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Electrophilic Trifluoromethylation of Dimetallofullerene Anions en Route to Air-Stable Single-Molecule Magnets with High Blocking Temperature of Magnetization.

Journal of the American Chemical Society, 2021
Lanthanide dimetallofullerenes with single-electron M-M bonds are an important class of single molecular magnets and qubit candidates, but stabilization of their unique electronic and spin structure in the form of a neutral molecule requires ...
Yaofeng Wang   +6 more
semanticscholar   +1 more source

Shining new light on multifunctional lanthanide single-molecule magnets.

Angewandte Chemie, 2020
Single-molecule magnets (SMMs) are at the forefront of new technological advances in quantum information processing and spintronics. Despite the recent impressive breakthroughs in extending the magnetic blocking temperatures beyond liquid nitrogen ...
R. Marin, G. Brunet, M. Murugesu
semanticscholar   +1 more source

Single-molecule magnets within polyoxometalate-based frameworks.

Dalton Transactions, 2021
As an extension of our interest in polyoxometalates (POMs) and lanthanoids, we report the design and synthesis of two polyoxometalate-based frameworks under hydrothermal conditions; [Ho4(PDA)4(H2O)11][(SiO4)@W12O36]·8H2O (1) and [Tb4(PDA)4(H2O)12][(SiO4)@
M. Babaei Zarch   +5 more
semanticscholar   +1 more source

Actinide-based single-molecule magnets

Dalton Transactions, 2015
Actinide single-molecule magnets compose a small yet complex consortium, presenting new design and characterization challenges for magnetochemists and physicists.
Katie R, Meihaus, Jeffrey R, Long
openaire   +2 more sources

Development of Single‐Molecule Magnets †

Chinese journal of chemistry, 2020
Single-molecule magnets (SMMs) are paramagnetic molecules that can be magnetized below a certain temperature and have potential applications in high-density information storage, magnetic qubits, spintronic devices, etc .
Dong Shao, Xin-Yi Wang
semanticscholar   +1 more source

Organolanthanide Single-Molecule Magnets with Heterocyclic Ligands.

Angewandte Chemie
Lanthanide (Ln) based mononuclear single-molecule magnets (SMMs) provide probably the finest ligand regulation model for magnetic property. Recently, the development of such SMMs has witnessed a fast transition from coordination to organometallic ...
Yidian Wang, Qianfu Luo, Yanzhen Zheng
semanticscholar   +1 more source

Heterometallic Cubane Single-Molecule Magnets

Inorganic Chemistry, 2007
Two new heterometallic cubane molecules have been synthesized. High-frequency electron paramagnetic resonance and magnetization measurements indicate that [Mn(3)Ni(hmp)(3)O(N(3))(3)(C(7)H(5)O(2))(3)] (1) displays a well-isolated S = 5 ground state (DeltaE > 120 K), with g = 2.0, D = -0.23 cm(-1), and ferromagnetic Mn-Mn exchange interactions competing ...
Feng, Patrick L.   +6 more
openaire   +3 more sources

Optical Readout of Single-Molecule Magnets Magnetic Memories with Unpolarized Light.

Journal of the American Chemical Society
Magnetic materials are widely used for many technologies in energy, health, transportation, computation, and data storage. For the latter, the readout of the magnetic state of a medium is crucial.
Maria Sara Raju   +6 more
semanticscholar   +1 more source

Single-Molecule Magnets

2003
Single-molecule magnets (SMMs) are among the best materials for studies of nano-scale magnets. SMMs are located in the boundary region between the discrete atoms and the bulk magnets, and exhibit unusual classical and quantum magnetic properties such as meso-scale magnets.
Keiji Takeda, Kunio Awaga
openaire   +1 more source

Conducting single-molecule magnet materials

Dalton Transactions, 2018
Multifunctional molecular materials exhibiting electrical conductivity and single-molecule magnet (SMM) behaviour are particularly attractive for electronic devices and related applications owing to the interaction between electronic conduction and magnetization of unimolecular units.
Goulven Cosquer   +3 more
openaire   +2 more sources

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