Results 21 to 30 of about 397 (163)

Theoretical Analysis of Simulated Moving Bed Reactor for Rapid Reversible Acetalization of Glycerol with Acetone to Synthesize Solketal

open access: yesJournal of Chemical Engineering of Japan, 2023
The efficient reversible acetalization to synthesis solketal from glycerol and acetone (A + B ⇄ C + D type reversible reaction) using a simulated moving bed reactor (SMBR) packed with hydrogen-type cation-exchange resin Amberlyst 16 as a solid catalyst ...
Takuya Fukumura   +5 more
doaj   +1 more source

Transformations of Glycerol into High-Value-Added Chemical Products: Ketalization and Esterification Reactions

open access: yesReactions, 2023
Biomass allows us to obtain energy and high-value-added compounds through the use of different physical and chemical processes. The glycerol obtained as a by-product in the synthesis of biodiesel is considered a biomass compound that has the potential to
Federico M. Perez   +3 more
doaj   +1 more source

Electrooxidation of the Glycerol Derivative Solketal over Cu−Co Hydroxycarbonates to Enable the Synthesis of Glyceric Acid

open access: yesChemElectroChem, 2023
The glycerol oxidation reaction (GOR) has high potential in substituting the oxygen evolution reaction (OER) in electrochemical water splitting, enabling the synthesis of value‐added organic products.
Bhawana Kumari   +7 more
doaj   +1 more source

Oxidation Kinetics of Neat Methyl Oleate and as a Blend with Solketal

open access: yesEnergies, 2023
The complexity of biodiesel aging has shown that the mechanism needs further research. The rate of aging product formation and associated interactions can help improve fuel quality. Since biodiesel is a multicomponent system and constant changes occur in
Julian Türck   +6 more
doaj   +1 more source

An Expedient Catalytic Process to Obtain Solketal from Biobased Glycerol [PDF]

open access: yesProcesses, 2021
Developing simple and effective chemistry able to convert industrial waste streams into valuable chemicals is a primary contributor to sustainable development. Working in the context of biodiesel production, we found that plain bisulfate on silica (SSANa, 3.0 mmol/g) proved to be an optimal catalyst to convert glycerol into solketal.
Roncaglia F.   +3 more
openaire   +2 more sources

Comparison of Engine Performance between Nano- and Microemulsions of Solketal Droplets Dispersed in Diesel Assisted by Microwave Irradiation

open access: yesMolecules, 2019
As a derivative product of bio-glycerol, this study first uses solketal as a combustion improver for enhancing diesel engine characteristics. The emulsions of nanometer- and micrometer-sized droplets of solketal, which disperse evenly in the ultra-low ...
Cherng-Yuan Lin, Shih-Ming Tsai
doaj   +1 more source

Biodiesel Additives Synthesis Using Solid Heteropolyacid Catalysts

open access: yesEnergies, 2023
Fossil additives are a primary energy source and their contribution is around 80% in the world. Therefore, bioadditives that reduce their impact are each very important. This article discusses the chemical transformation of glycerol to carbonate, ethers,
Marcio Jose da Silva   +2 more
doaj   +1 more source

Ketalization of glycerol to solketal in supercritical acetone

open access: yesThe Journal of Supercritical Fluids, 2011
Abstract In the last few years, the increasing production of biodiesel has led to an overproduction of glycerol, the main byproduct of this industry. This paper reports on the ketalization of glycerol in supercritical acetone to give solketal (4-hydroxymethyl-2,2-dimethyl-1,3-dioxolane), an oxygenated compound useful as chemical and fuel additive for
Royon, Daniela Beatriz   +2 more
openaire   +2 more sources

Soot formation and ignition properties of diesel fuels with solketal in an injection chamber

open access: yesEnergy Conversion and Management: X
The global energy transition drives an enhanced emphasis on innovative fuel design approaches. Novel renewable fuel components are being sought that are drop-in compatible and exhibit synergistic interactions within fuel components.
Julian Türck   +7 more
doaj   +1 more source

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