Results 101 to 110 of about 110,995 (308)

How Solid-Electrolyte Interphase Forms in Aqueous Electrolytes

open access: yesJournal of the American Chemical Society, 2017
Solid-electrolyte interphase (SEI) is the key component that enables all advanced electrochemical devices, the best representative of which is Li-ion battery (LIB). It kinetically stabilizes electrolytes at potentials far beyond their thermodynamic stability limits, so that cell reactions could proceed reversibly.
Liumin Suo   +15 more
openaire   +3 more sources

Polarizable Vanadium Dipoles Promote Water Dissociation on Vanadium‐Based Metal Organic Framework

open access: yesAdvanced Functional Materials, EarlyView.
The polarization of unpaired V 3d electrons weakens the H─O bond to improve water dissociation by the dual Vδ+:O─H and Pλ−:H─O coupling hydrogen bonds formation and relaxation. P@V‐MOF electrocatalyst shows low overpotentials (94 mV in acid, 178 mV in neutral, and 77 mV in alkaline solutions) with excellent stability for effective overall water ...
Xinjuan Liu   +13 more
wiley   +1 more source

Solid electrolytes and solid-state batteries [PDF]

open access: yesAIP Conference Proceedings, 2016
Solid-state batteries are regarded as reliable battery systems that overcome some issues in current lithium-ion batteries originated from the organic-solvent electrolytes; however, their power densities have not been high enough to practical use. Intensive studies aiming at the improvement of the rate capability have provided solid electrolytes with ...
openaire   +1 more source

Receptor‐Free Identification of Toxic Gases Enabled by Hygroscopic Aqueous Salt Films

open access: yesAdvanced Functional Materials, EarlyView.
Water as a gas sensor coating sounds impossible—until it stops evaporating. Here, hygroscopic salt solutions (LiCl, LiBr, H3PO4) form non‐drying aqueous films on CNT chemiresistors under ambient air. Gases partition into these liquid layers, sometimes transforming into water, and generate salt‐specific resistance fingerprints across a four‐channel ...
Seongwoo Lee   +5 more
wiley   +1 more source

Mathematical modelling of the catalyst layer of a polymer-electrolyte fuel cell [PDF]

open access: yes, 2007
In this paper we derive a mathematical model for the cathode catalyst layer of a polymer electrolyte fuel cell. The model explicitly incorporates the restriction placed on oxygen in reaching the reaction sites, capturing the experimentally observed fall ...
Shah, A., Promislow, K., Kim, G.S.
core  

Fast Charge–Discharge of LiNi0.9Co0.05Mn0.05 Enabled by a Bikitaite‐Infused Separator for Li Metal Batteries

open access: yesAdvanced Functional Materials, EarlyView.
A bikitaite‐infused cellulose separator is introduced for Li metal batteries, leveraging bikitaite zeolite's ion‐conductive properties to regulate Li+‐ion flux and suppress dendrite growth. The membrane design ensures uniform Li plating, enhanced electrolyte wettability, and robust thermal/mechanical stability, delivering stable performance and low ...
Isheunesu Phiri   +2 more
wiley   +1 more source

Argyrodite Solid Electrolyte-Integrated Ni-Rich Oxide Cathode with Enhanced Interfacial Compatibility for All-Solid-State Lithium Batteries [PDF]

open access: yes
All-solid-state lithium batteries (ASSLBs) paired with an argyrodite sulfide solid electrolyte have become a candidate to take the world by storm for achieving high energy and safety.
Jun Zhang (48506)   +8 more
core   +1 more source

X‐Functionality–Driven Photocatalytic Hydrogen Evolution in 2D 4‐X‐PEA2SnI4 Perovskites

open access: yesAdvanced Functional Materials, EarlyView.
We report a water‐based synthesis of 2D 4‐X‐PEA2SnI4 perovskite microcrystals with prominent photocatalytic (PC) activity for H2 production. The synergy between organic functionalization and HI‐derived iodide scavenges holes suppress octahedral distortion, and favor electron accumulation, enabling a PC H2 evolution ∼20 µmol·g−1 and long‐term stability ...
Taeyeon Kim   +21 more
wiley   +1 more source

PEO Electrolyte As Interlayer for Li Metal Battery Comprising an Halide Based Hybrid Electrolyte [PDF]

open access: yes
International audienceIn the context of the energetic transition, lithium (Li) metal is considered as the most promising material for battery anode electrodes regarding its physico-chemical and electrochemical properties with its high capacity leading to
Boulmier, Thomas   +6 more
core   +2 more sources

Polymer Interface Enables Reversible Quasi‐Solid Sulfur Conversion in Sodium‐Sulfur Batteries

open access: yesAdvanced Functional Materials, EarlyView.
The polymer interface enables a stable quasi‐solid sulfur conversion pathway in room‐temperature Na─S batteries. The coating regulates Na+ transport, stabilizes the cathode–electrolyte interphase, and accommodates mechanical stress, suppressing electrolyte decomposition and sulfur migration, thereby improving reaction uniformity, reducing polarization,
Reza Andaveh   +12 more
wiley   +1 more source

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