Results 91 to 100 of about 11,860 (227)

Cation Distribution in Li2CaSiO4:Gd, Pr, Na Uncovered Through Anomalous Diffraction

European Journal of Inorganic Chemistry, EarlyView.
Li2CaSiO4 co‐doped with Gd3+ and Pr3+ shows strong blue‐to‐UV‐B up‐conversion. Herein, we explore the doping element distribution in order to discern the reason for the strongly supportive co‐doping effect using high‐resolution Rietveld refinement and multiple‐edge anomalous dispersion measurements.
Christoph Rick, Raphael Steinbach, Daniel M. Többens, Thomas Jüstel, Joachim Breternitz   +4 more
wiley   +1 more source

Hypervision Proton Surgery: The Future Direction of Proton Therapy

iNew Medicine, EarlyView.
ABSTRACT Proton beams provide unique physical advantages characterized by a low entrance dose, negligible exit dose, and a sharp Bragg peak, which enable superior sparing of normal tissues and support safe dose escalation for improved tumor control. However, conventional photon‐based fractionation remains widely used in proton therapy, where prolonged ...
Li Li, Shuanghu Yuan
wiley   +1 more source

A Personal Perspective on Metalloprotein Structure and the Future of Macromolecular X‐Ray Crystallography

Journal of the Chinese Chemical Society, EarlyView.
While X‐ray crystallography has been the primary method for determining the structures of metalloproteins, cryoEM has taken over this role, illustrated by [4Fe4S]‐cluster containing proteins deposited in the Protein Data Bank. What will be the role for X‐ray crystallography as cryoEM and machine learning methods dominate the initial structural analysis?
Douglas C. Rees
wiley   +1 more source

A Power‐Efficient Monte Carlo Framework for Nonlinear Light–Matter Interactions: In Silico Modeling of Spontaneous and Stimulated Raman Scattering in Turbid Media

Journal of Raman Spectroscopy, EarlyView.
Power‐efficient Monte Carlo modeling of nonlinear light–matter interactions in turbid media is demonstrated using Apple Silicon–accelerated photon transport. The Metal‐base framework enables accurate simulation of spontaneous and stimulated Raman scattering, revealing detection‐dependent SRS efficiency while providing a scalable, energy‐efficient ...
Ilya Vladyko, Vladislav Yakovlev, Alexander Doronin   +2 more
wiley   +1 more source

Field‐Cycling NMR Relaxometry in Tire Elastomer Science

Magnetic Resonance in Chemistry, EarlyView.
Field‐cycling NMR relaxometry has established as an ideal tool to investigate multiscale polymer dynamics. Here, we review and discuss applications on elastomers and elastomer compounds of interest for the tire industry to obtain information on segmental dynamics and on polymer dynamics over different regimes as a function of chain length in polymer ...
Francesca Nardelli, Michele Pierigé, Elisa Carignani, Marco Geppi, Francesca Martini, Lucia Calucci   +5 more
wiley   +1 more source

Interaction With Surface Spins as a Contribution to Nuclear Magnetic Relaxation of Liquids Adsorbed in Mesoporous Materials

Magnetic Resonance in Chemistry, EarlyView.
Liquids at silica interfaces experience demixing as a consequence of their respective polarity. The distribution of liquids and their primary relaxation contributions are studied by surface modification with OD and radical moieties, respectively. ABSTRACT NMR relaxation of liquids in the presence of solid interfaces, such as silica gel or porous glass,
Carlos Mattea, Hannah Leptin, Moritz Schmidt, Siegfried Stapf   +3 more
wiley   +1 more source

Structure and Dynamics of Ultra‐Low‐Crosslinked Microgels

Journal of Polymer Science, EarlyView.
This study reveals the relationship between microgel internal architecture, zero‐shear viscosity, structural relaxation time, and the ability of ultra‐soft colloidal suspensions to remain viscous fluids under overcrowded conditions. This interplay between microgel compressibility and zero‐shear viscosity is further highlighted by a colloid‐polymer ...
Nikolaos A. Burger, Alexander V. Petrunin, Ann E. Terry, Ralf Schweins, Andrea Scotti   +4 more
wiley   +1 more source

The Age and Origin of Block Deposits in the Victorian Alps, Australia

Permafrost and Periglacial Processes, EarlyView.
ABSTRACT Large periglacial block deposits are found in the mountains of southeastern Australia. Despite their widespread distribution, their mode of formation and age are poorly understood. These landforms hold considerable potential to shed light on the nature of cooling during glacial periods. In this paper we present a new study of block deposits in
Timothy T. Barrows, Michelle S. Worland, Julian Murton, Stephanie C. Mills, L. Keith Fifield   +4 more
wiley   +1 more source

Laser‐Induced‐Structural Transformation in Ti3CNTx MXene Monitored by Raman Spectroscopy with DFT Insight

Small, EarlyView.
A multi‐wavelength Raman study of microwave‐assisted hydrothermal Ti3CNTx MXene, supported by theoretical calculations, identifies laser‐power thresholds and evaluates its ambient‐condition stability. ABSTRACT MXenes are emerging 2D nanomaterials that have attracted growing attention for their highly tunable atomic structure, composition, and surface ...
Subrata Ghosh, Narayan N. Som, Muhammad Abiyyu Kenichi Purbayanto, Dorota Moszczyńska, Anna Wójcik, Carlo S. Casari, Agnieszka Maria Jastrzębska, Madhurya Chandel   +7 more
wiley   +1 more source

Fractionation‐Free Protein Corona Quantification Through Synchrotron‐Based Small‐Angle X‐ray Scattering

Small Methods, EarlyView.
A fractionation‐free SAXS approach quantifies protein corona formation on silica nanoparticles under native conditions. By deconvoluting scattering from free and bound proteins, adsorbed mass is directly determined in simple and complex media. The method resolves adsorption regimes and thermodynamics, establishing non‐invasive, in situ characterization
Juliana T. T. Carvalho, Caroline E. P. Silva, Lindomar J. C. Albuquerque, Antônio A. Malfatti‐Gasperini, Liming Wang, Nathan P. Cowieson, Mateus B. Cardoso   +6 more
wiley   +1 more source