Results 221 to 230 of about 2,631,999 (304)

Phase Diagrams Enable Solid‐State Battery Design

open access: yesAdvanced Materials Interfaces, EarlyView.
Batteries are non‐equilibrium devices with inherent thermodynamic driving forces to react at interfaces, regardless of kinetics or operating conditions. Chemical potential mismatches across interfaces are dissipated via interfacial reactions. In this work, it is illustrated how phase diagrams and chemical potential maps predict degradation pathways but
Nathaniel L. Skeele, Matthias T. Agne
wiley   +1 more source

Tailor‐Made Protective LixAlSy Layer for Lithium Anodes to Enhance the Stability of Solid‐State Lithium–Sulfur Batteries

open access: yesAdvanced Materials Interfaces, EarlyView.
An intentionally added, chemically formed LixAlSy coating stabilizes the lithium–electrolyte interface in solid‐state Li–S batteries. The layer suppresses side reactions, preserves smooth charge transfer, and improves ion transport from the start. This approach offers a practical route to more durable solid‐state batteries and a clearer understanding ...
Xinyi Wang   +4 more
wiley   +1 more source

A Family of Sodium Solid‐State Electrolytes Based on the NaGaxAl1‐xCl4 Solid Solution

open access: yesAdvanced Materials Interfaces, EarlyView.
ABSTRACT Sodium‐based metal chloride solid electrolytes are promising for sodium solid‐state batteries due to their excellent oxidation stability, which, as shown for Li halides, can coexist with high ionic conductivity. To explore cationic substitution effects, we synthesized NaGaxAl1‐xCl4 (0 ≤ x ≤ 1) via ball milling and investigated structural and ...
Hao Guo, Matteo Bianchini
wiley   +1 more source

Binder‐Free Direct Ink Writing of Li6.4La3Zr1.4Ta0.6O12 Garnet Electrolytes for All‐Solid‐State Batteries

open access: yesAdvanced Materials Interfaces, EarlyView.
Polymer binders and thick pressed LLZTO pellets limit all‐solid‐state battery integration through grain‐boundary carbon and high ohmic losses. A binder‐free capillary suspension ink is direct‐ink‐written and sintered into 254 μm$\mu{\rm m}$, 95.8%‐dense Ta‐stabilized LLZTO with 17.3 mS cm−1$\text{cm}^{-1}$ bulk conductivity, enabling thinner ...
Sri Vaishnavi Thummalapalli   +7 more
wiley   +1 more source

2D Hierarchical Black Phosphorus‐Mn2O3 Heterostructured Composites for High‐Performance Flexible Supercapacitors

open access: yesAdvanced Materials Interfaces, EarlyView.
A sonochemical strategy constructs an ex situ 2D hierarchical black phosphorus–Mn2O3 heterostructure, enabling intimate interfacial coupling, enhanced charge transport, and improved electrochemical stability. The optimized BPM‐37.5% electrode delivers 466 F g−1 with 84% retention after 8000 cycles, while the flexible device exhibits high areal energy ...
Sowmiya Selvaraj   +1 more
wiley   +1 more source

Conformal Coating and Transfer of 2D Nanomaterials via Dynamic Interface Engineering

open access: yesAdvanced Materials Interfaces, EarlyView.
This review discusses conformal coating and transfer of two‐dimensional (2D) nanomaterials with a focus on dynamic interface engineering. By actively regulating nanosheet transport and interfacial contact during film formation, recent dynamic coating strategies overcome the limitations of conventional passive approaches and enable geometry‐adaptive ...
Seungyeon Kim   +4 more
wiley   +1 more source

Beyond Passivation: Designing Structurally Tailored Artificial Interphases for High‐Energy Lithium‐Based Anodes

open access: yesAdvanced Materials Interfaces, EarlyView.
This review outlines critical engineering design rules for building artificial protective coatings on next‐generation lithium metal and silicon battery anodes. It highlights how balancing structural flexibility with strict electronic and ionic transport limits prevents early battery failure.
Surin Gupte, Vilas G. Pol
wiley   +1 more source

Development of a Solid‐Liquid Hybrid Electrolyte Composed of LiTa2PO8 and [C2mim][FSA]–Li[FSA] Ionic Liquid for Rechargeable Lithium Metal Batteries

open access: yesAdvanced Materials Interfaces, EarlyView.
LiTa2PO8 (LTPO) suffers from high interfacial resistance when paired with Li metal due to poor solid‐solid contact. Coating LTPO with an ionic liquid (IL) markedly improves interfacial stability, maintaining favorable resistance up to 2000 cycles. However, contact between IL‐coated LTPO and Li metal induces discoloration of LTPO, which is attributed to
Mizuki Fukuda   +5 more
wiley   +1 more source

Smart‐Release Ion‐Exchanged Ca‐Montmorillonite for Corrosion Protection of AA2024 Aluminium Alloy

open access: yesAdvanced Materials Interfaces, EarlyView.
Smart‐release anticorrosion pigments based on Zn‐ and Mn‐modified montmorillonite were developed by ion exchange of Ca‐montmorillonite and evaluated for the protection of AA2024 aluminium alloy in artificial acid rain. Both modified pigments provided effective corrosion inhibition, with Zn‐modified montmorillonite (Zn‐MMT) achieving an inhibition ...
Sergiy Korniy   +2 more
wiley   +1 more source

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