Results 181 to 190 of about 228,179 (253)

The Serendipitous Discovery of Rollover Cyclometalation: From Unrecognized Observation to Transformative Chemistry

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Rollover cyclometalation is a distinctive variant of classical cyclometalation where a chelated heterocyclic ligand undergoes internal rotation, releasing one donor atom from coordination and subsequently activating a remote C─H bond with high regioselectivity.
Antonio Zucca, Maria I. Pilo
wiley   +1 more source

Electroclinical phenotypes—genetic characterization of developmental and epileptic encephalopathies in a cohort study

open access: yesEpileptic Disorders, EarlyView.
Abstract Objective Developmental and epileptic encephalopathies (DEEs) are characterized by refractory seizures and frequently recurring epileptic activity with neurodevelopmental delay or regression that usually begin in early life. We aimed to define the relationship between electroclinical features and etiology, as well as the genotype–phenotype ...
Burcu Yaman   +7 more
wiley   +1 more source

[Situs ambiguous in a school child with respiratory disease].

open access: yesAnales de pediatria (Barcelona, Spain : 2003), 2009
M, Tortajada Girbés   +5 more
openaire   +1 more source

Study on Fluid Pressure in Tubing, Dynamic Stress in Reservoir, and Fracture Propagation Morphology During Variable‐Rate Hydraulic Fracturing

open access: yesEnergy Science &Engineering, EarlyView.
Variable‐rate hydraulic fracturing can induce unsteady flow in the tubing, thereby generating fluctuating fluid pressure near the bottom‐hole reservoir. Dynamic stress is generated in the reservoir under the action of fluctuating fluid pressure and propagates as stress waves.
Zhu Ge, Wang Chaojing, Li Weicheng
wiley   +1 more source

Genetics in Heterotaxy: A Case Series and Literature Review on DNAH9, PKD1L1, MMP21, and GDF1. [PDF]

open access: yesClin Genet
Ho TBT   +23 more
europepmc   +1 more source

Mechanistic Understanding of Nickel Catalyzed Urea Oxidation Reaction to Cyanate and Nitrite

open access: yesExploration, EarlyView.
The urea oxidation reaction (UOR) is a promising alternative to oxygen evolution reaction (OER) for energy efficient hydrogen production, yet its reaction mechanism remains controversial because many proposed pathways have not been directly correlated with experimentally verified products and intermediates.
Kyu In Shim   +4 more
wiley   +1 more source

Programmable crack dynamics engineering enables flexible strain sensors with high linearity

open access: yesFlexMat, EarlyView.
First‐decoupling theoretical framework of crack evolution elucidating the control methods, mechanistic insights, and structure‐activity relationships is established. Crack propagation from uncontrollable randomness systematically evolves into spatially ordered states.
Chunjin Wu   +9 more
wiley   +1 more source

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