Results 81 to 90 of about 1,733,188 (294)

An Electrochemical Perspective of Aqueous Zinc Metal Anode

Nano-Micro Letters, 2023
Highlights Detailed discussion and summary of aqueous electrolyte chemistry, parasitic reactions chemistry, and storage energy chemistry and their relationship in aqueous zinc ions batteries are conducted.
Huibo Yan, Songmei Li, Jinyan Zhong, Bin Li   +3 more
doaj   +1 more source

Particle‐Level ZrO2 Atomic Layer Deposition Enables Fast‐Cycling and Long‐Life Graphite Cathodes for Dual‐Ion Batteries

Advanced Functional Materials, EarlyView.
A spatial location of atomic layer deposition (ALD)‐derived ZrO2 coatings is demonstrated to be a critical design parameter for stabilizing graphite cathodes in DIBs. Direct particle‐level ALD (PALD) screening of representative metal oxides identified ZrO2 as the coating that provides the most favorable balance of high‐rate capability and interfacial ...
Jieun Kang, Sung Eun Jo, Yunah Ji, Dongjoo Kim, Sungho Kim, Jaegeon Ryu, Jihwan An, Soojin Park   +7 more
wiley   +1 more source

Electrolyte Engineering toward Rational Electrode–Electrolyte Interfacial Designs for Metal Batteries

Advanced Science
Lithium, zinc, sodium, potassium, and magnesium metal batteries have emerged as the core direction of next‐generation energy storage technologies due to their ultrahigh theoretical capacities.
Yunlong Yang, Xuchao Yang, Xinle Liu, Lei Zhao, Dongxia Luo, Zhihua Hai, Yuantong Guo, Hongquan Niu, Fen Ran   +8 more
doaj   +1 more source

Reversible Deposition and Stripping of the Cathode Electrolyte Interphase on Li2RuO3

Frontiers in Chemistry, 2020
Performance decline in Li-excess cathodes is generally attributed to structural degradation at the electrode-electrolyte interphase, including transition metal migration into the lithium layer and oxygen evolution into the electrolyte.
Julia C. Hestenes, Andrew W. Ells, Mateo Navarro Goldaraz, Ivan V. Sergeyev, Boris Itin, Lauren E. Marbella   +5 more
doaj   +1 more source

Engineering a Fluorinated AlPO4 Interface: Toward High Initial Coulombic Efficiency and Stable Oxygen Redox in Li‐Rich Layered Oxide Cathodes

Advanced Functional Materials, EarlyView.
We report a chemically incorporated fluorinated AlPO4 (AlPO4‐F) architecture that functions as a multifunctional “interfacial fortress” for Li‐rich layered oxides (LLOs). By modulating the surface potential to –32.16 mV, this architecture enriches Li+ concentration and repels detrimental electrolyte anions.
Hojun Moon, Harim Jeong, Younghwon Kim, Buseong Kim, Geunhyeong Kim, Suyeon Lee, Jeongjin Lee, Joonwoo Kim, Jemin Lee, Youngsoo Kim, Young‐Il Kim, Dae Won Cho, Jeeyoung Yoo, Misook Kang   +13 more
wiley   +1 more source

Designing solid-liquid interphases for sodium batteries

Nature Communications, 2017
The chemistry at the interface between electrolyte and electrode plays a critical role in determining battery performance. Here, the authors show that a NaBr enriched solid–electrolyte interphase can lower the surface diffusion barrier for sodium ions ...
Snehashis Choudhury, Shuya Wei, Yalcin Ozhabes, Deniz Gunceler, Michael J. Zachman, Zhengyuan Tu, Jung Hwan Shin, Pooja Nath, Akanksha Agrawal, Lena F. Kourkoutis, Tomas A. Arias, Lynden A. Archer   +11 more
doaj   +1 more source

Multinuclear solid-state NMR study of the aqueous solid-electrolyte interphase formation in NaTi2(PO4)3 / [PDF]

Solid-electrolyte interphases enable stable operation of non-aqueous Li-ion batteries, but their formation, especially in aqueous systems, is not well understood.
Dubauskas, Aurimas,, Traškina, Nadežda,, Manionis, Matas,, Klimavičius, Vytautas,, Vilčiauskas, Linas,, Pilipavičius, Jurgis,   +5 more
core   +1 more source

Mechanistic Origins of Chemo‐Mechanical Instability and Failure in Solid‐State Lithium‐Sulfur Electrodes

Advanced Functional Materials, EarlyView.
Conversion‐induced sulfur expansion generates strong mechanical constraints and localized stresses within solid‐state Li‐S cathodes. Heterogeneous solid‐electrolyte confinement creates tensile strain‐energy hotspots that govern particle cracking. Larger sulfur particles accelerate fracture, while higher porosity relaxes constraint and delays damage ...
Arpan K. Sharma, Ahmad Ahmad, Bairav S. Vishnugopi, Partha P. Mukherjee   +3 more
wiley   +1 more source

Exploring the Impact of In Situ-Formed Solid-Electrolyte Interphase on the Cycling Performance of Aluminum Metal Anodes

Unwanted processes in metal anode batteries, e.g., non-uniform metal electrodeposition, electrolyte decomposition, and/or short-circuiting, are not fully captured by the electrolyte bulk solvation structure but rather defined by the electrode−electrolyte
Ahmed, Nashaat, Yu, Chengzhong, Rakov, Dmitrii A., Kong, Y., Rakov, D.A., Ahmed, N., Nanjundan, A.K., Popov, I., Huang, X., Nanjundan, Ashok Kumar, Sokolov, Alexei P., Kong, Yueqi, Sokolov, A.P., Huang, Xiaodan, Popov, Ivan, Yu, C.   +15 more
core   +1 more source

Interfacial Failure and Self‐Healing in Solid‐State Batteries

Advanced Materials, EarlyView.
Dynamic interfacial self‐healing offers an adaptive route to mitigate coupled mechanical, chemical, and electrochemical degradation in solid‐state batteries. This review connects evolving interfacial failure mechanisms with physical‐flow, chemical‐restoration, stimuli‐responsive, and electric‐field‐assisted repair strategies, highlighting targeted self‐
Xinxin Zhu, Tengfei Dai, Wendi Dou, Zhiheng Li, Kaihua Wen, Yanqun Lv, Ming Zhao, Jun Lu, Zaiping Guo   +8 more
wiley   +1 more source