Results 121 to 130 of about 1,254,309 (209)
ALDH Inhibition‐Primed Photocatalysis Disrupts Cancer Stemness Plasticity
DE‐Et converts ALDH‐mediated redox buffering into a photoredox vulnerability by coupling ALDH inhibition with red‐light‐driven catalytic NADH oxidation. This enzyme‐coupled photoredox strategy sustains mitochondrial NADH/NAD+ imbalance, induces pyroptotic tumor cell death, suppresses tumor growth in vivo, and promotes systemic antitumor immunity ...
Yujin Kim +10 more
wiley +2 more sources
The S‐scheme of SnS2‐C/g‐C3N4 heterostructure enables Photocatalytic Cr(VI) and 4‐NP reduction. ABSTRACT Hexavalent chromium (Cr(VI)) and 4‐nitrophenol (4‐NP) are persistent and highly toxic water pollutants that require efficient treatment under mild conditions. In this work, L‐cysteine‐derived carbon‐modified SnS2 (SnS2‐C) was prepared hydrothermally
Dhayanantha Prabu Jaihindh +8 more
wiley +1 more source
A recyclable carbon nitride/nickel metallaphotoredox platform enables direct α‐C(sp3)─H arylation and alkylation of ethers, amides, and benzylic substrates under visible light. Broad substrate scope, late‐stage functionalization, five‐cycle photocatalyst reuse, and continuous‐flow translation are demonstrated, while mechanistic studies support ...
Miguel M. de Vries Ibáñez +8 more
wiley +1 more source
Synthetic Strategies for the Construction of Cyclobutane‐Fused Heterocycles
Cyclobutane‐fused heterocycles are important motifs commonly present in bioactive compounds, recognized for their rigid 3D structures that confer unique properties. However, synthesizing these compounds remains challenging. This review discusses current methods for their synthesis, such as photochemical, metal‐catalyzed, and Lewis acid‐mediated [2 + 2]
Michela Vargiu +2 more
wiley +1 more source
Mitochondrial oxidative metabolism generates ROS. Downstream chemiexcitation triplet carbonyls, singlet oxygen; produces ultra‐weak photon emission (UPE). Energetic bounds restrict well‐coupled respiration to extremely weak, red/NIR‐biased emission. Stronger visible UPE indicates elevated oxidative flux, linking measured photon counts to redox state ...
Samuel Crowther +2 more
wiley +1 more source
Cyclopropylamines have emerged as powerful photocatalytic building blocks. Upon light‐induced single‐electron oxidation, they undergo strain‐release ring opening to generate distonic iminium radicals that enable diverse transformations, including ring‐opening functionalization, formal [3 + 2] cycloadditions, radical cascades, and asymmetric bond ...
Maria Chiara Cabua +3 more
wiley +1 more source
Charge-transfer dynamics in bowl-shaped imide-functionalized corannulenes at ensemble and single-molecule levels. [PDF]
Thavamani T +6 more
europepmc +1 more source
Mechanistic Study on Dual-Donor Modified Distyryl-BODIPY Photosensitizers. [PDF]
Yang Y +5 more
europepmc +1 more source
This work demonstrates a layer‐bridging coordination strategy of Co single atoms in COFs that promotes the formation and utilization of triplet excited states. The introduction of Co single atoms induces pronounced energy‐level splitting and enhanced spin–orbit coupling, facilitating the generation of 1O2 and O2•– for efficient photocatalytic H2O2 ...
Guoen Tang +6 more
wiley +1 more source

