Magnet with Toroidal Magnetic Moments
Materials that coexist magnetic and electric properties on the molecular scale in single‐molecule magnets (SMMs) with peculiar quantum behaviors have promise in molecular electronics and spintronics.
Yu‐Xia Wang +8 more
doaj +1 more source
Level splittings in exchange-biased spin tunneling
The level splittings in a dimer with the antiferromagnetic coupling between two single-molecule magnets are calculated perturbatively for arbitrary spin.
A. Garg +31 more
core +1 more source
Fabrication of Nano-Gapped Single-Electron Transistors for Transport Studies of Individual Single-Molecule Magnets [PDF]
Three terminal single-electron transistor devices utilizing Al/Al2O3 gate electrodes were developed for the study of electron transport through individual single-molecule magnets.
Christou, G. +4 more
core +3 more sources
Influencing the properties of dysprosium single-molecule magnets with phosphine, phosphide and phosphinidene ligands [PDF]
Single-molecule magnets are a type of coordination compound that can retain magnetic information at low temperatures. Single-molecule magnets based on lanthanides have accounted for many important advances, including systems with very large energy ...
A Cornia +44 more
core +2 more sources
Multiple relaxation times in single-molecule magnets
Multiple relaxation times detected in the ac magnetic susceptibility of several single-molecule magnets have been always assigned to extrinsic factors, such as nonequivalent magnetic centers or effects of intermolecular interactions in the crystal.
Chibotaru, Liviu F., Ho, Le Tuan Anh
core +1 more source

