The Preparatory (Anti)Bonding Character of Molecular Orbitals
Herein, a concept to qualitatively predict changes in bond dissociation energies upon reduction or oxidation of molecular compounds is introduced. Changing the population of so‐called preparatory molecular orbitals influences how molecular fragments are relaxing after bond cleavage, which is shown for isolated organometallic aluminum compounds as well ...
Jonas O. Wenzel +10 more
wiley +1 more source
Is Singlet Oxygen an Important Oxidant in Advanced Oxidation Processes? [PDF]
Garg S, Waite TD.
europepmc +1 more source
Coordination‐Tuned Iridium Single‐Atom Nanozymes Boost Multienzyme Activity for Colorimetric Sensing
Breaking the coordination symmetry of Ir single‐atom sites through asymmetric Ir–N3S1 engineering tailors interfacial electron transfer, oxygen activation, and multienzyme‐like catalytic pathways. Operando spectroscopy and theoretical modeling uncover the atomic‐level origin of activity enhancement, providing a strategy for designing multifunctional ...
Tao Li +10 more
wiley +1 more source
A Scalable Singlet Oxygen Reactor for Photodegradation of Active Pharmaceutical Compounds and Disinfection. [PDF]
Samarawickrama P +6 more
europepmc +1 more source
Flanking‐Group Engineering Unlocks Emerging Functionalities in Diketopyrrolopyrrole Semiconductors
This review presents a comprehensive and unified perspective of flanking‐group engineering in Diketopyrrolopyrrole (DPP) based organic semiconductors that connects molecular‐level design with cross‐device functionalities. By integrating insights from molecular design, solid‐state packing, and device physics, this review seeks to establish general ...
Xiaoyun Wu +5 more
wiley +1 more source
Endoperoxide delivered singlet oxygen: the future of PDT, without light or oxygen. [PDF]
Wang W +5 more
europepmc +1 more source
A concise supramolecular assembly strategy using α‐cyclodextrin and phenylpyridine derivatives affords dual‐functional materials with switchable multicolor photochromism and tunable ultralong organic phosphorescence, offering new platforms for various photonic applications. ABSTRACT Supramolecular photochromic materials capable of reversible alteration
Xue Bai +8 more
wiley +1 more source
Standardized Workflows for Time-Resolved Singlet Oxygen Quantification in Aqueous Systems. [PDF]
Fernandez H +12 more
europepmc +1 more source
This study introduces β‐glucan‐shielded apremilast laden nanomicelles that withstand gastrointestinal degradation, selectively accumulate in inflamed colon tissue, and modulate the microbiota–gut–brain axis. The formulation restores barrier integrity, reduces systemic and neuroinflammation, and improves anxiety‐ and depression‐like behaviors in colitis
Chandrashekhar Jori +10 more
wiley +1 more source
Immunotherapy of Canine Leishmaniasis by Vaccination with Singlet Oxygen-Inactivated Leishmania infantum. [PDF]
Manna L +4 more
europepmc +1 more source

