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Sorption of Phenanthrene by Reference Smectites

Environmental Science & Technology, 2001
Fate and behavior of nonionic hydrophobic organic compounds (HOCs) in the environment is mainly controlled by their interactions with various components of soils and sediments. Due to their large surface area and abundance in many soils, smectites may greatly influence the fate and transport of HOCs in the environment.
L S, Hundal   +3 more
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Complexation of carboxylate on smectite surfaces

Physical Chemistry Chemical Physics, 2017
We report a first principles molecular dynamics (FPMD) study of carboxylate complexation on clay surfaces.
Xiandong Liu   +4 more
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Interstratified kaolinite-smectite: Nature of the layers and mechanism of smectite kaolinization

American Mineralogist, 2006
This study aims to contribute to a better understanding of the nature and evolution mechanism of interstratified clay minerals. We examined the
Dudek T, Cuadros J, Fiore S
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Atrazine Desorption from Smectites

Soil Science Society of America Journal, 1994
Abstract In soils low in organic matter, pesticide adsorption and desorption by clay minerals may strongly influence the fate of pesticides in soil environments. Atrazine (2‐chloro‐4‐ethylamino‐6‐isopropylamino‐1,3,5‐triazine) adsorption‐desorption was determined on 11 reference smectites (<2‐µm size fraction), and a soil smectite (
Barriuso, E.   +3 more
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Smectite and illite/smectite mixed-layer clay minerals in the Ashibetsu coals

International Journal of Coal Geology, 1994
Abstract Smectite, K-smectite and illite/smectite (I/S) mixed-layer minerals are found as expandable clay minerals in the Paleogene coal seams of the Ashibetsu coal mine in the Ishikari coal field, Hokkaido, Japan. As K-smectite often exists in tuff, tuffaceous shale and coal near tuff, and only occasionally in shale, the K-smectite is simply thought
Tatsuo Kimura   +2 more
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Influence of coexistent salt on hydrothermal synthesis of smectite and film-formability of the smectite

Applied Clay Science, 2009
Abstract To evaluate the influence of coexistent salt in the Mg–Si precursor for the hydrothermal synthesis of smectite, stevensite was synthesized hydrothermally from Mg–Si precursors with different salt concentrations. Prepared homogeneous Mg–Si precursors were washed with distilled water before hydrothermal treatment. The salt concentration of the
Hyun-Jeong Nam   +4 more
openaire   +1 more source

Pathways of Smectite Illitization

Clays and Clay Minerals, 1986
AbstractJunction probability diagrams show variation in both composition and layer arrangement in mixed-layer clay minerals. These diagrams can represent short-range and long-range ordered, random, and segregated interstratifications. Mineralogical analyses of illite/smectite from shale cuttings, bentonites, and hydrothermally altered tuffs define ...
Craig M. Bethke   +2 more
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Expansion of Smectite by Hexadecyltrimethylammonium

Clays and Clay Minerals, 2002
AbstractThe adsorption of hexadecyltrimethylammonium (HDTMA) in smectite was studied by adsorption isotherms, X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM). Smectites that had reacted for 48 h with HDTMA cations equivalent to 0.2–3.0 times the cation exchange capacity (CEC) were converted to HDTMA-exchanged ...
Seung Yeop Lee, Soo Jin Kim
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Trioctahedral Smectite and Interstratified Chlorite/Smectite in Jurassic Strata of the Connecticut Valley

Clays and Clay Minerals, 1981
AbstractTrioctahedral smectite and regularly interstratified chlorite/smectite in strata of the East Berlin Formation of the Connecticut Valley are largely restricted to black shale and gray mudstone deposited in alkaline, perennial lakes. The precursor of the mixed-layer clay appears to have been a smectite.
exaly   +2 more sources

Hydration Energies of Smectites

1985
Abstract Dehydration isotherms of five smectites and one vermiculite saturated with Na, K, Mg, and Ca were used to calculate the hydration energies of clay minerals in different water-activity and cation-exchange conditions. As the water activity decreased, differences in hydration energies appeared to be dependent on the nature of ...
Y. Tardy, O. Touret
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