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Chemistry, 2020
A rational approach of modulating easy-axis magnetic anisotropy by axial donor ligand on heptacoordinated Fe II complexes have been explored. In this series of complexes with formulae of [Fe(H 4 L)(NCS) 2 ]·3DMF·0.5H 2 O ( 1 ), [Fe(H 4 L)(NCSe) 2 ]·3DMF ...
A. Mondal +3 more
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A rational approach of modulating easy-axis magnetic anisotropy by axial donor ligand on heptacoordinated Fe II complexes have been explored. In this series of complexes with formulae of [Fe(H 4 L)(NCS) 2 ]·3DMF·0.5H 2 O ( 1 ), [Fe(H 4 L)(NCSe) 2 ]·3DMF ...
A. Mondal +3 more
semanticscholar +1 more source
Slow magnetic relaxation in a cobalt magnetic chain
Chemical Communications, 2011A homospin ladder-like chain, [Co(Hdhq)(OAc)](n) (1; H(2)dhq = 2,3-dihydroxyquinoxaline), shows a single-chain-magnet-like (SCM-like) behavior with the characteristics of frequency dependence of the out-of-phase component in alternating current (ac) magnetic susceptibilities and hysteresis loops.
Yang, C.I., Chuang, P.H., Lu, K.L.
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Slow relaxation in magnetic materials
Ultramicroscopy, 1992Magnetic aftereffects in magnetic materials have previously been attributed to rotation of individual domains and wall motion between domains. We have measured the relaxation of the remanent magnetization as a function of time, in several magnetic materials including random magnetic systems and single-crystal ferromagnets, from 10-5 to 104s after ...
R.V. Chamberlin, M.R. Scheinfein
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Slow magnetic relaxation in hexacoordinated cobalt(ii) field-induced single-ion magnets
, 2020To gain a better insight into the factors affecting the enhancement of the energy barrier in single molecule (single ion) magnets, three hexacoordinate cobalt(II) complexes based on the tridentate ligand 2,6-bis(pyrazol-1-yl)pyridine (pypz) and ...
A. Świtlicka +8 more
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Dalton Transactions, 2020
Two mononuclear Co(ii) complexes with tetrahedral coordination geometry have been constructed from different bulky Schiff-base ligands. Both complexes exhibit slow magnetic relaxation without a static field and their relaxation behaviors can be tuned by ...
G. Peng +4 more
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Two mononuclear Co(ii) complexes with tetrahedral coordination geometry have been constructed from different bulky Schiff-base ligands. Both complexes exhibit slow magnetic relaxation without a static field and their relaxation behaviors can be tuned by ...
G. Peng +4 more
semanticscholar +1 more source
A Ferroelectric Metallomesogen Exhibiting Field‐Induced Slow Magnetic Relaxation
Chemistry – A European Journal, 2021AbstractMagnetoelectric (ME) materials exhibiting coupled electric and magnetic properties are of significant interest because of their potential use in memory storage devices, new sensors, or low‐consumption devices. Herein, we report a new category of ME material that shows liquid crystal (LC), ferroelectric (FE), and field‐induced single molecule ...
Ryohei Akiyoshi +7 more
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Computer simulation of slow magnetic relaxation
Journal of Magnetism and Magnetic Materials, 1995Abstract We present a computer simulation study of magnetic relaxation for a system of single-domain particles. We focus on the dependence of the magnetic viscosity coefficient with the shape of the distribution function of activation energies, and compare our computational results with known experimental results for a ferrofluid system.
C. Sánchez +2 more
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Slow Magnetic Relaxation in Iron: A Ferromagnetic Liquid
Science, 1993The remanent magnetization of single-crystal iron whiskers has been measured from 10 -5 to 10 4 seconds after the removal of an applied field. The observed response is accurately modeled by localized magnon relaxation on a Gaussian size distribution of dynamically correlated domains ...
R V, Chamberlin, M R, Scheinfein
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Slow Magnetic Relaxation in an Octanuclear Manganese Chain
Inorganic Chemistry, 2010A one-dimensional chain containing a mixed-valence octanuclear manganese(II,III) building unit, (NEt(4))(2n)[Mn(8)O(2)(salox)(6)(N(3))(8)(MeOH)(3)](n) (H(2)salox = salicylaldoxime), was synthesized and characterized structurally and magnetically. Each building unit contains a [Mn(II)(2)Mn(III)(6)O(2)](18+) structural topology.
Chen-I, Yang +4 more
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Coupling Dy3 Triangles Enhances Their Slow Magnetic Relaxation
Angewandte Chemie International Edition, 2010Two's company: Coupling two Dy3 triangles to give Dy6 (see picture; Dy blue, Cl green, O red) leads to a dramatic enhancement of the barrier height to magnetization reversal. The enhancement has been rationalized by single-crystal magnetometry measurements and ab initio calculations.
Anson, N. +9 more
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