Results 111 to 120 of about 105,393 (314)

Polyimide‐Linked Hexaazatriphenylene‐Based Porous Organic Polymer with Multiple Redox‐Active Sites as a High‐Capacity Organic Cathode for Lithium‐Ion Batteries

Advanced Materials, EarlyView.
A high‐capacity polyimide‐linked porous organic polymer (HAT‐PTO) incorporating numerous redox‐active centers is synthesized via a hydrothermal reaction, delivering a high theoretical capacity of 484 mAh g−1. In situ hybridization with carboxyl‐functionalized multiwalled carbon nanotubes enhances conductivity and stability, achieving 397 mAh g−1 at C ...
Arindam Mal, Jonathan Caroni, Asia Patriarchi, Olivera Luzanin, Rafael Ramos, Jan Bitenc, Manuel Melle‐Franco, Manuel Souto   +7 more
wiley   +1 more source

Reactive Carbide‐Based Synthesis and Microstructure of NASICON Sodium Metal All Solid‐State Electrolyte

Advanced Materials, EarlyView.
Sodium Metal All‐Solid State Batteries (Na‐ASSBs) are enabled by the synthesis of the solid state electrolyte, NASICON (Na1+xZr2SixP3‐xO12), using carbide‐based precursor compounds (ZrC and SiC); resulting in dense, pure, and mechanically improved microstructure.
Callum J. Campbell, Scott Monismith, Vikalp Raj, Yixian Wang, Qianqian Yan, Cole D. Fincher, Rohit Raj, Yet‐Ming Chiang, John Watt, Josefine D. McBrayer, David Mitlin   +10 more
wiley   +1 more source

Water-shielding electric double layer and stable interphase engineering for durable aqueous zinc-ion batteries

Nature Communications
Aqueous zinc-ion batteries persistently encounter interface issues stemming from the water-rich electrical double layer and unstable solid-electrolyte interphase, drastically compromising reversibility and cyclability.
Zhongyou Peng, Shulong Li, Ling Tang, Jinyang Zheng, Licheng Tan, Yiwang Chen   +5 more
doaj   +1 more source

Comprehensive Understanding of Accelerated Kinetics Driven by Anion–Diluent Dynamics Enabling Wide Temp Operation in Dual‐Ion Batteries

Advanced Materials, EarlyView.
The transient interactions between TFSI− anions and a diluent within an anion‐dictated electrolyte are revealed, which can reduce interfacial reorganization energy, thereby accelerating ion kinetics and markedly facilitating sustainable anion storage in high‐voltage graphite cathodes for dual‐ion batteries at fast charge and wide temperature range ...
Sungho Kim, Youngbi Kim, Heejae Yang, Dongjoo Kim, Jieun Kang, Dokyung Kim, Young Joo Lee, Jeong Woo Han, Jaegeon Ryu, Soojin Park   +9 more
wiley   +1 more source

Synergistic Coupling of Host and Electrolyte Achieving 1270 Wh L−1 in Anode‐Free Lithium Metal Batteries

Advanced Materials, EarlyView.
A synergistic combination of a highly reversible host and a commercially viable carbonate‐rich electrolyte enables simultaneous stabilization of both anode and cathode interfaces in anode‐free lithium metal batteries. This integrated strategy delivers exceptional reversibility and a record volumetric energy density of 1270 Wh L−1 (including package) in
Dong‐Yeob Han, Saehun Kim, Junsu Son, Sangwon Lee, Sungjin Cho, Donghyun Lee, Jiyoon Lee, Tae Kyung Lee, Nam‐Soon Choi, Soojin Park   +9 more
wiley   +1 more source

Trace doping of multiple elements enables stable battery cycling of LiCoO2 at 4.6 V [PDF]

, 2019
LiCoO2 is a dominant cathode material for lithium-ion (Li-ion) batteries due to its high volumetric energy density, which could potentially be further improved by charging to high voltages. However, practical adoption of high-voltage charging is hindered
Chen, L, Chu, Y, Ge, M, Hu, E, Huang, X, Huang, X, Li, H, Li, Q, Li, S, Liu, Y, Ma, C, Ouyang, C, Xiao, R, Yang, W, Yang, XQ, Yu, H, Yu, X, Zhang, JN   +17 more
core  

Correlated Dual‐Gradient Electrodes Enabling Spatially Synchronized Sulfur Redox in High‐Mass‐Loading Li–S Batteries Under High Current Densities

Advanced Materials, EarlyView.
Coupling a dual‐gradient carbonized framework with Fe2O3/Fe‐N‐C catalytic sites enables spatially synchronized sulfur redox across the entire electrode thickness in high‐mass‐loading Li–S batteries. This synergistic structural–catalytic design effectively mitigates concentration, ohmic, and electrochemical polarization, thereby achieving high‐capacity ...
Yuxuan Zhang, Yeongjun Oh, Jinwook Baek, Minyoung Kim, Zachary Didat, Han Wook Song, Sunghwan Lee   +6 more
wiley   +1 more source

Impact of Anode to Cathode Crossover in Lithium‐metal Batteries With High‐Nickel Cathodes

Advanced Materials, EarlyView.
Anode‐to‐cathode chemical crossover is identified as a critical degradation mechanism in lithium‐metal batteries. Full‐cell experiments with high‐Ni layered oxide cathodes and localized high‐concentration electrolytes reveal accelerated cathode impedance growth and CEI thickening driven by lithium‐metal anodes. The findings underscore the importance of
Zezhou Guo, Andrei Dolocan, Arumugam Manthiram   +2 more
wiley   +1 more source

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, 2018
Department of Energy Engineering (Battery Science and Technology)Aprotic electrolyte based lithium-oxygen batteries are of considerable interest due to its ultrahigh theoretical specific energy density (1675 mAh per gram of oxygen) against the present ...
Cha, Aming
core  

Non-linearity of the solid-electrolyte-interphase overpotential [PDF]

Electrochimica Acta, 2017
In today's modeling and analysis of electrochemical cycling of Li- and Na-ion batteries, an assumption is often made regarding the interphase that forms between the active material and liquid electrolyte at low potentials, the so-called solid-electrolyte interphase (SEI).
openaire   +2 more sources