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Proximity Matters: Interfacial Solvation Dictates Solid Electrolyte Interphase Composition

Nano Letters, 2023
The composition of the solid electrolyte interphase (SEI) plays an important role in controlling Li-electrolyte reactions, but the underlying cause of SEI composition differences between electrolytes remains unclear. Many studies correlate SEI composition with the bulk solvation of Li ions in the electrolyte, but this correlation does not fully capture
Solomon T. Oyakhire   +9 more
openaire   +2 more sources

Molecularly Woven Artificial Solid Electrolyte Interphase

Angewandte Chemie
Abstract Lithium‐metal batteries (LMBs) are the most promising candidates for next‐generation high‐energy‐density storage systems, but they suffer from destructive dendrite growth. Here, we integrate cutting‐edge molecular weaving technology into the fabrication of artificial solid electrolyte interphases (ASEI ...
Tianyu Shan   +10 more
openaire   +2 more sources

Solid Electrolyte Interphase on Lithium Metal Anodes

ChemSusChem
AbstractLithium metal batteries (LMBs) represent the most promising next‐generation high‐energy density batteries. The solid electrolyte interphase (SEI) film on the lithium metal anode plays a crucial role in regulating lithium deposition and improving the cycling performance of LMBs. In this review, we comprehensively present the formation process of
Zhichuan Shen   +5 more
openaire   +2 more sources

Solid-Electrolyte-Interphase: Characterization by Impedance Spectroscopy

ECS Meeting Abstracts, 2009
Abstract not Available.
George Harriott   +4 more
openaire   +1 more source

Single-Component Solid Electrolyte Interphases on Lithium

ECS Meeting Abstracts, 2019
The ability to utilize Li metal anodes in rechargeable batteries would be an enabling breakthrough in the quest to increase energy density and meet current aggressive performance targets (> 350 Wh/kg) for electric vehicles. However, Li anodes face several persistent challenges:1 ,2 (1) Large volume expansion upon cycling, leading
Betar M. Gallant, Mingfu He, Rui Guo
openaire   +1 more source

Protective Oxide Coating for Ionic Conductive Solid Electrolyte Interphase

ACS Applied Materials & Interfaces, 2016
To employ Li-based batteries to their full potential in a wide range of energy-storage applications, their capacity and performance stability must be improved. Si is a viable anode material for Li-based batteries in electric vehicles due to its high theoretical capacity and good economic feasibility.
Yong Su, Kim   +10 more
openaire   +2 more sources

Structural Properties of Solid Electrolyte Interphase on Lithium Metal

Journal of Nanoscience and Nanotechnology, 2015
To gain an understanding of the structural properties of the solid electrolyte interphase (SEI) created on the surface of lithium during an electrochemical deposition/dissolution reaction in propylene carbonate (PC) containing different concentrations of LiClO4 (1.09, 3.27 mol kg(-1)), the surface of lithium was examined through transmission electron ...
Soon-Ki, Jeong   +2 more
openaire   +2 more sources

In Situ and Quantitative Characterization of Solid Electrolyte Interphases

Nano Letters, 2014
Despite its importance in dictating electrochemical reversibility and cell chemistry kinetics, the solid electrolyte interphase (SEI) on graphitic anodes remains the least understood component in Li ion batteries due to its trace presence, delicate chemical nature, heterogeneity in morphology, elusive formation mechanism, and lack of reliable in situ ...
Arthur, v Cresce   +4 more
openaire   +2 more sources

Regulating Li deposition at artificial solid electrolyte interphases

Journal of Materials Chemistry A, 2017
An artificial solid electrolyte interphases (SEI) layer was established on the lithium metal anode via magnetron sputtering deposition for promoting uniform lithium electrodeposition.
Lei Fan   +4 more
openaire   +1 more source

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