Results 21 to 30 of about 308,535 (321)
The Tripodal Ligand’s 4f Complexes: Use in Molecular Magnetism
A predictable type of coordination is a key property of tripodal ligands. Homo- and heteroleptic lanthanide complexes with tripodal ligands are a representative class of compounds.
Kira E. Vostrikova
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Lanthanide-Based Metal–Organic Frameworks with Single-Molecule Magnet Properties
Lanthanide metal–organic frameworks (Ln-MOFs) showing single-molecule magnet (SMM) properties are an ever-growing family of materials where the magnetic properties can be tuned by various interrelated parameters, such as the coordinated solvent ...
Fabio Manna +3 more
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Ab Initio Prediction of High-Temperature Magnetic Relaxation Rates in Single-Molecule Magnets.
Organometallic molecules based on [Dy(CpR)2]+ cations (where CpR is a substituted cyclopentadienyl anion) have emerged as clear front-runners in the search for high-temperature single-molecule magnets. Within this family of structurally similar molecules,
D. Reta, Jon G. C. Kragskow, N. Chilton
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Electrical detection and modulation of magnetism in a Dy-based ferroelectric single-molecule magnet
Electrical control of magnetism in single-molecule magnets with peculiar quantum magnetic behaviours has promise for applications in molecular electronics and quantum computing. Nevertheless, such kind of magnetoelectric effects have not been achieved in
Yu-Xia Wang +4 more
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Engineering Chemisorption of Fe4 Single‐Molecule Magnets on Gold
Gaining control over the grafting geometry is critically important for any application of surface‐supported single‐molecule magnets (SMMs) in data storage, spintronics, and quantum information science.
Lorenzo Poggini +21 more
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Methods and Models of Theoretical Calculation for Single-Molecule Magnets
Theoretical calculation plays an important role in the emerging field of single-molecule magnets (SMMs). It can not only explain experimental phenomena but also provide synthetic guidance.
Qian-Cheng Luo, Yan-Zhen Zheng
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Three isostructural cyano-bridged 3d–4f linear heterotrinuclear compounds, (H2.5O)4{Ln[TM(CN)5(CNH0.5)]2(HMPA)4} (Ln = YIII, TM = [FeIII]LS (1); Ln = DyIII, TM = [FeIII]LS (2); Ln = DyIII, TM = CoIII (3)), have been synthesized and characterized by ...
Xia Xiong +7 more
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Field-Induced Single-Molecule Magnets of Dysprosium Involving Quinone Derivatives
The coordination reaction of the [Dy(hfac)3(H2O)2] units (hfac− = 1,1,1,5,5,5-hexafluoroacetylacetonate) with the two quinone-based derivatives 4,7-di-tert-butyl-2-(3,5-di-tert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)benzo[d][1,3]dithiole-5,6-dione (L1 ...
Konstantin Martyanov +8 more
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Future Directions for Transuranic Single Molecule Magnets
Single Molecule Magnets (SMMs) based on transition metals and rare earths have been the object of considerable attention for the past 25 years. These systems exhibit slow relaxation of the magnetization, arising from a sizeable anisotropy barrier, and ...
Nicola Magnani, Roberto Caciuffo
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Achiral single molecule magnet and chiral single chain magnet [PDF]
An achiral molecular square and a chiral chain composed of cyanide bridged Fe(III) and Ni(II) ions were prepared, and they act as a single molecule magnet and a chiral single chain magnet, respectively.
Norihisa, Hoshino +3 more
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