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Long term porosity of solid electrolyte interphase on model silicon anodes with liquid battery electrolytes. [PDF]
Commun ChemGrill J, Popovic-Neuber J.
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Electrochimica Acta, 1977
New Li-ion conductors with several different structure types are reported. Li4B7O12(Cl,Br) and LiM2P3O12 (MZr, Hf) have framework structures. The others are based on structures with isolated polyhedra in a network of edge-linked Li polyhedra and include Li2+xC1−xBxO3, Li3−x B1−xCxO3, Li4+xSi1−xSi1−xAlxO4, Li4−xSi1−xPxO4, Li4−2xSi1−xSxO4 and Li 5−xAl1 ...
R.D. SHANNON +3 more
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New Li-ion conductors with several different structure types are reported. Li4B7O12(Cl,Br) and LiM2P3O12 (MZr, Hf) have framework structures. The others are based on structures with isolated polyhedra in a network of edge-linked Li polyhedra and include Li2+xC1−xBxO3, Li3−x B1−xCxO3, Li4+xSi1−xSi1−xAlxO4, Li4−xSi1−xPxO4, Li4−2xSi1−xSxO4 and Li 5−xAl1 ...
R.D. SHANNON +3 more
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Solid Ionics—Solid Electrolyte Cells
Journal of The Electrochemical Society, 1970The characteristics of the solid electrolyte cells Ag /RbAg4IJTe and Ag/RbAg4Is/Se have been studied. The open-circui t voltages of these solid electrolyte cells were 0.217V and 0.265V, respectively, at 20~ These cells could discharge in the temperature range of --75 ~ to 150~ Only a small polarization was observed at relat ively high current density ...
Takehiko Takahashi, Osamu Yamamoto
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Russian Journal of Electrochemistry, 2010
Studies of composite ionic conductors are overviewed. Mechanisms of defect formation at ionic crystal surfaces and at interphase boundaries in the composites are discussed; the Stern model that allows calculating surface potential has been involved.
N. F. Uvarov +2 more
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Studies of composite ionic conductors are overviewed. Mechanisms of defect formation at ionic crystal surfaces and at interphase boundaries in the composites are discussed; the Stern model that allows calculating surface potential has been involved.
N. F. Uvarov +2 more
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Berichte der Bunsengesellschaft für physikalische Chemie, 1989
AbstractA review of recent progress in the science and applications of solid electrolytes is given. This includes the development of new materials, both as ionic and mixed ionic/electronic conductors, improved understanding of conduction mechanisms and the factors that led to high ionic conductivity in solids and increased applications in batteries ...
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AbstractA review of recent progress in the science and applications of solid electrolytes is given. This includes the development of new materials, both as ionic and mixed ionic/electronic conductors, improved understanding of conduction mechanisms and the factors that led to high ionic conductivity in solids and increased applications in batteries ...
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ECS Meeting Abstracts, 2014
Solid state batteries offer significant advantages over today’s cells containing liquid electrolytes. In large format cells required for automotive applications, replacement of volatile, flammable organic solvents with a solid phase electrolyte eliminates safety concerns.
Dee Strand, Marissa Caldwell
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Solid state batteries offer significant advantages over today’s cells containing liquid electrolytes. In large format cells required for automotive applications, replacement of volatile, flammable organic solvents with a solid phase electrolyte eliminates safety concerns.
Dee Strand, Marissa Caldwell
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1976
A solid electrolyte should consist of a rigid, three-dimensional network, stabilized by electrons donated by mobile ions which partially occupy a two or three-dimensionally linked interstitial space. Such networks may be classified into three groups, depending on whether the three-dimensional., rigid skeleton is built from tetrahedra, octahedra, or a ...
H. Y-P Hong +3 more
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A solid electrolyte should consist of a rigid, three-dimensional network, stabilized by electrons donated by mobile ions which partially occupy a two or three-dimensionally linked interstitial space. Such networks may be classified into three groups, depending on whether the three-dimensional., rigid skeleton is built from tetrahedra, octahedra, or a ...
H. Y-P Hong +3 more
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Surface Science, 1980
Abstract Tunnelling is a useful concept in nonadiabatic solid-electrolyte processes in cases where the barrier is sufficiently unambiguously characterized, such as electron transfer at film-covered metal electrodes and through the space charge layer of semiconductors.
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Abstract Tunnelling is a useful concept in nonadiabatic solid-electrolyte processes in cases where the barrier is sufficiently unambiguously characterized, such as electron transfer at film-covered metal electrodes and through the space charge layer of semiconductors.
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Polyphosphazene solid electrolytes
Journal of the American Chemical Society, 1984Abstract : The phosphazene polymer (NP(OC2H40C2H4OCH3)n, MEEP, was synthesized and amorphous solvent-free salt complexes were performed with LiSo3CF3, NaSO3CF3, Sr(SO3CF3)2, and AgSO3CF3. A material with the composition (LiSO3CF3)0.25. MEEP has a conductivity of .00008 ohm/cm at 30 C, which is much higher than corresponding poly (ethylene oxide ...
Peter M. Blonsky +3 more
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