Results 201 to 210 of about 4,064 (240)

Introduction of a Double‐Headed Nucleotide Into G‐Quadruplex DNA: Position‐Dependent Stabilization and Structural Insights

open access: yesChemistry – A European Journal, EarlyView.
A double‐headed bis‐guanine (G) nucleotide (GG) was evaluated as a noncanonical building block in G‐quadruplexes (G4s). Biophysical and computational analyses reveal that GG can directly participate in G‐tetrads and strongly stabilize G4s in a position‐ and topology‐dependent manner. These findings establish design rules for using GG to engineer highly
Krista Urup   +5 more
wiley   +1 more source

Electrochemiluminescence of Heteroleptic Iridium(III) Complexes Featuring Substituted 2,4‐diphenylpyridinato Ligands

open access: yesChemistry – A European Journal, EarlyView.
Five heteroleptic iridium(III) complexes bearing cyclometalated 2,4‐diphenylpyridinato ligands were synthesized and their electrochemiluminescence (ECL) investigated. Two different coreactants were evaluated: tri‐n‐propylamine and benzoyl peroxide under anodic and cathodic potentials, respectively.
Ovini Jayawardana   +6 more
wiley   +1 more source

Embedding a Dinuclear Ru─Pt Photocatalyst Into Polyampholytic Graft Copolymer Matrix Enables Prolonged Hydrogen Evolution While Allowing Catalyst Repair

open access: yesChemistry – A European Journal, EarlyView.
A unimolecular polyampholytic graft copolymer matrix provides a protective confinement for an electrostatically embedded tetrapyridophenazine‐bridged heterodinuclear Ru‐Pt hydrogen evolving photocatalyst. The matrix slows the degradation kinetics of the catalyst and at the same time does not hinder its repair by ammonium persulfate.
Yurii Utievskyi   +10 more
wiley   +1 more source

Compositional Stages in the Thermal Activation of Metal‐Organic Frameworks in Vacuo: In Situ Spectroscopy and Computation

open access: yesChemistry – A European Journal, EarlyView.
The ultrahigh surface area intrinsic to many metal‐organic frameworks (MOFs) may only be accessed after the removal of synthesis solvent from within the pores. This study elucidates the electronic and structural changes undergone through the guest removal process within a commonly used CUS MOF.
George W. Fritze   +2 more
wiley   +1 more source

Enhanced but not superior: Performance outcomes from the inaugural enhanced games. [PDF]

open access: yesPhysiol Rep
Azevedo RA   +7 more
europepmc   +1 more source

A study of Ni‐Co/CeO2 catalyst derived from metal–organic framework for dry reforming of methane

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract The efficacy of cobalt‐doped, MOF‐derived catalysts for dry reforming of methane (DRM) was examined. The focus was on the influence of varying nickel and cobalt molar ratios on catalytic performance. Three catalysts with Ni:Co ratios of 1:1, 1:0.5, and 0.5:1, were synthesized and tested with cerium oxide as a constant support. The DRM reaction
Ruth D. Alli, Nader Mahinpey
wiley   +1 more source

Enhanced games and performance-optimized athletes: anticipating the orthopedic challenges, a narrative review. [PDF]

open access: yesActa Orthop Traumatol Turc
Eftekhari M   +6 more
europepmc   +1 more source

Opsoclonus in Pediatric Patients: Differential Diagnosis and a Practical Approach to Evaluation

open access: yesAnnals of the Child Neurology Society, EarlyView.
ABSTRACT Opsoclonus is an ocular dyskinesia characterized by involuntary, arrhythmic, multidirectional saccades. In pediatrics, opsoclonus is most commonly attributed to the rare neuroinflammatory disorder opsoclonus‐myoclonus‐ataxia syndrome (OMAS), typically considered a paraneoplastic syndrome associated with neural crest tumors. However, opsoclonus
Aubrey C. Reed   +5 more
wiley   +1 more source

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