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Interface Engineering of All‐Solid‐State Batteries Based on Inorganic Solid Electrolytes
ChemSusChem, 2023AbstractAll‐solid‐state batteries (ASSBs) based on inorganic solid electrolytes (SEs) are one of the most promising strategies for next‐generation energy storage systems and electronic devices due to the higher energy density and intrinsic safety. However, the poor solid‐solid contact and restricted chemical/electrochemical stability of inorganic SEs ...
Lei Xi +7 more
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ECS Meeting Abstracts, 2023
Meeting the promise of all-solid-state batteries will require solid electrolytes that have high metal ion conductivity, low electronic conductivity, are electrochemically stable at both low and high potential, and have sufficiently high critical current density to avoid metal dendrite penetration.
Matthew Ko +4 more
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Meeting the promise of all-solid-state batteries will require solid electrolytes that have high metal ion conductivity, low electronic conductivity, are electrochemically stable at both low and high potential, and have sufficiently high critical current density to avoid metal dendrite penetration.
Matthew Ko +4 more
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A Theory of Surface Conductance at an Electrolyte-Solid Interface
Physics, 1932An expression has been derived on the basis of the Maxwell-Boltzmann distribution and Poisson's equation for the tangential surface conductance of an electrolyte in contact with a charged plane surface. One part of this expression is analogous to the result given by Smoluchowski for a Helmholtz double layer, while the second part arises from the ...
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Accounts of Chemical Research, 2017
Electrode-electrolyte interfacial properties play a vital role in the cycling performance of lithium-sulfur (Li-S) batteries. The issues at an electrode-electrolyte interface include electrochemical and chemical reactions occurring at the interface, formation mechanism of interfacial layers, compositional/structural characteristics of the interfacial ...
Xingwen Yu, Arumugam Manthiram
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Electrode-electrolyte interfacial properties play a vital role in the cycling performance of lithium-sulfur (Li-S) batteries. The issues at an electrode-electrolyte interface include electrochemical and chemical reactions occurring at the interface, formation mechanism of interfacial layers, compositional/structural characteristics of the interfacial ...
Xingwen Yu, Arumugam Manthiram
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Nano Letters, 2017
Li-ion batteries (LIB) have been successfully commercialized after the identification of ethylene-carbonate (EC)-containing electrolyte that can form a stable solid electrolyte interphase (SEI) on carbon anode surface to passivate further side reactions but still enable the transportation of the Li+ cation.
Dongping Lu +15 more
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Li-ion batteries (LIB) have been successfully commercialized after the identification of ethylene-carbonate (EC)-containing electrolyte that can form a stable solid electrolyte interphase (SEI) on carbon anode surface to passivate further side reactions but still enable the transportation of the Li+ cation.
Dongping Lu +15 more
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Comprehensive Insights into Electrolytes and Solid Electrolyte Interfaces in Potassium-Ion Batteries
Energy Storage Materials, 2021Abstract Potassium-ion batteries (KIBs) are competitive alternatives to lithium-ion batteries (LIBs) due to the abundant K resources and high energy density. As an indispensable part of the battery, the electrolyte affects the battery capacity, rate capability, cycle life, and safety.
Xiao Zhang +5 more
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The Solid/Electrolyte Interface
1983The solid/electrolyte interface is considered at four levels: the interface in the absence of solvent or solution; the interface in relation to adsorbed, oriented solvent dipoles when the solid is in contact with a solution; the interface when adsorbed ions are present, giving rise to an ionic double-layer, and the consequences of interaction of these ...
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Interdiffusion across solid electrolyte-electrode interface
Applied Physics Letters, 2014A phase-field model is developed for studying the cation interdiffusion across electrolyte-electrode interfaces in solid oxide fuel cell (SOFC) that can be contributing to long timescale performance degradation. Demonstrated on an interface between an 8%molY2O3-stabilized ZrO2 and a La0.65Sr0.3MnO3−x typically used in SOFC, time-dependent evolution of ...
Jia-Mian Hu +5 more
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Electrochemical processes at the interface between solid electrolyte and liquid electrolyte
Solid State Ionics, 1989Abstract The ac impedance of the interface between beta-alumina membrane and molten mixtures CO(NH2)2+NaI+I2 or (C4H9)4Ni+I2 can be represented by parallel combination of a charge transfer resistance RF and Warburg impedance Z W =(1−j) W ω − 1 2 . The value of RF depends on electronic state of solid electrolyte.
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Methodology for ion neutralization at solid/electrolyte interfaces
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 1986Abstract When ion scattering from a solid/electrolyte is studied, the complexity of the system mandates the use of simple models. To this end, the two-level approach is adopted to investigate the surface ion neutralization process in a binary-collision model of ion scattering from a solid surface.
S.G. Davison, K.W. Sulston, A.T. Amos
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