Results 191 to 200 of about 59,243 (260)

Breaking the Polarity–Coordination Coupling in Electrolyte Design for High‐Voltage Lithium Batteries

Advanced Energy Materials, EarlyView.
Steric and electronic co‐regulation of 2,2,2‐trifluoro‐N, N‐dimethylethylamide (DMTFA) decouples high polarity from strong Li+ coordination, creating an anion‐mediated pseudo‐weakly solvating electrolyte. This design lowers Li+ desolvation barriers, enhances Li+ mobility, and builds B‐, F‐, and N‐rich inorganic interphases, enabling stable 3.0–4.6 V ...
Xue Li, Shangquan Zhao, Yifan Wu, Naigen Zhou, Fei Luo, Runze Liu, Chengjin Peng, Junzhi Li, Stefano Passerini, Shan Fang   +9 more
wiley   +1 more source

Concentration-Dependent Photoproduction of Singlet Oxygen by Common Photosensitizers. [PDF]

Molecules
Szewczyk G, Mokrzyński K.
europepmc   +1 more source

Hyperpolarization of Pyridine 15N‐Oxide Molecular Probes Enabled by Parahydrogen

Angewandte Chemie, EarlyView.
Pyridine 15N‐oxides are introduced as motifs for hyperpolarization studies and biochemical applications are demonstrated. ABSTRACT Magnetic resonance (MR) is a powerful non‐invasive technique for probing structural, functional, and metabolic processes with high spatial and temporal resolution.
Ruhuai Mei, Lisa Maria Fries, Gonzalo Gabriel Rodriguez, Charlotte von Petersdorff‐Campen, Leander Konstantin May, Julius Frederik Matz, Sergey Korchak, Grysette Daher, Stefan Glöggler   +8 more
wiley   +1 more source

Planar Chiral Carbazole‐Naphthalene Bisimide Hetero‐Cyclophane for Circularly Polarized Delayed Fluorescence

Angewandte Chemie, EarlyView.
Tightly stacked carbazole and 1,2:5,6–naphthalene bisimide units afforded a planar chiral hetero‐cyclophane. The architecturally refined system, with strong charge‐transfer interaction and enhanced structural rigidity, exhibits orange‐red delayed CPL emission in both solution and solid states.
Sanchari Debnath, Swadhin Garain, Yvonne Wagenhäuser, Frank Würthner   +3 more
wiley   +1 more source

Multifunctional N-substituted 2-pyridylbenzothiazole derivatives: singlet oxygen generation, protein binding, and photoactivated anticancer and antibacterial activities. [PDF]

RSC Adv
Mohamed HA, Abdel-Shafi AA, Miyatake H, El-Khouly ME, Nassrallah AA.   +4 more
europepmc   +1 more source

Introducing Diradicaloid Thiele's Hydrocarbon Derivatives as Ligand in Transition Metal Chemistry

Angewandte Chemie, EarlyView.
N‐doped Thiele's hydrocarbon derivative is introduced as a ligand for the synthesis of mono‐ and bimetallic rhodium complexes as well as cyclometalated iridium complexes. These compounds constitute the first metal complexes based on a Thiele's hydrocarbon (or p‐quinodimethane) derivative and, to the best of our knowledge, the first cyclometalated ...
Alok Mahata, Nicolás. I. Neuman, Biprajit Sarkar   +2 more
wiley   +1 more source

Gold Clusters With Open‐Shell Ligands: Superatom Mediated Magnetic Interaction

Angewandte Chemie, EarlyView.
Open‐shell verdazyl radicals were covalently integrated with atomically precise Ir‐doped Au12 (Ir@Au12) superatoms. The resulting radical–superatom hybrids exhibit photoinduced electron transfer, spin delocalization onto the metal‐cluster core, and weak ferromagnetic communication between radicals mediated by the superatomic electronic structure ...
Katsuya Mutoh, Kosei Hayashi, Yoichi Kobayashi, Kazunobu Sato, Rika Tanaka, Daichi Kitagawa, Tatsuya Tsukuda, Takuya Nakashima   +7 more
wiley   +1 more source

Connecting Brown Carbon Composition and Physicochemical Properties of Aqueous Urban PM_2.5 to their Photosensitized Production of Singlet Oxygen and Organic Triplet Excited States. [PDF]

Environ Sci Technol
Lyu Y, Li Y, Ma R, Zhou T, Borduas-Dedekind N, Nah T.   +5 more
europepmc   +1 more source

Generation of the Camptothecin Scaffold by a Flavin‐Catalyzed Photooxidative Skeletal Reorganization

Angewandte Chemie, EarlyView.
The biosynthetic pathway of the anticancer drug precursor camptothecin involves an enigmatic skeletal reorganization from a 6/5/6 tetrahydro‐β‐carboline to a 6/6/5 pyrroloquinoline ring system. Here, we show that this transformation can be achieved by photooxidation with flavin cofactors, such as flavin mononucleotide (FMN) as catalysts.
Shenyu Liu, Zeliang Zhang, Benedikt Seligmann, Van Hung Bui, Tuan‐Anh Minh Nguyen, Thu‐Thuy T. Dang, Jakob Franke   +6 more
wiley   +1 more source

Analysis of Singlet Oxygen Luminescence Generated By Protoporphyrin IX. [PDF]

Antioxidants (Basel)
Vikas V, Yang W, Wilson BC, Zhu TC, Hadfield RH.   +4 more
europepmc   +1 more source