Pre-Constructed Mechano-Electrochemical Adaptive Solid Electrolyte Interphase to Enhance Li<sup>+</sup> Diffusion Kinetics and Interface Stability for Chemically Prelithiated SiO Anodes. [PDF]
Wang Z +10 more
europepmc +1 more source
Frontier orbital energy engineering of PTFE by incorporating electron‐withdrawing oxygen‐ and nitrogen‐containing functional groups alters the local electronic environment and elevates the LUMO energy. This molecular modification strategy suppresses reduction‐induced side reactions in dry‐processed anodes.
Minsung Kim +6 more
wiley +1 more source
Zinc anode performance is maximized within an optimal deposition‐kinetic window. Additives that tune the deposition exchange current density (i0,Dep) suppress HER at intermediate values, but overly fast kinetics promote dendrites and overly slow kinetics accelerate corrosion/HER.
Md. Arif Faisal +7 more
wiley +2 more sources
Dipole-dipole interaction-induced dense primitive solid-electrolyte interphase for high-power Ah-level anode-free sodium metal batteries. [PDF]
Huang J +6 more
europepmc +1 more source
Abstract A multipore, multiphase, continuum model is assembled for the first time for room temperature sodium–sulfur (RT Na–S) batteries, with Na+ ion transport and redox reactions in the liquid electrolyte phase and semisolid phase of precipitates softened by the electrolyte solvent, as guided by molecular dynamics simulations in this study ...
Hakeem A. Adeoye +3 more
wiley +1 more source
On the Role of Reaction Current Distribution to Attain Competitive Solid‐State Batteries
We conducted a case study on reaction current inhomogeneities when increasing areal loadings and charging rates in NCM‐argyrodite composite cathodes for solid‐state batteries. Using a combination of cycling experiments and operando high‐energy X‐ray diffraction, we show that employing faster conducting Li5.5PS4.5Cl1.5 instead of Li6PS5Cl as catholyte ...
Johannes Hartel +8 more
wiley +2 more sources
Formation and Evolution of the Solid Electrolyte Interphase on Silicon Electrodes from Fluorine-Free Electrolytes. [PDF]
Lu Z +6 more
europepmc +1 more source
Information Dense and Industry Scalable Accelerated Formation
Pulsed formation can reduce lithium‐ion battery formation time by over 50% while maintaining or enhancing performance. Validated on 25 Ah prismatic cells, this industry‐scalable method yields thinner, more homogeneous solid electrolyte interphases (SEIs).
Leon Merker +3 more
wiley +1 more source
Electrochemical activation is critical for enhancing the performance of Li‐ and Mn‐rich (LMR) cathodes, however, the underlying mechanism has not been fully understood. A spinel‐like phase is found within the C2/m domains of LMR after activation, where above a critical activation voltage is needed. ABSTRACT Electrochemical activation is a critical step
Peng Zuo +2 more
wiley +2 more sources
Artificial Solid Electrolyte Interphase Developed In Vitro by Tailoring Molecular Layer Deposition of a Li-Ion-Containing Electrolyte on Carbonaceous Anode Materials. [PDF]
Fedorov RG +7 more
europepmc +1 more source

