Results 81 to 90 of about 1,254,309 (209)

Photochemistry of N‐Phenyl Benzonaphthothiophene and Dinaphthothiophene Sulfoximines

European Journal of Organic Chemistry, EarlyView.
The sequential photorelease of nitrenes and atomic oxygen [O(3P)] from N‑phenyl benzonaphthothiophene and dinaphthothiophene sulfoximines is a rare photochemical phenomenon in which two reactive intermediates can be released from a single chromophore. The sequential photorelease of nitrenes and atomic oxygen [O(3P)] is a rare photochemical phenomenon ...
Henry J. Politte, Bashar Aziz, Riley J. N. Tharp, Ryan D. McCulla   +3 more
wiley   +1 more source

Research progress in photo‐controlled radical involved luminescence materials

FlexMat, EarlyView.
This review systematically dissects radical generation mechanisms, triplet‐exciton photophysics, material design strategies, and cutting‐edge applications in smart encryption, environmental sensing, and 3D printing. Abstract In recent years, photo‐controlled radical room‐temperature phosphorescent (RTP) materials have shown significant application ...
Sichen Meng, Shengwen Bao, Xiang Li, Shuaishuai Lu, Danfeng Ye, Ying Liu, Deli Sun, Hongwei Wu, Liangliang Zhu   +8 more
wiley   +1 more source

Singlet Oxygen Reactivity with Carbonate Solvents Used for Li-Ion Battery Electrolytes

, 2018
High degrees of delithiation of layered transition metal oxide cathode active materials (NCMs and HE-NCM) for lithium-ion batteries (LIBs) was shown to lead to the release of singlet oxygen, which is accompanied by enhanced electrolyte decomposition ...
Anna T. S. Freiberg, Regina de Vivie-Riedle, Anna T. S. Freiberg (5938301), Matthias K. Roos (1339590), Matthias K. Roos, Regina de Vivie-Riedle (1339584), Johannes Wandt (5938304), Johannes Wandt, Hubert A. Gasteiger (1831615), Hubert A. Gasteiger   +9 more
core   +1 more source

Activating Triplet Excitons in COFs via Layer-Bridging Co Single Atoms for Photocatalytic H₂O₂ Production and Tandem C─N Coupling. [PDF]

Angew Chem Int Ed Engl
This work demonstrates a layer‐bridging coordination strategy of Co single atoms in COFs that promotes the formation and utilization of triplet excited states. The introduction of Co single atoms induces pronounced energy‐level splitting and enhanced spin–orbit coupling, facilitating the generation of 1O2 and O2•– for efficient photocatalytic H2O2 ...
Tang G, Zhang J, Liang G, Zhang J, Bie C, Yu J, García H.   +6 more
europepmc   +2 more sources

Zero‐Dimensional Organic–Inorganic Hybrid Metal Halides as Luminescent Materials: A Review From the Perspective of Molecular Level

Laser &Photonics Reviews, EarlyView.
Advances in zero‐dimensional organic–inorganic hybrid metal halides are reviewed from a molecular‐engineering perspective. Four design strategies (polyhedral‐architecture, elemental‐composition‐substitution, donor–acceptor/host–guest, multi‐emissive‐center integration‐coupling engineering) and structure‐performance trade‐offs are summarized.
Rufeng Wang, Junnan Song, Guiqiang Pu, Yangmin Tang, Jiacheng Wang   +4 more
wiley   +1 more source

Liquid-liquid reaction of hydrogen peroxide and sodium hypochlorite for the production of singlet oxygen in a centrifugal flow singlet oxygen generator

, 2011
Liquid-liquid reaction of hydrogen peroxide and sodium hypochlorite for the production of singlet oxygen in a centrifugal flow singlet oxygen generatorAn attempt is made to produce gas-phase singlet oxygen O-2(a(1)Delta(g)) in a liquid-liquid reaction ...
Deng, Lie-zheng, Shi, Wen-bo, null Guo-he Sha, Zhang, Cun-hao, null Rong-rong Cui, null Wen-bo Shi, null Lie-zheng Deng, Yang, He-ping, 邓列征, null He-ping Yang, Cui, Rong-rong, Sha, Guo-he, null Cun-hao Zhang   +12 more
core   +1 more source

Conjugation‐Length Dependent Interplay Between Charge Transfer and Locally Excited States in Sequence‐Defined Donor–Acceptor Substituted Oligo(Phenylene Ethynylene)s

Macromolecular Rapid Communications, EarlyView.
Iterative synthesis gives access to sequence‐defined oligo(para‐phenylene ethynylene)s, bridging donor and acceptor units through stepwise extension of the conjugated backbone. Accurate length control enables systematic structure‐property relationship investigations across absorption, emission, and excited‐state dynamics.
Qianyu Cai, Till Paha, Marianne Armbruster, André Jung, Eli Zysman‐Colman, Andreas‐Neil Unterreiner, Michael A. R. Meier   +6 more
wiley   +1 more source

Temperature dependence of singlet oxygen generation by different photosensitizers [PDF]

, 2019
The temperature dependences of the lifetimes and the efficiency of singlet oxygen generation for a set of compounds (porphyrins, metalloporphyrins, porphycene, terrylene etc.) has been measured and characterized. Based on the character of the temperature
Starukhin Aleksander, Dobkowski Jacek, Gorski Aleksander   +2 more
core   +2 more sources

Resorufin‐Catalyzed PhotoATRP Under Red Light

Macromolecular Rapid Communications, EarlyView.
The sodium salt of resorufin, a commercially available, water‐soluble dye, serves as an efficient photocatalyst for dual‐catalysis PhotoATRP under red light. High control is achieved at catalyst loadings as low as 1 ppm. This versatile system operates across the visible spectrum in both organic and aqueous media, relying on a dynamic oxidative ...
Halil Ibrahim Coskun, Hyerin Kang, Steffen Jockusch, Gorkem Yilmaz, Krzysztof Matyjaszewski   +4 more
wiley   +1 more source

Band Engineering of Benzothiadiazole‐Derived Metal‐Organic Frameworks for Photocatalytic Organic Transformations

National Materials, EarlyView.
BTID‐functionalized metal‐organic frameworks provide a modular platform for tailoring photocatalytic electronic structures through acceptor‐linker engineering. By correlating band alignment, charge‐transfer characteristics, and reactive oxygen species generation, this review highlights design principles that enable efficient visible‐light‐driven ...
Xin Li, Long‐Shuang Chen, Meng‐Hao Li, Ying‐Wei Yang   +3 more
wiley   +1 more source