Results 81 to 90 of about 5,746 (260)

Regulating Solvent‐Separated Ion Pairs to Control Polysulfide Redox for Fast and Stable Room‐Temperature Na‐S Batteries

Advanced Science, EarlyView.
A local high‐concentration electrolyte with tailored solvent‐separated ion pairs is pioneered to design for room‐temperature sodium‐sulfur batteries. This electrolyte allows sparingly dissolved polysulfides and localizes them onto reactive interfaces for liquid‐solid conversion.
Xiang‐Long Huang, Xue Li, Hengjia Shao, Xinran Gao, Zhengzhao Huang, Lingfei Zhao, Long Yao, Kunjie Zhu, Fu‐Sheng Ke, Hua‐Kun Liu, Wei‐Hong Lai, Yun‐Xiao Wang   +11 more
wiley   +1 more source

Polyrotaxane‐Assembled Semi‐Interpenetrating Polymer Electrolytes Enabling High‐Voltage Lithium Metal Batteries

Advanced Science, EarlyView.
This work develops a polyrotaxane‐based supramolecular semi‐interpenetrating network electrolyte. Its unique architecture decouples ion transport, achieving high ionic conductivity (0.18 mS cm−1), a superior Li+ transference number (> 0.73), and an extended electrochemical window (> 4.9 V), thereby significantly enhancing the performance of high ...
Tianyi Wang, Yue Ma, Jiacheng Liu, Zhaofan He, Jin Liang, Kailiang Ren, Jie Kong   +6 more
wiley   +1 more source

2D Metal‐Organic Frameworks for High‐Performance Solid‐State Electrolytes: A Comprehensive Review

Advanced Science, EarlyView.
In this review, we elucidate the intrinsic advantages, synthetic methodologies, structural characteristics, ion‐transport mechanisms and performance optimization strategies while highlighting representative material systems and applications of 2D MOFs for electrolyte applications.
Changchun Ai, Yuan Tian, Yilei Shu, Peng Hang, Wentao Li, Yiling Yao, Huijuan Guo, Qun Yi, Hongmei Dai   +8 more
wiley   +1 more source

Boosting Fast‐Charging Performance of Ni‐Rich NCM9055 Cathodes with Nb2O5 Dual Functional Modification

Advanced Science, EarlyView.
A dual‐functional Nb2O5 modulation strategy is reported to overcome kinetic limitations in Ni‐rich cathodes. The formation of LiNbO3 phase at the grain boundary of the polycrystalline NCM9055 cathode preserves a radially aligned microstructure and establishes fast lithium‐ion pathways.
Tian Rao, Zhaowen Bai, Jian Wang, Yang Ren, Qingsong Weng, Zhongzhu Liu, Maxim Avdeev, Robson Monteiro, Luanna Parreira, Xuejie Huang, Guohua Chen, Yongming Zhu   +11 more
wiley   +1 more source

Bioinspired Microphase‐Engineered Binders for Silicon Anodes

Advanced Science, EarlyView.
Inspired by the tough exoskeleton of Phloeodes diabolicus, a bio‐based binder featuring LRA–click chemistry and hierarchical crosslinking forms well‐defined microphase‐separated structures that enable robust silicon anodes. This system promotes the formation of a LiF–rich, ultrathin SEI (∼17 nm) with high modulus and ionic conductivity, ensuring long ...
Lirong Tang, Lan Zhao, Zhiyi Cao, Fengcai Lin, Biao Huang, Haijun Li, Lingling Qian, Yingshan Shi, Yaohang Weng, Xuan Yang, Hanyang Liu, Beili Lu, Jianhua Lv, Xinda You, Jiayu Tao, Zhenwei Wu   +15 more
wiley   +1 more source

Induction Effect of Fluorine-Grafted Polymer-Based Electrolytes for High-Performance Lithium Metal Batteries

Nano-Micro Letters
Highlights Fluorine-grafted quasi-solid-state composite electrolyte (F-QSCE)@30 exhibits high ionic conductivity of 1.21 mS cm–1 at 25 °C. The inductive effect weakens the coordination between Li+ and TFSI‒, enhancing Li+ transport.
Haiman Hu, Jiajia Li, Fei Lin, Jiaqi Huang, Huaiyang Zheng, Haitao Zhang, Xiaoyan Ji   +6 more
doaj   +1 more source

A reversible dendrite-free high-areal-capacity lithium metal electrode

Nature Communications, 2017
Despite recent technological advances, it remains challenging to realize reversible high-areal-capacity lithium metal anodes. Here, the authors demonstrate such an anode by tailoring the top solid electrolyte interphase layer.
Hui Wang, Masaki Matsui, Hiroko Kuwata, Hidetoshi Sonoki, Yasuaki Matsuda, Xuefu Shang, Yasuo Takeda, Osamu Yamamoto, Nobuyuki Imanishi   +8 more
doaj   +1 more source

Review: Insight on Porous Carbon Positive Electrode for Sodium‐Ion Capacitors: Interplay Between Synthesis, Properties, and Performance

Advanced Science, EarlyView.
Sodium ion capacitor (SIC) is currently constrained by the low discharge capacity of commercial activated carbon as positive electrode material. This review provides a holistic summary of research efforts on alternative porous carbon materials for SIC. Image created by the authors with www.biorender.com.
Ademola Adeniji, Adrian Beda, Camélia Matei Ghimbeu   +2 more
wiley   +1 more source

A Si‐MoSe2 Heterostructured Anode with Enhanced Thermal Transport and Electrochemical Performance for Liquid and All‐Solid‐State Lithium‐Ion Batteries

Advanced Science, EarlyView.
Chemically bonded Si@MoSe2@C heterointerfaces with robust Si─Se─Mo bonds enable high‐performance Si anodes. Lattice‐matched MoSe2 on porous Si with carbon‐protective coating delivers 1054 mAh g−1 after 100 cycles and 99.5% Coulombic efficiency over 400 cycles.
Yajun Zhu, Jiaqi Gu, Guangwu Zhang, Tianli Han, Yang Lu, Zhongbing Li, Hang Su, Fei Wang, Haojun Xu, Wentuan Bi, Qiye Zheng, Jinyun Liu   +11 more
wiley   +1 more source

In‐Operando FTIR Study to Investigate the Effect of Varying Lithium Salts on Solid Electrolyte Interface (SEI) Evolution in Lithium Metal Batteries

Advanced Science, EarlyView.
A clear correlation between electrolyte salt chemistry and Solid Electrolyte Interface (SEI) performance in lithium metal batteries is established using in operando FTIR spectroscopy. This study shows that LiTFSI instantaneously forms a robust, inorganic organic hybrid SEI (LiF, Li3N, Li2O, ROCO2Li, ROLi) that minimizes overpotential, while less ...
Samia Rahman, Rhyz Pereira, Jantakan Nedsaengtip, Vibha Kalra   +3 more
wiley   +1 more source